Dislocations at Prismatic Fracture Surfaces in Sapphire

Single-crystal sapphire exhibits a highly anisotropic fracture behavior. The surfaces of specimens fractured along prismatic planes are wavy, with fractographic features appearing as small areas of contrast under an optical microscope. Optical microscopy, atomic force microscopy, X-ray topography, and confocal microscopy are used to demonstrate a correlation between the areas of contrast and dislocations penetrating the sample surface. The surface features are argued to be a consequence of the stress field surrounding the dislocations, which deflect the crack approximately 10 nm normal to the surface as the crack cuts the dislocations. The lateral extent of measurable surface deflection is of the order of 5 μm. These images can be compared directly to show the equivalence of the position of the dislocations observed by X-ray topography and the surface contrast observed optically.     

A neural network approach to predict activity coefficients

Artificial neural networks (ANNs) and a group‐contribution approach were used to develop an algorithm to predict activity coefficients for binary solutions. The Levenberg–Marquardt algorithm was used to train the ANN and to predict the parameters of the Margules equation. The ANN was trained using phase‐equilibrium database from DECHEMA. The selected systems include alcohols, phenols, aldehydes, ketones, and ethers. The trim mean based on 20% data elimination was selected as the best representation of the Margules‐equation parameters. The algorithm was validated with 121 VLE systems and results show that the ANN provides a relative improvement over the UNIFAC method.     

Flexible design‐planning of supply chain networks

Nowadays market competition is essentially associated to supply chain (SC) improvement. Therefore, the locus of value creation has shifted to the chain network. The strategic decision of determining the optimal SC network structure plays a vital role in the later optimization of SC operations. This work focuses on the design and retrofit of SCs. Traditional approaches available in literature addressing this problem usually utilize as departing point a rigid predefined network structure which may restrict the opportunities of adding business value. Instead, a novel flexible formulation approach which translates a recipe representation to the SC environment is proposed to solve the challenging design‐planning problem of SC networks. The resulting mixed integer linear programming model is aimed to achieve the best NPV as key performance metric. The potential of the presented approach is highlighted through illustrative examples of increasing complexity, where results of traditional rigid approaches and those offered by the flexible framework are compared. The implications of exploiting this potential flexibility to improve the SC performance are highlighted and are the subject of our further research work. © 2009 American Institute of Chemical Engineers AIChE J, 2009     

Life Cycle Assessment of urban wastewater reuse with ozonation as tertiary treatment: A focus on toxicity-related impacts

Life Cycle Assessment has been used to compare different scenarios involving wastewater reuse, with special focus on toxicity-related impact categories. The study is based on bench-scale experiments applying ozone and ozone in combination with hydrogen peroxide to a wastewater effluent from a Spanish sewage treatment plant. Two alternative characterisation models have been used to account for toxicity of chemical substances, namely USES-LCA and EDIP97. Four alternative scenarios have been assessed: wastewater discharge plus desalination supply, wastewater reuse without tertiary treatment, wastewater reuse after applying a tertiary treatment consisting on ozonation, and wastewater reuse after applying ozonation in combination with hydrogen peroxide. The results highlight the importance of including wastewater pollutants in LCA of wastewater systems assessing toxicity, since the contribution of wastewater pollutants to the overall toxicity scores in this case study can be above 90%. Key pollutants here are not only heavy metals and other priority pollutants, but also non-regulated pollutants such as pharmaceuticals and personal care products. Wastewater reuse after applying any of the tertiary treatments considered appears as the best choice from an ecotoxicity perspective. As for human toxicity, differences between scenarios are smaller, and taking into account the experimental and modelling uncertainty, the benefits of tertiary treatment are not so clear. From a global warming potential perspective, tertiary treatments involve a potential 85% reduction of greenhouse gas emissions when compared with desalination.     

Electrical stimulation vs thermal effects in a complex electromagnetic environment

Studies linking exposure to low levels of radiofrequencies with adverse health effects, notwithstanding their present apparent inconsistency, have contributed to a steady improvement in the quality of evaluating that exposure. In complex electromagnetic environments, with a multitude of emissions of different frequencies acting simultaneously, knowledge of the spectral content is fundamental to evaluating human exposure to non-ionizing radiation. In the present work, we quantify the most significant spectral components in the frequency band 0.5-2200 MHz in an urban area. The measurements were made with a spectrum analyzer and monopole, biconical, and log-periodic antennas. Power density levels were calculated separately for the medium wave, short wave, and frequency modulation radio broadcasting bands, and for the television and GSM, DCS, and UMTS mobile telephony bands. The measured levels were compared with the ICNIRP reference levels for exposure to multiple frequency sources for thermal effects and electrical stimulation. The results showed the criterion limiting exposure on the basis of preventing electrical stimulation of peripheral nerves and muscles to be stricter (exposure quotient 24.7 10^− 4) than that based on thermal considerations (exposure quotient 0.16 10^− 4). The bands that contribute most to the latter are short wave, with 46.2%, and mobile telephony with 32.6% of the total exposure.In a complex electromagnetic environment, knowledge of the radiofrequency spectrum is essential in order to quantify the contribution of each type of emission to the public's exposure. It is also necessary to evaluate the electrical effects as well as the thermal effects because the criterion to limit exposure on the basis of the effect of the electrical stimulation of tissues is stricter than that based on thermal effects.     

Temporal trends of pollution Pb and other metals in east-central Baffin Island inferred from lake sediment geochemistry

Concentrations and stable isotope ratios of lead (Pb) from lake sediments were used to quantify temporal patterns of anthropogenic Pb pollution in the Clyde River region of Baffin Island, Arctic Canada. Surface sediments from eight lakes on eastern Baffin Island and one from northern-most Greenland, spanning a gradient of 20° latitude, showed great variability with respect to Pb concentration and stable isotopic Pb ratios, with little apparent latitudinal trend. To constrain the temporal evolution of regional Pb pollution, a well-dated core from one of the sites, Lake CF8 on east-central Baffin Island, was analyzed geochemically at high stratigraphic resolution. A pronounced decrease in the ²⁰⁶Pb/²⁰⁷Pb ratio occurs in sediments deposited between 1923 and the mid-1970s, likely reflecting alkyl-Pb additives derived from the combustion of fossil fuels at a global scale. A two-component mixing model indicates that 17-26% of the Pb in the labile fraction of sediments deposited in Lake CF8 between 2001 and 2005 is from anthropogenic input. A Pb-Pb co-isotopic plot (²⁰⁶Pb/²⁰⁷Pb vs.²⁰⁸Pb/²⁰⁶Pb ratios) of the Lake CF8 time series data indicates multiple possible sources of industrial Pb pollution. Despite widespread reductions in industrial Pb emissions since the 1970s, there is no evidence for attendant reductions of pollution Pb at Lake CF8. Enhanced scavenging from increased primary production as well as changing precipitation rates as climate warms may represent important factors that modulate Pb deposition to Lake CF8, and Arctic lakes elsewhere.     

Activated α,β‐Unsaturated Aldehydes as Substrate of Dihydroxyacetone Phosphate (DHAP)‐Dependent Aldolases in the Context of a Multienzyme System

The utility for carbon‐carbon bond formation of a multienzyme system composed of recombinant dihydroxyacetone kinase (DHAK) from Citrobacter freundii, the fructose bisphosphate aldolase from rabbit muscle (RAMA) and acetate kinase (AK) for adenosine triphosphate (ATP) regeneration has been studied. Several aldehydes with great structural diversity, including three α,β‐unsaturated aldehydes, have been analysed as acceptor substrates. It was found that α,β‐unsaturated aldehydes bearing an electron‐withdrawing group in the β position to the double bond with a trans configuration are good acceptors for RAMA in this multienzyme system. The aldol reaction proceeds with excellent D ‐threo enantioselectivity and the aldol adduct is obtained in good overall yield. The L ‐threo and D ‐erythro enantiomers are also accessible from rhamnulose 1‐phosphate aldolase (Rha‐1PA) and fuculose 1‐phosphate aldolase (Fuc‐1PA) catalysed reactions, respectively.     

Treatment of petroleum refinery sourwater by advanced oxidation processes

The performance of several oxidation processes to remove organic pollutants from sourwater was investigated. Sourwater is a specific stream of petroleum refineries, which contains slowly biodegradable compounds and toxic substances that impair the industrial biological wastewater treatment system. Preliminary experiments were conducted, using the following processes: H2O2, H2O2/UV, UV, photocatalysis, ozonation, Fenton and photo-Fenton. All processes, except Fenton and photo-Fenton, did not lead to satisfactory results, reducing at most 35% of the sourwater dissolved organic carbon (DOC). Thus, further experiments were performed with these two techniques to evaluate process conditions and organic matter removal kinetics. Batch experiments revealed that the Fenton reaction is very fast and reaches, in a few minutes, an ultimate DOC removal of 13-27%, due to the formation of iron complexes. Radiation for an additional period of 60 min can increase DOC removal up to 87%. Experiments were also conducted in a continuous mode, operating one 0.4L Fenton stirred reactor and one 1.6L photo-Fenton reactor in series. DOC removals above 75% were reached, when the reaction system was operated with hydraulic retention times (HRT) higher than 85 min. An empirical mathematical model was proposed to represent the DOC removal kinetics, allowing predicting process performance quite satisfactorily.     

A 0.8 μm CMOS testable switched-capacitor filter for video frequency applications

This paper presents the design of a fifth-order low-pass elliptic filter that employs a parallel connection of two all-pass sections to satisfy specifications commonly used in video frequency applications. Operating with a sampling frequency of 16 MHz, the IC prototype was implemented in a standard double-poly CMOS 0.8 μm process. The experimental verification showed a passband frequency deviation smaller than 0.08 dB up to the passband edge frequency of 3.4 MHz, and an output noise power of 0.97 ${\mu {\rm V}_{\rm RMS}}/{\sqrt {Hz}}This paper presents the design of a fifth-order low-pass elliptic filter that employs a parallel connection of two all-pass sections to satisfy specifications commonly used in video frequency applications. Operating with a sampling frequency of 16 MHz, the IC prototype was implemented in a standard double-poly CMOS 0.8 μm process. The experimental verification showed a passband frequency deviation smaller than 0.08 dB up to the passband edge frequency of 3.4 MHz, and an output noise power of 0.97 , resulting in a dynamic range of 49.1 dB. The filter structure enables multiple fault detection and suits modern automated testing configurations to allow accurate estimation of the actually implemented transfer function parameters, an issue of increasing importance in VLSI circuit design. The relative area required for testing the fifth-order filter is only 8% of the total filter area, and decreases as the filter order increases. Jorge Morales Ca?ive was born in Cienfuegos, Cuba, in 1963. He received the B.Sc. and M.Sc. degrees from the Technical University of San Petersburg, Russia, in 1986 and 1988, respectively, and the D.Sc. degree from the Federal University of Rio de Janeiro, Brazil, in 1991, all in electrical engineering. From 1988 to 1994, he worked at CEADEN, in Havana, Cuba, on the development of nuclear equipments. From 1994 to 1997, he worked at INOR, in Havana, Cuba, on the research and development of acquisition systems and image processing for nuclear medicine. His research interests are in the areas of analog and digital signal processing. Antonio Petraglia (S’89-M’91-SM’99) received the Engineer and M.Sc. degrees from the Federal University of Rio de Janeiro (UFRJ), Brazil, in 1977 and 1982, respectively, and the Ph.D. degree from the University of California, Santa Barbara (UCSB), in 1991, all in electrical engineering. In 1979, he joined the Faculty of UFRJ as an Associate Professor of electrical engineering, where he served as a Co-Chair in the Department of Electronic Engineering from 1982 to 1984. During the second semester of 1991, he was a post-Doctoral researcher with the Department of Electrical and Computer Engineering at UCSB. Since 1992 he has been on the faculty of the Program for Post-Graduate Engineering at UFRJ, where in 1997 he established the Laboratory for the Processing of Analog and Digital Signals. From March 2001 through March 2002 he was a Visiting Scholar with the Electrical Engineering Department at the University of California, Los Angeles. He has been involved in teaching and research activities in the areas of analog and digital signal processing, and in mixed analog-digital integrated circuit design. He is a distinguished member of the Brazilian Millenium Group in Nanoelectronics and Microelectronics in 2006-2008. Dr. Petraglia served as an Associate Editor for the IEEE Transactions on Circuits and Systems-II: Analog and Digital Signal Processing in 2002–2003 Mariane Rembold Petraglia (M’97) received the B.Sc. degree in electronic engineering from the Federal University of Rio de Janeiro, Brazil, in 1985, and the M.Sc. and Ph.D. degrees in electrical engineering from the University of California, Santa Barbara, in 1988 and 1991, respectively. From 1992 to 1993, she was with the Department of Electrical Engineering, Catholic University of Rio de Janeiro, Brazil. Since 1993, she has been with the Department of Electronic Engineering and with the Program of Electrical Engineering, COPPE, at the Federal University of Rio de Janeiro, where she is presently an Associate Professor. From March 2001 to February 2002, she was a Visiting Researcher with the Adaptive Systems Laboratory, at the University of California, Los Angeles. Her research interests are in adaptive signal processing, multirate systems, and image processing. Dr. Petraglia is a member of Tau Beta Pi, and a distinguished member of the Brazilian Millenium Group in Nanoelectronics and Microelectronics in 2006–2008. She is serving as an Associate Editor for the IEEE Transactions on Signal Processing since Nov. 2004.