Growth of bubbles containing plasma in water by high-frequency irradiation

Plasma was generated in water by irradiation at high frequency of 13.56 MHz, and the behavior of bubbles including the plasma was observed by a high-speed camera. The generation pattern of the bubbles was classified into four types according to liquid temperature and supplied power. Conducting the simulation, the maximum temperature in the bubble was found to be from 3500 K to 4300 K, and the decomposition of water molecule occurred. The gas in the bubble was found to become high ratio of hydrogen. The phenomenon can be regarded as a film boiling of exceptionally high heat flux.     

Synthesis of optical quality ZnO nanowires utilizing ultrasonic spray pyrolysis

ZnO nanowires were grown by an ultrasonic spray pyrolysis technique. The aspect ratio and size of the wire were dependent mainly on the pH value of a precursor solution and the growth temperature. By high-resolution transmission electron microscopic analysis and photoluminescence measurements, it was confirmed that the nanowires are monocrystalline with good optical quality.     

Nanostructure formation in the surface layer of metals under influence of high-power electric current pulse

The possibility to tailor the microstructure of metals is explored utilising a skin-effect for surface treatment. The theoretical simulation of the electric and magnetic fields in a metallic cylinder shows that melting followed by rapid quenching can occur in a skin layer of 5–10-μm thickness if the amplitude of a single electric pulse of several nanoseconds duration is of the order of hundreds kiloamperes. The experiments using the SUS304 stainless steel show that besides a thin amorphous layer, a specific nano-twin structure can form at the near-surface region. The appearance of nano-twins is explained considering the stress components arising at the surface layer and in the bulk of the specimen during shock wave propagation caused by temperature gradients and the Lorentz force. It is shown that the high stress amplitudes can arise locally, furnishing the required conditions for twin nucleation and resulting in intensive plastic deformation of the sub-surface layer.     

Self-flux synthesis and photoluminescent properties of LiAl5O8

Pure-phase LiAl₅O₈ was selected as an oxide ceramic red phosphor material without dopants (color centers) and was synthesized using a self-flux method. The LiAl₅O₈ was formed by heating a powder mixture consisting of γ-Al₂O₃:Li₂SO₄ = 1:2 (molar ratio) at over 1100 °C for 1 h. Photoluminescence (PL) properties for the synthesized LiAl₅O₈ were investigated. The maximum intensity of the excitation spectrum for the photoluminescent emission of LiAl₅O₈ synthesized was at 274 nm. The peak intensity of the emission spectrum was at a wavelength of 667 nm (red color). The intensity of the peak emission spectrum increased with the heating temperature, i.e., the maximum peak intensity of the red emission spectrum was detected for the LiAl₅O₈ synthesized by heating at 1500 °C for 1 h.     

First paralytic shellfish poison (PSP) infestation of bivalves due to toxic dinoflagellate Alexandrium tamiyavanichii, in the southeast coasts of the Seto Inland Sea, Japan

The mussel Mytilus edulis and the cultured ark shell Anadara broughtonii in the southeast coasts of the Seto Inland Sea were contaminated with paralytic shellfish poison (PSP) following the appearance of the dinoflagellate Alexandrium tamiyavanichii in early December 1999. A. tamiyavanichii plankton collected around the Straits of Naruto on December 3, 1999 showed PSP toxicity, of which 83 mol% was accounted for by GTX2, GTX3 and GTX4. Its specific toxicity was 112.5 fmol/cell, and one MU was equivalent to 7,200 cells. Toxicity values at the beginning of toxification were 4.7 MU/g for the ark shell and 7.3 MU/g for the mussel. In the former, the value remained at almost 4 MU/g, resulting in prohibition of marketing for about two months. In the latter, it sharply decreased to less than 4 MU/g. These bivalves collected during the toxification period were dissected into five tissues, mantle, adductor muscle, hepatopancreas, gills and "others", and submitted to high-performance liquid chromatography (HPLC). The cultured ark shell accumulated GTX2, GTX3 and STX as major components and GTX1, GTX4, GTX5, neoSTX, dcSTX and PX1-3 (C1-C3) as minor ones. The amount of GTX3 decreased with time, while STX tended to increase. At the early stage of PSP toxification, toxins were accumulated in the gills and "others", most of which were quickly detoxified. On the other hand, PSP of the toxified mussel consisted of GTX4 as a main component, and GTX1, GTX2, GTX3, GTX5, STX and PX1-2 (C1-C2) as minor ones. Its toxin composition pattern was similar to that of the ingested causative plankton. Its total toxin decreased soon after disappearance of the dinoflagellate. During the decrease of toxicity, PSP tended to be retained in the hepatopancreas, resulting in accumulation of 50 mol% of total toxin.     

Isotope 18O/16O ratio measurements of water vapor by use of the 950-nm wavelength region with cavity ring-down and photoacoustic spectroscopic techniques

Two optical methods, cavity ring-down spectroscopy and photoacoustic spectroscopy, are applied to the measurement of the isotope ratio 18O/16O in water-vapor samples with a Nd3+:YAG pumped-dye laser. The combination band of (2v1 + v3) in the 960-nm region of water molecules is investigated for two standard water samples, the Vienna Standard Mean Ocean Water and the Standard Light Antarctic Precipitation. The results demonstrate that the two methods have the potential of compact systems for in-situ measurements of H2O isotope ratio in the environment.     

A flow method with photocatalytic oxidation of dissolved organic matter using a solid-phase (TiO2) reactor followed by amperometric detection of consumed oxygen

A photocatalytic sensor for the determination of chemical oxygen demand (COD) using titanium dioxide, based on the use of a pair of oxygen electrodes and flow injection analysis, is described. The measuring principle is based on the direct determination of the oxygen concentration change resulting from photocataltic oxidation of organic compounds. One of the two oxygen electrodes, the reference oxygen electrode, was utilized to measure the reference signal responding only to oxygen present in the injected samples. Oxygen consumption due to the TiO2-catalyzed photochemical oxidation of organic compounds in samples was monitored with the working oxygen electrode. The COD value of this sensor was calculated as the difference of the currents at reference and working oxygen electrodes, respectively. The operation characteristics of the sensor are demonstrated using artificially treated wastewater as a substrate. The sensor was also applied to the determination of COD in real water samples from dam reservoirs (n = 20) all over Japan. The results were in good agreement with those from the conventional COD methods (i.e., permanganate and dichromate methods).     

Sperm phospholipase Czeta from humans and cynomolgus monkeys triggers Ca2+ oscillations,activation and development of mouse oocytes

Fusion with a fertilizing spermatozoon induces the mammalian oocyte to undergo a remarkable series of oscillations in cytosolic Ca(2+), leading to oocyte activation and development of the embryo. The exact molecular mechanism for generating Ca(2+) oscillations has not been established. A sperm-specific zeta isoform of phospholipase C (PLCzeta) has been identified in mice. Mouse PLCzeta triggers Ca(2+) oscillations in mouse oocytes and exhibits properties synonymous with the 'sperm factor' that has been proposed to diffuse into the oocyte after gamete fusion. The present study isolated the PLCzeta homologue from human and cynomolgus monkey testes. Comparison with mouse and monkey PLCzeta protein sequences indicates a shorter X-Y linker region in human PLCzeta and predicts a distinctly different isoelectric point. Microinjection of complementary RNA for both human and cynomolgus monkey PLCzeta elicits Ca(2+) oscillations in mouse oocytes equivalent to those seen during fertilization in mice. Moreover, human PLCzeta elicits mouse egg activation and early embryonic development up to the blastocyst stage, and exhibits greater potency than PLCzeta from monkeys and mice. These results are consistent with the proposal that sperm PLCzeta is the molecular trigger for egg activation during fertilization and that the role and activity of PLCzeta is highly conserved across mammalian species.     

Model-less visual servoing using modified simplex optimization

This article describes a robot positioning task with respect to a static target by visual servoing. The vision system is uncalibrated, and the kinematic model of the robot may be totally unknown. The displacements of the robot at joint level are generated in real time in order to minimize the objective function. The objective function includes the quadratic error between the current and the desired target images. A simplex method is used to minimize the objective function, and a Newton-like method is also used near convergence. We successfully validated this method with simulations under the graphic library OpenGL. This work was presented in part at the 10th International Symposium on Artificial Life and Robotics, Oita, Japan, February 4–6, 2005     

Mechanism for change in leakage current waveform on a wet silicone rubber surface-a study using a dynamic 3-D model

This paper describes the results of experiments and simulations made to examine the waveform of leakage current flowing through the surface of HTV (high temperature vulcanized) silicone rubber specimen exposed to clean fog. Water droplets were placed on the surface of specimen energized with AC voltage and investigations of the surface state were done by a high-speed video camera in a wet condition produced by sprayed clean fog. Simultaneously, according to the experimental condition, a dynamic 3-D model was built to calculate the electric field and current density distribution on the specimen surface by a finite element software. A conducting water layer is formed due to the deformation of droplets and the development of dry band arcing. This caused large distortion and nonlinearly which increased the odd harmonic components in the leakage current waveform. This is in good agreement with the simulating calculation. The information from the leakage current frequency characteristic was extracted and correlated with the insulation surface condition. It can be considered as a diagnostic index for electrical characteristics and insulation state of polymer insulators in the wet condition.