API X52管线钢与Corus RQT 701超高强钢的焊接工艺

针对超高强钢在机械行业的广泛使用,焊接接头易出现淬硬脆化、裂纹等缺陷的情况,采用焊条电弧焊(SMAW)和药芯气体保护焊(FCAW-GS)组合的焊接方法,对API X52管线钢与Corus RQT 701超高强钢的焊接进行了工艺试验,并进行常规力学性能试验。结果表明,通过合理匹配焊接工艺参数,严格控制低热输入量及层间温度,实现了小熔合比的异种钢焊接,且焊接接头具有良好的力学性能,达到了标准和规格书的要求;异种高强钢焊接,采用SMAW打底焊接和FCAWGS填充并盖面的方法,焊接效率较单纯采用焊条电弧焊工艺提高2倍以上。     

Colored amorphous silica-based powder with TiN nanocrystals precipitated by ammonolysis of Ti–Si–O ternary glass

Coloration of amorphous silica powder containing titania was investigated by nitridation in an ammonia flow. The oxide precursors were obtained by the hydrolysis of a mixture of tetraethyl orthosilicate (TEOS) and tetrabutoxy titanium (TBT). The color changed with the amount of TBT in the mixture, the hydrolysis pH and the ammonolysis temperature. The original white color of the 8 mol% TBT powder hydrolyzed under basic pH conditions changed to pale goldenrod at 700°C, then to dark olive green at 800°C, and further darkened with increasing ammonolysis temperature. A steel-blue color appeared at 900°C for the powder obtained with 3 mol% TBT, and increased in darkness at 1000°C. A similar bluish color was observed for powders obtained by acidic hydrolysis after ammonolysis above 900°C, and this was independent of the amount of titania, although the chroma decreased with increasing firing temperature for the powder with 3 mol% TBT. The ammonolysis powder products were characterized using X-ray diffraction (XRD), electron probe micro analysis (EPMA), transmission electron microscopy-electron energy-loss spectroscopy (TEM-EELS), scanning transmission electron microscopy-high-angle annular dark-field imaging (STEM-HAADF) and Ti–K edge X-ray absorption fine structure (XAFS). The color change was related to both precipitated TiN nanocrystals and residual titanium in the amorphous silica matrix. The TiN exhibited a goldish reflection and also plasmonic absorption from light blue to gray depending on the TiN crystallite size. The plasmonic absorption and resonance of nanocrystalline TiN will be useful similarly to that of gold in nanotechnology for various kinds of energy application.     

Investigation of Alkali‐Ion (Li,Na, and K) Intercalation in KxVPO4F (x ∼ 0) Cathode

This work compares the intercalation of K, Na, and Li in K_xVPO₄F (x ～ 0). The K_xVPO₄F (x ～ 0) cathode delivers reversible capacities of ≈90–100 mAh g^?1 in K, Na, and Li cells, at an average voltage of ≈4.33 V for K, ≈3.98 V for Na, and ≈3.96 V for Li. This is so far the highest average voltage known for a K‐intercalation cathode. The lower voltage of Li insertion compared to Na is attributable to undercoordinated Li ions in the K_xVPO₄F (x ～ 0) framework. While the material shows high rate capability for all the alkali ions, Li migration in K_xVPO₄F (x ～ 0) is more difficult than with Na and K. This work suggests that a large cavity is not always good for insertion of alkali ions and cathode materials need to be suitably tailored to each intercalating ion species.     

Predicting the Life Span of Dies Used for Soft Magnetic Core Motors

This paper describes a method of predicting the life span of the dies used in motor manufacture from soft magnetic composites (SMCs). In the present study, a clawtooth motor was used. The method involves performing a stress analysis of a die followed by fatigue testing of test pieces. In the analysis, the SMC was assumed to be in powder form and its yield function was derived by a simple method. In addition to the analysis, we describe a simpler and more effective method in which the properties of the SMC are treated as boundary conditions. In the fatigue tests, we used test pieces that simulated the shape and construction material of the die. To predict the life span of the die, we evaluate the SN diagram, which represents the relationship between the maximum stress and fatigue life with respect to the stress generated in the die. The life expectancy of a new die, which is about 100 cycles of use, is found to agree substantially with its actual life. Furthermore, we explain how to extend the life span of a die to the targeted life span, namely, more than 200,000 cycles of use, by changing its shape to reduce stress.     

Thermodynamic Properties of Ionic Semiclathrate Hydrate Formed with Tetrabutylammonium Propionate

The phase equilibrium temperature and dissociation heat of tetrabutylammonium propionate (TBAPr) hydrate are reported. TBAPr hydrate is a type of ionic semiclathrate hydrates and also could potentially be used as thermal energy storage material. The temperature‐composition phase diagram of the TBAPr hydrate was determined in a defined range of mass fractions. Considering the dissociation heat of differential scanning calorimetry (DSC) measurements, multiple peaks of heat flow were observed in the TBAPr‐water system at the TBAPr mass fraction lower than 0.35, and there was a single peak at the mass fraction higher than 0.37.     

Wide Color Variation in SiNO Thin Films Dispersed with Precipitated TiN Nano Particles

Amorphous thin films of Ti_1?ySi_y(N,O) with y ≥ 0.38 were prepared by reactive sputter deposition in a nitrogen atmosphere. Thermal annealing of the films in an ammonia flow above 800°C yielded Si(N,O) amorphous thin films dispersed with precipitated TiN nanosized particles. The film color changed with Si content y and the annealing conditions, from carrot orange to cream yellow in the as‐deposited films due to their oxynitride nature, and from dark green to canary yellow and from iron blue to horizon blue at respective annealing temperatures of 800°C and 900°C due to metallic nature of the TiN nanosized particles precipitated in the annealing.     

Adaptive backstepping control of wheeled inverted pendulum with velocity estimator

In this paper, we introduce a backstepping control design of a wheeled inverted pendulum. Based on a second-order motion equation of the body angle, an adaptive integral backstepping controller is designed to stabilize the body angle. It is shown that the σ-modification rule in the adaptive update law guarantees the boundedness of the errors in estimating the time-varying signal that is an output of a linear system with every bounded input signal. Then, the stabilizing controller for the wheel angle is constructed by a PD-type positive feedback. The derived controller requires the full-state measurements. In the output feedback case, the K filter or the observer backstepping is needed. However, the structure of the controller becomes complicated. We propose a non-model-based differentiator based on the adaptive update law. Since the non-model-based differentiator does not require any knowledge of the dynamic structure of the signal, we can use it as a velocity estimator for unknown nonlinear systems. Therefore, we replaced the velocity measurement with the estimates by the non-model-based differentiator. Finally, simulation results for the proposed controller are presented.     

Effect of α-substituents on molecular motion and wetting behaviors of poly(fluoroalkyl acrylate) thin films with short fluoroalkyl side chains

The effect of α-substituent on the molecular motion and wetting behavior of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C₄], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C₄], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C₄], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C₄] films were characterized by dynamic contact angle measurement, lateral force microscopy (LFM), wide angle X-ray diffraction (WAXD), and X-ray photoelectron spectroscopy (XPS). WAXD of oriented PFClA-C₄ fiber suggested the presence of rod-like chain due to the presence of bulky α-substituent. The glass transition temperature (T_g) of PFFA-C₄ and PFClA-C₄ were well above the room temperature. The water repellencies of PFFA-C₄ and PFClA-C₄ were as high as that of PFMA-C₄ and their oil repellency of PFFA-C₄ and PFClA-C₄ was higher than the PFMA-C_4. This result was originated from the low main chain mobility of PFFA-C₄ and PFClA-C₄ due to the presence of bulky α-substituents. The effect of molecular motion on water repellency was clarified by the results of temperature dependence studies of dynamic contact angle, LFM, and surface chemical composition measured by XPS.     

Compression molding and melt‐spinning of the blends of poly(lactic acid) and poly(butylene succinate‐co‐adipate)

Poly(lactic acid) (PLA) is a biobased polymer made from biomass having high mechanical properties for engineering materials applications. However, PLA has certain limited properties such as its brittleness and low heat distortion temperature. Thus, the aim of this study is to improve toughness of PLA by blending with poly(butylene succinate‐co‐adipate) (PBSA), the biodegradable polymer having high toughness. Polymer blends of PLA and PBSA were prepared using a twin screw extruder. The melt rheology and the thermal property of the blends were examined. Further the blends were fabricated into compression molded parts and melt‐spun fiber and were subjected to tensile and impact tests. When the PBSA content was low, PBSA phase was finely dispersed in the PLA matrix. On the other hand, when the PBSA content was high, this minor phase dispersed as a large droplet. Mechanical properties of the compression molded parts were affected by the dispersion state of PBSA minor component in PLA matrix. Impact strength of the compression molded parts was also improved by the addition of soft PBSA. The improvement was pronounced when the PBSA phase was finely dispersed in PLA matrix. However, the mechanical property of the blend fibers was affected by the postdrawing condition as well as the PBSA content. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41856.