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981.
Toshihiro Hirai Hiroki Sadatoh Tsutomu Ueda Toshiaki Kasazaki Yasushi Kurita Mitsuhiro Hirai Sadao Hayashi 《大分子材料与工程》1996,240(1):221-229
Polyurethane elastomers were investigated as electrically active materials for actuators. Components in hard segment and soft segment in the elastomers were varied. The elastomers with excellent electrostrictive properties were limited to those which had soft segments of polyesters and polylactones. It turned out, that the elastomers, whose soft segments are polyethers are electrically inert under the experimental conditions. The chemical structure of the hard segment seems not to influence to the electrostrictive property. The charging and discharging process was investigated. The charging process was found to proceed simultaneously with the contracting process caused by the electric field, suggesting that the orientation of the soft segment in the elastomer plays critical rolls in the electrostrictive action. In the elastomer, which has a soft polyether segment and was inactive to the electric field, could be actuated very efficiently when the elastomer was swollen with dimethyl sulfoxide. We conclude that the polyurethane elastomer, whose soft segment has chemical bonds with a relatively large dipole moment, can be actuated by the electric field application, and that even the elastomer, whose soft segment is inactive, could be actuated in the presence of a solvent with a large dipole moment. Thus, the concept found with the gel, could be applied to an elastomer, the soft segment of which plays partly the roll of the solvent in the gel. 相似文献
982.
Aeromonas hydrophila N‐6, isolated from a soil sample, converted vegetable oils to several rare unsaturated fatty acids and alcohols accumulated inside the cells as a wax ester form. A. hydrophila N‐6 effectively decreased fatty acid chain lengths, and converted rapeseed, safflower and linseed oils into 7‐16:1 and 5‐14:1 fatty acids, 7,10‐16:2 and 5,8‐14:2 fatty acids, and 7,10,13‐16:3 fatty acids, respectively. Furthermore, A. hydrophila N‐6 reduced the resulting fatty acids to rare unsaturated fatty alcohols, such as 7‐16:1, 5‐14:1, 9,12‐18:2, 7,10‐16:2, 9,12,15‐18:3 and 7,10,13‐16:3. Such unsaturated fatty acids and alcohols are rarely found in natural oils. Because decreasing fatty acid carbon chain lengths from the carboxyl end and reducing unsaturated fatty acids to unsaturated fatty alcohols in industrially applicable scale are both difficult reactions to accomplish by chemical means, we suggest that A. hydrophila N‐6 may facilitate the introduction of new bioprocesses for producing rare unsaturated fatty acids and alcohols, especially fatty alcohols with more than two double bonds. 相似文献
983.
Toshihiro Tanaka Nev A. Gokcen Dieter Neuschütz Philip J. Spencer Zen-ichiro Morita 《国际钢铁研究》1991,62(9):385-389
The partial excess Gibbs energy Δ?BEx as well as the relationship between the partial enthalpy of mixing ΔH?B and the partial excess entropy of solution ΔS?BEx of various solute elements in liquid Fe, Al and Pb binary alloys were evaluated from a new solution model, in which ΔS?BEx can be calculated from the values of ΔH?B by Miedema's semi-empirical method and some relevant physical properties of the components in the alloys. These calculated values of Δ?BEx were found to be in reasonable agreement with the selected values presented so far. The present model gives the values of Δ?BEx, for which the experimental data are not yet available. 相似文献
984.
Park KH Sung WJ Kim S Kim DH Akaike T Chung HM 《Journal of Bioscience and Bioengineering》2005,99(3):285-289
Poly[N-p-vinylbenzyl-O-beta-mannopyranosyl-(1-4)-D-gluconamide] (PV-Man) is a polystyrene derivative that contains mannose moieties and interacts with the mannose-receptor-carrying macrophage cell line. To clarify the specific interaction between the PV-Man and the macrophage cell line J774A1, PV-Man polymer labeled with fluorescent fluorescein isothiocyanate (FITC) was used to amonitor the specific interaction, which was visualized by confocal laser microscopy. We found that PV-Man strongly binds to macrophage cells, probably due to a specific interaction mediated by the presence of mannose receptors on the cell membrane. The fluorescence intensity of PV-Man and macrophage cells was up to 7-fold that of any other glycopolymers bound to macrophage cells. Moreover, cellular fluorescence intensity increased significantly with increasing incubation time and polymer concentration. Many macrophage cells strongly express mannose and mannose receptor-related receptors, and receptor-mediated gene transfer via the mannose receptor using a PV-Man glycopolymer is a versatile means of targeted gene delivery into these cells. 相似文献
985.
Takahisa?YAMAMOTOEmail author Yukio?SATO Tomohito?TANAKA Katsuro?HAYASHI Yuichi?IKUHARA Taketo?SAKUMA 《Journal of Materials Science》2005,40(4):881-887
In some electroceramic materials, their unique electrical properties are due to potential barriers, i.e., double Schottky barriers (DSBs), formed at grain boundaries. So far, some researchers have revealed that the electrical properties of DSB are closely related to grain boundary characters, especially grain boundary coherency. For example, highly coherent boundary does not give PTCR or varistic property, while random types exhibit clear resistivity jump or abrupt current increment. Therefore, a concept of grain boundary design will be required for future device manufacturing, even in bulk materials. But it has not been clarified yet why the electron transport behaviors depend on them. In order to address this question, it is necessary to carry out a systematic experiment focusing on single grain boundaries using well-defined bicrystals.In the present study, we have summarized our studies with a special interest in electron transport behavior across single grain boundaries for n-type BaTiO3, SrTiO3 and ZnO. 相似文献
986.
Toshihiro Minemura Yoshio Hanzawa Sourin Dutta 《Computers & Industrial Engineering》1992,23(1-4):191-194
This paper shows the development of a method of creating Diagnostic Centers for examination rooms for elderly patients. The data related to the population of patients treated in hospitals in Japan. The results of the analysis are being used to develop a suitable facility for examination of elderly patients. 相似文献
987.
988.
MANABU TANAKA 《Journal of Materials Science Letters》1997,16(12):1040-1042
Abstracts are not published in this journal
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
989.
990.
Toshihiro Kasuga Koichi Nakamura Eikichi Inukai Yoshihiro Abe 《Journal of the American Ceramic Society》1996,79(4):885-888
A new method for joining bismuth-based superconducting glass-ceramics has been developed; they are joined easily by melting-annealing with a liquid natural gas (LNG) -oxygen flame. Two edge portions of the glass-ceramics to be joined are melted by a high-temperature flame, and the molten faces are placed quickly against each other. Subsequently, the joined portion is annealed sufficiently with a soft flame, resulting in a unified product with no cracks. Although the directly unified product is broken electrically, it is converted to a superconductor, with T c ∼ 90 K, by postheating at ∼ 830°C, and its critical current density is almost the same as that of the original glass-ceramic. This technique is very important for fabrication of large-sized superconducting ceramics, such as bushing apparatuses. 相似文献