Metall-Matrix-Verbundwerkstoffe auf Eisenbasis

Metal-Matrix-Composites use a reinforcing phase to improve the mechanical properties of the matrix material or achieve a weight reduction. For example in iron and steel industrial applications typically carbides and borides are used to improve wear resistance. The intention of current investigations at the Chair of Metallurgy at the Montanuniversitaet Leoben is to produce a composite with reduced density and consistent or increased stiffness as steel. This paper reviews possible processing routes on steel composites with ceramic reinforcing phases based on a literature survey. A classification of the processing steps based on the origin of the ceramic phase is made and the advantages and disadvantages of these steps are summarized. Two tables are given to present the high amount of possible producing steps and the used investigation techniques for steel-based metal matrix composites.     

Life-cycle assessment of hydrogen technologies with the focus on EU critical raw materials and end-of-life strategies

We present the results of a life-cycle assessment (LCA) for the manufacturing and end-of-life (EoL) phases of the following fuel-cell and hydrogen (FCH) technologies: alkaline water electrolyser (AWE), polymer-electrolyte-membrane water electrolyser (PEMWE), high-temperature (HT) and low-temperature (LT) polymer-electrolyte-membrane fuel cells (PEMFCs), together with the balance-of-plant components. New life-cycle inventories (LCIs), i.e., material inputs for the AWE, PEMWE and HT PEMFC are developed, whereas the existing LCI for the LT PEMFC is adopted from a previous EU-funded project. The LCA models for all four FCH technologies are created by modelling the manufacturing phase, followed by defining the EoL strategies and processes used and finally by assessing the effects of the EoL approach using environmental indicators. The effects are analysed with a stepwise approach, where the CML2001 assessment method is used to evaluate the environmental impacts. The results show that the environmental impacts of the manufacturing phase can be substantially reduced by using the proposed EoL strategies (i.e., recycled materials being used in the manufacturing phase and replacing some of the virgin materials). To point out the importance of critical materials (in this case, the platinum-group metals or PGMs) and their recycling strategies, further analyses were made. By comparing the EoL phase with and without the recycling of PGMs, an increase in the environmental impacts is observed, which is much greater in the case of both fuel-cell systems, because they contain a larger quantity of PGMs.     

Nonoxidative methane activation,coupling, and conversion to ethane,ethylene, and hydrogen over Fe/HZSM‐5, Mo/HZSM‐5, and Fe–Mo/HZSM‐5 catalysts in packed bed reactor

A high abundance of methane and its relatively low price make it an attractive raw feedstock for the production of ethylene, which is in the consumer demand in recent years. Direct catalytic nonoxidative conversion is interesting, because it could be utilized on natural gas well sites. Monometallic and bimetallic Fe and Mo catalysts were prepared for the purpose of the coupling to ethane and ethene. Three supported materials were synthesized with the following loading of metal: 2.5‐wt% Fe, 5.0‐wt% Fe, and 2.5‐wt% Mo on HZSM‐5. Process' chemical reactions were also catalyzed with a constant 2.5‐wt% Mo/HZSM‐5, which had different amounts of Fe, namely, 0.5, 1.0, and 2.5 wt%. Fourier transform infrared (FTIR), N₂ adsorption/desorption, NH₃ temperature‐programmed desorption (TPD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X‐ray diffraction (XRD) were applied for characterization. Coke, accumulated on spent solids, was determined by thermogravimetric analysis (TGA). Activity was evaluated in quartz‐packed bed reactor. All surfaces suffered from deactivation due to carbon formation. The addition of Fe to Mo increased CH₄ reacted. The highest selectivity for alkenes was achieved over 1.0‐wt% Fe to 2.5‐wt% Mo/HZSM‐5. At the peak of performance, the C‐based reactivity was 52% for olefins and 2% for alkanes. Stability was accomplished over 2.5‐wt% Fe/HZSM‐5, where the rate of C₂ synthesis was comparatively stable for 20 hours of the time on stream. The selective C‐basis yield for C₂H₄ and C₂H₆ was 36% and 23%, respectively. The lowest measured quantity of (carbonaceous) by‐products was deposited on 2.5‐wt% Fe/HZSM‐5 after 26 hours. Propylene was detected very limitedly.     

Corrosion of Mg alloys EV31A,WE43B,and ZE41A in chloride- and sulfate-containing solutions saturated with magnesium hydroxide

This study studied corrosion in 0.1 M Na₂SO₄, 0.1 M NaCl, and 0.6 M NaCl, all saturated with Mg(OH)₂, using weight loss, hydrogen evolution, and electrochemical measurements. Corrosion was similar in all cases. Nevertheless, the corrosion rates were alloy-dependent, were somewhat lower in 0.1 M Na₂SO₄ than in 0.1 M NaCl, and increased with NaCl concentration. The corrosion damage morphology was similar for all solutions; the extent correlated with the corrosion rate. The corrosion rates evaluated by the electrochemical methods were lower than those evaluated from hydrogen evolution, consistent with the Mg corrosion mechanism involving the unipositive Mg⁺ ion.     

A novel facile synthesis and characterization of molybdenum nanowires

We describe a straightforward technique to synthesize pure Mo nanowires (NWs) from Mo₆S_yI_z (8,2 <y + z ≤ 10) NWs as precursor templates. The structural transformations occur when Mo₆S_yI_z NWs are annealed in Ar/H₂ mixture leading to the formation of pure Mo NWs with similar structures as initial morphologies. Detailed microscopic characterizations show that large diameters (>15 nm) Mo NWs are highly porous, while small diameters (<7 nm) are made of solid nanocrystalline grains. We find NW of diameter 4 nm can carry up to 30 μA current without suffering structural degradation. Moreover, NWs can be elastically deformed over several cycles without signs of plastic deformation.     

高山庇护所 斯诺文尼亚

<正>建设单位:PD Ljubljana Matica项目计划:庇护所结构工程:AKT II, Hanif Kara, Edward Wilkes实施及现场协调:PD Ljubljana Matica,Matevz Jerman, Davor Rozman项目情况:2016年竣工主承包商:Permiz d.o.o., Bostjan Perme OFIS和AKT II的建筑师同哈佛大学设计研究生院、Freeaproved、PD Ljubljana Matica、Rieder和Rockwool的学生合作完成了这个项目。     

Linkages between manufacturing strategy, benchmarking, performance measurement and business process reengineering

An empirical analysis is presented for researching linkages between manufacturing strategy, benchmarking, performance measurement (PM) and business process reengineering (BPR). Although the importance of these linkages has been described in conceptual literature, it has not been widely demonstrated empirically. The survey research was carried out in 73 medium and large-sized Slovenian manufacturing companies within the mechanical, electro-mechanical and electronic industries. The resulting data were subjected to reliability and validity analyses. Canonical correlation analysis was used to test six hypotheses.The results confirmed the need for a strategically-driven BPR approach and the positive impact of performance measurement on BPR performance.     

Student progress assessment with the help of an intelligent pupil analysis system

Students and lecturers would like to know how well students have learned the study materials being taught. A formal test or exam would cause needless stress for students. To resolve this problem, the authors of this article have developed an Intelligent Pupil Analysis (IPA) System. A sufficient amount of studies worldwide prove an interrelation between pupil size and a person's cognitive load. The obtained research results are comparable with the results from other similar studies. The original contribution of this article, compared to the research results published earlier, is as follows: the IPA System developed by the authors is superior to the traditional pupil analysis research due to the integration of pupil analysis with subsystems of decision support, recommender and intelligent tutoring systems and innovative Models of the Model-base, which permit a more detailed analysis of the knowledge attained by a student. This article ends with a case study to demonstrate the practical operation of the IPA System.     

Water Concession Principles for Geothermal Aquifers in the Mura-Zala Basin,NE Slovenia

Demand for thermal water in the Mura-Zala basin, situated between Slovenia, Austria, Hungary and Croatia, is constantly increasing, with the sandy geothermal aquifer within the Neogene Mura formation being the most exploited. During the water concession granting process various problems were identified, together with the need for elaboration of the uniform concession granting principles. The latter were devised according to the specific hydrogeological settings and field inspection of 23 geothermal wells, performed through use of an adapted methodology. The inspection revealed changes in wells performance, low efficiency of energy abstraction and a lack of reinjection. The acquired information was applied to the development of particular principles, including the six key indicators. Firstly, a unified and integrated operational monitoring programme must be established, and upgraded by a national surveillance monitoring. Secondly, an application of the best available techniques is proposed. Stimulation of energetic and balneology efficiency is also needed, with recharge and reinjection conditions evaluated and applied where possible. Limited or full water concessions could be granted based on their fulfilment then. This continuous step-by-step approach should enable the implementation of adequate measures to meet the standards required for the thermal groundwater bodies according to the EU water framework directions.     

Modelling of speech using primarily prosodic parameters

Hidden Markov Models are used in an experiment to investigate how state occupancy corresponds to prosodic parameters and spectral balance. In order to define separate sub-classes in the data using a maximum likelihood approach, modelling was performed using a single model where individual states correspond to different categories without assuming the structure of the data, rather than manually segmenting the data and modelling each predefined category separately.The results indicate a significant content of segmental information in the prosodic parameters, but the results based on the time-alignment of the model states with the feature vectors are in a form which is not directly usable in a recognition environment. The classification of various phonetic categories is particularly consistent for vowels and nasals and is generally better for voiced than unvoiced speech. The classification is also robust to influences of segmental effects on the data, with consistent alignments with segments regardless of the type of neighbouring phenemes.