Development of radiochromic dosimeters based on polymer films with fluoran and divinyl phthalide dyes

Journal of Materials Science: Materials in Electronics - We fabricated polyvinyl chloride (PVC) and poly(methyl methacrylate) (PMMA) films containing NIR Black78, Black100 and Black400 for use as...     

A Consensus Protocol over Noisy Two‐Layered Networks with Cooperative and Antagonistic Interactions

This study is concerned with the consensus problems of multi‐agent systems with cooperative and antagonistic noisy interactions described by two‐layered network. That is, each agent is simultaneously influenced by the force of attraction and repulsion between each neighboring agents in cooperative and antagonistic layers. A distributed algorithm for achieving the consensus in a probabilistic sense is proposed and its sufficient conditions are clarified. The conditions tell us rigorous stopping rules which enable us to know the number of iterations that achieves consensus within a prespecified accuracy and probability. Some applications of consensus problems with cooperative and antagonistic interactions are shown through numerical examples.     

Low‐frequency sound absorption of organic hybrid comprised of chlorinated polyethylene and N,N′‐dicyclohexyl‐2‐benzothiazolyl sulfenamide

We investigated the sound absorption characteristics of an organic hybrid material comprised of chlorinated polyethylene (CPE) as the matrix polymer and N,N′‐dicyclohexyl‐2‐benzothiazolyl sulfenamide (DBS) as the second component of an organic low‐molecular‐weight compound. We found specific crystallites, obtained by annealing, that generated new absorption for a low‐frequency sound in a CPE/DBS blend. We observed two sound absorption peaks, around 300 and 1000 Hz, in the annealed CPE/DBS (50 : 50 w/w) blends, whereas those peaks were not observed in the untreated sample. There were two kinds of crystals with different melting points in the annealed samples. It was confirmed that the crystals with the lower melting point brought about sound absorption at a low frequency. The crystals that had the lower melting point were smaller and/or more disordered than the crystals that had the higher melting point. We calculated the fraction of these two types of crystals from differential scanning calorimetry and wide‐angle X‐ray diffraction measurements. The annealing or reannealing temperature specified the fraction of the crystal with the lower melting point, and the obtained crystal fraction characterized sound absorption frequency. Therefore, it is possible to control the sound absorption frequency of an organic hybrid by heat treatment such as annealing. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

Removal of fluoride ions from aqueous solution at low pH using schwertmannite

Wastewater containing fluoride requires polishing after precipitation/coagulation treatment in order to meet stringent environmental legislation. Accordingly, adsorption characteristics of fluoride onto schwertmannite adsorbent were studied in a batch system with respect to changes in initial concentration of fluoride, equilibrium pH of sample solution, adsorbent dosage and co-existing ions. Equilibrium adsorption data were obtained at 295.6, 303 and 313 K, and are interpreted in terms of two-site Langmuir, Freundlich, Langmuir-Freundlich, Redlich-Peterson, Tóth and Dubinin-Radushkevitch isotherm models. The experimental and equilibrium modeling results revealed that the capacity of schwertmannite for fluoride is high but insensitive to changes in solution temperature. An increase in equilibrium pH of sample solution reduced significantly the fluoride removal efficiency. In binary component systems, inner-sphere complex forming species had negative effects on fluoride adsorption while outer-sphere complex forming species improved slightly the fluoride removal efficiency. The schwertmannite adsorbent was regenerable and had the ability to lower the fluoride concentration to acceptable levels.     

One-step direct assay for mature-type adrenomedullin with monoclonal antibodies

Adrenomedullin (AM) is a potent hypotensive peptide. Plasma contains mature-type AM (m-AM), which is amidated at the carboxy terminus, and an intermediate, AM-Gly. We developed a one-step two-site IRMA specific for determining human m-AM with monoclonal antibodies. The detection limit was 0.5 pmol/L, and the working range (CV <15%) was 1-300 pmol/L. Dilution of plasma samples showed good linearity. The recovery of added AM was 91-118%. The intra- and interassay imprecision values (CVs) were 4.4-8.2% and 5.5-8.3%, respectively. The assay had no cross-reactivity with AM-Gly or other peptides similar to AM. The mean (+/- SD) plasma human m-AM concentration of 61 healthy subjects was 1.18 +/- 0.65 pmol/L. In conclusion, our IRMA makes it possible to specifically measure m-AM, using a small amount of plasma sample (0.2 mL) by a one-step overnight assay without prior extraction. Our simplified method would be suitable for clinical studies on AM, especially when large numbers of samples must be processed.     

Recent development and prospect of electromagnetic processing of materials

Application of electromagnetic force to materials processing, so called Electromagnetic Processing of Materials (EPM) has been recognized as a cutting edge technology, especially in the fields of advanced materials processing. The backgroundto promote EPMis described. The present state of EPMis given through a brief introduction of several examples of the applications of a high frequency magnetic field, a DC magnetic field, DC magnetic and electric fields, and a traveling magneticfield. Furthermore, a high static magnetic field has been applied to generate compression waves in molten metals. As otherexamples of the application of a high static field, the crystal orientations in thin films in vapordeposition and electrodeposition processes and those in carbon fibers in a graphitization process are described. Finally the future view of EPM is revealed.     

Advances in nature-guided materials processing

The center of excellence (COE) titled ‘The Creation of Nature-Guided Materials Processing’ has been established in Nagoya University as the 21st Century COE Program supported by Ministry of Education, Culture, Sports, Science and Technology. In the Nature COE, various activities on the education and research are being performed through learning the laws of nature, namely, methods of attaining ‘appearance of the maximum function under the minimum substance and energy consumption’, which the nature and living organisms have acquired through their evolution in long period. Together with such educational programs for PhD students as research incentive, oversea training, and external evaluation programs, an ‘Open-Cluster Program’ was originated for promoting researches proposed by research groups consisting of young researchers in and out of the university and also for fostering them.

The researches are being advanced on materials used for living bodies, mimicking structures which nature or living bodies are forming, and producing materials by mimicking processes to form the structures observed in the nature or the living bodies. In this COE, these researches are conducted by four groups to extend the processes observed in the natural world to a new type of processing, that is, thoroughly examined and rationalized by plunging a scalpel of engineering and to establish a new academic field of materials science and engineering.     

Application of optical sensor for arc welding

Summary

In CO₂ gas-shielded arc welding, spatter is scattered and adheres to the base metal surface. The main factors affecting any difference in the bonding force remain obscure. This paper examines the bonding force of spatter adhering to the surface of SS400 base metal (rolled steel sheets) under different temperature conditions in CO₂ gas-shielded arc welding using 1.2 mm dia. solid wire. The following four types of base metal surface condition were adopted:

Type 1: As-received surface covered with an oxide film;

Type 2: Ground surface machined with a plain grinder (R_max = 0.6 μm);

Type 3: Surface with fume adhering to the ground surface;

Type 4: Free-ground surface machined with a disc grinder (R_max = 7–16 μm).

The base metal was heated by a 14 mm dia. x 600 mm ceramic heater arranged on the back of the base metal. The bonding force was measured as the shearing force of the spatter. Some 400 spatter particles on each surface were examined. The particles mostly have diameters ranging between 0.4–1.4 mm.

At a base metal temperature below around 450 K, the spatter on the scaled surface is insufficiently hot to melt the base metal and cannot adhere by melting the base metal surface. The shear stress is mostly below around 40 MPa. Despite a rising base metal temperature, however, spatter removal is still possible at less than 300 MPa.

Fume on the surface or the surface roughness do not affect the bonding force as directly as scale on the surface. The temperature, however, affects the bonding force. At a base metal temperature below around 450 K, the bonding force is slightly smaller.

When spatter adheres to the surface, heat causes the microstructure to change with corresponding hardening. The spatter and HAZ of the base metal here show a slightly higher Vickers hardness value (some spatter particles having HV470) than the base metal hardness (HV156–165), although this depends on the surface conditions and temperature.     

Real-time investigation of crystallization in poly(vinylidene fluoride)-based nano-composites probed by infrared spectroscopy

Via time-resolved Fourier transform infrared spectroscopy (FTIR), we examined the real-time investigation of the conformational changes of poly(vinylidene fluoride) (PVDF) chain segment during crystallization of neat PVDF and the corresponding nano-composites having intercalated structure. It was shown that in the following crystallization processes the crystal growth was virtually the same in both nano-composites and neat PVDF. We have examined an annealing at an infinitely long time at 200 °C (∼20 min) to erase the thermal history in the nano-composites. The dispersed titanate nano-filler particles exhibited strong contribution to enhance the heterogeneous nucleation for the formation of both γ- and β-phase crystals.