Radiation-induced polymerization of ethylene in pilot plant. III. Heavy-phase recycling process

Radiation-induced polymerization of ethylene using aqueous tert-butyl alcohol as medium was carried out in a large-scale pilot plant with a 50-liter central source-type reactor at a pressure of 105 to 395 kg/cm², temperature of 30° to 80°C, mean dose rate of 4.5 × 10⁴ to 1.9 × 10⁵ rads/hr, ethylene feed rate of 5.5 to 23.5 kg/hr, and medium feed rate of 21 to 102 l./hr. The space–time yield and molecular weight of the polymer were in the range of 4.7 to 16.8 g/l.-hr and 1.3 × 10⁴ to 8.9 × 10⁴, respectively. The space–time yield and molecular weight increased with mean residence time at 30°C, whereas at 80°C they became almost independent of the time. The space–time yield increased with pressure and dose rate, slightly decreased with temperature, and was maximum at ethylene molar fraction of 0.5. The polymer molecular weight increased with pressure and ethylene molar fraction, and decreased with dose rate and temperature. The total amount of deposited polymer on the reactor wall, source case wall, and scraping blades was usually less than 1 kg, which was negligibly small for the analysis of polymerization. Continuous discharge of the polymer slurry and production of fine-powder polyethylene were successfully carried out. In the central source-type reactor, a dose rate of 1.9 × 10⁵ rads/hr was obtained with a ⁶⁰Co source of ca. 12 kCi.     

The oxidation of nanocrystalline Ni3Al fabricated by mechanical alloying and spark plasma sintering

Nanocrystalline Ni₃Al was fabricated through mechanical alloying of elemental powders and spark plasma sintering. The nanocrystalline Ni₃Al has a nearly full density after being sintered at 1223 K for 10 min under a pressure of 65 MPa. Isothermal and cyclic oxidations of nanocrystalline Ni₃Al were tested at 1173–1373 K with intervals of 100 K. The results indicate that nanocrystalline Ni₃Al exhibits excellent isothermal and cyclical oxidation resistance. The oxide scales consist primarily of dense and continuous -Al₂O₃. The grain refinement is beneficial for improving the oxidation resistance of Ni₃Al by providing more nucleation centers for the Al₂O₃ formation, promoting the selective formation of Al₂O₃ and improving the adhesion of oxide scales to the matrix.     

Parametric polynomial spectral factorization using the sum of roots and its application to a control design problem

This paper presents an algebraic approach to polynomial spectral factorization, an important mathematical tool in signal processing and control. The approach exploits an intriguing relationship between the theory of Gröbner bases and polynomial spectral factorization which can be observed through the sum of roots, and allows us to perform polynomial spectral factorization in the presence of real parameters. It is discussed that parametric polynomial spectral factorization enables us to express quantities such as the optimal cost in terms of parameters and the sum of roots. Furthermore an optimization method over parameters is suggested that makes use of the results from parametric polynomial spectral factorization and also employs two quantifier elimination techniques. This proposed approach is demonstrated in a numerical example of a particular control problem.     

Patient views of adverse events: comparisons of self-reported healthcare staff attitudes with disclosure of accident information

In the present paper, we report results of surveys in 2003 in Japan and Denmark about patients' views about adverse events, focusing on the actions of healthcare staff involved in a medical accident. Results show that patients were more likely to indicate negative expectations to a doctor's reactions after a medical accident when asked in general terms than when asked in relation to concrete case stories. When asked in general terms, 66% (47%) of Japanese (Danish) respondents expected that doctors sometimes hold back on providing information to patients about a medical accident, while 37% (7%) did so when asked about a concrete, mild-outcome case. We examine some possible reasons for the relatively high level of distrust of Japanese patients, and we discuss whether the seemingly lower level of disclosure in Japan than in Denmark and the negative stories in the Japanese press may have an impact. We also suggest some implications for introducing a patient-centred or customer-centred approach to risk management in healthcare and other domains.     

Fractional power approximation and its generation

For an analog simulating system, an approximating system is proposed. Its mathematical form is expressed by an algebraic equation:

$\text{? (x) ≈ α + β χ + γχ}{}^{\mathrm{k}}$

with four parameters given by real numbers. Their values can be determined so as to satisfy a best fit in a Chebyshev sense. Then, the accuracy is of the same order with that obtained by any kind of ordinary power series up to terms o f the third order. It is noticeable that a given function can be accurately approximated by this equation without destroying its uniform continuity.As its electronic system, it is possible to utilize forward current-voltage characteristics o f p-n diodes near their origins. Different functions can be produced by adjusting an amount o f ordinary resistances connected to diodes in series.     

Leak-tightness characteristics concerning the containment structures of the HTTR

The containment structures of the HTTR consist of the reactor containment vessel, the service area, and the emergency air purification system, which minimise the release of fission products in postulated accidents, which lead to fission product release from the reactor facilities. The reactor containment vessel is designed to withstand the temperature and pressure transients and to be leak-tight in the case of a rupture of the primary concentric hot-gas duct, etc. The pressure inside the service area is maintained at a negative pressure by the emergency air purification system. The emergency air purification system will also remove airborne radioactivity and will maintain a correct pressure in the service area.The leak-tightness characteristics of the containment structures are described in this paper. The measured leakage rates of the reactor containment vessel were enough less than the specified leakage limit of 0.1%/d confirmed during the commissioning tests and annual inspections. The service area was kept in a way that the design pressure becomes well below its allowable limitation by the emergency air purification system, which filters efficiency of particle removal and iodine removal well over the limited values.The obtained data demonstrate that the reactor containment structures were fabricated to minimise the release of fission products in the postulated accidents with fission product release from the reactor facilities.     

Te concentration dependent photoemission and inverse-photoemission study of FeSe1?xTex

We have characterized the electronic structure of FeSe_1−xTe_x for various x values using soft x-ray photoemission spectroscopy (SXPES), high-resolution photoemission spectroscopy (HRPES) and inverse photoemission spectroscopy (IPES). The SXPES valence band spectral shape shows that the 2 eV feature in FeSe, which was ascribed to the lower Hubbard band in previous theoretical studies, becomes less prominent with increasing x. HRPES exhibits systematic x dependence of the structure near the Fermi level (E_F): its splitting near E_F and filling of the pseudogap in FeSe. IPES shows two features, near E_F and approximately 6 eV above E_F; the former may be related to the Fe 3d states hybridized with chalcogenide p states, while the latter may consist of plane-wave-like and Se d components. In the incident electron energy dependence of IPES, the density of states near E_F for FeSe and FeTe has the Fano lineshape characteristic of resonant behavior. These compounds exhibit different resonance profiles, which may reflect the differences in their electronic structures. By combining the PES and IPES data the on-site Coulomb energy was estimated at 3.5 eV for FeSe.     

Environmental impact assessment of the Egyptian cement industry based on a life-cycle assessment approach: a comparative study between Egyptian and Swiss plants

Egypt in 2015 announced the alteration of the fuels used in cement plants without the least regard to minimizing the environmental burden (EB) excesses. This study conducts a life-cycle assessment (LCA) of Egyptian cement-manufacturing unit, which is considered as the first one on LCA cement analysis to be conducted in Egypt. This study investigates the LCA of the cement industry in Egypt compared to the Swiss industry, using two methodologies. The first one has been done on-site, surveying the most common types of cement used in the construction industry in Egypt. Meanwhile, SimaPro software has been used to assess the environmental impacts, and three different cement plants were selected for this study: an Egyptian cement plant (ECP) which uses electricity, natural gas, and diesel as energy sources; a Swiss cement plant (SCP) which depends mainly on electricity, natural gas, and coal; and an Egyptian hypothetical plant (EHP) in which electricity and coal are assumed to be the main energy feeds, and comparisons of different strategies including midpoint and endpoint methods are outlined. Regarding the midpoint method, ETP recorded higher respiratory inorganics, aquatic acidification, global warming, and nonrenewable energy impacts than ECP, because of using coal, while for SCP, global warming and respiratory inorganics achieved the highest adverse impacts compared to ECP and EHP—due to the different manufacturing technology used. With regard to the endpoint method, the peak possibility of human health deterioration has been recorded due to the use of coal as fuel. This possibility was reduced by 46 % in the case of SCP as a result of the technology applied, which interestingly represents a reasonable reduction in terms of technological application.