对二甲苯直接电解氧化反应的研究

研究了在有机溶剂、支持电解质和碳棒存在下，对二甲苯的直接电解氧化反应，使用GC－MS方法分析鉴定了主要电解氧化产物，讨论了电解氧化产物成分随电解时间的变化规律，提出了对二甲苯的直接电解氧化反应过程。     

Electrically conductive composite of polypyrrole and liquid crystalline copoly(ester-amide)s

The modification of the mechanical properties of polypyrrole (PPY) by electrochemical preparation of conductive composite film from pyrrole (PY) and three kinds of liquid crystalline copoly(ester-amide)—PEA(H), PEA(C), PEA(O)—are presented. The electrical conductivity of the PEA(H)/PPY, PEA(C)/PPY, and PEA(O)/PPY composites are the same order of magnitude as PPY. The mechanical properties of the composite films are much better than that of pure PPY, and the composite films have good conductivity and thermostability. © 1994 John Wiley & Sons, Inc.     

成果导向背景下二级教学质量监控的责权划分研究

围绕当前高校内部校级教学质量监控规模过大导致的校级督导工作难以满足学校发展要求这一难题，本文通过引入成果导向理念，厘清学校与院系的教学质量管理权责范围，提出了二级教学质量监控权利分配策略，实现了校院两级教学质量监控的有效衔接，改变了“原地踏步式”的教学质量监控现状。     

聚合条件对合成聚1-丁烯热塑性弹性体的影响

以1-丁烯(B t)为原料,负载钛(简称Ti)-三异丁基铝(简称Al)为催化体系,用本体聚合法合成了聚1-丁烯(PBt)热塑性弹性体(TPE)。考察了聚合条件对PBt TPE的影响,并用差示扫描量热法对聚合物进行了分析。结果表明,随着氢气压力的升高,单体转化率、催化效率呈下降趋势;随着Al/Ti(摩尔比)的增加,转化率和催化效率先升高后降低;随着Ti/Bt(摩尔比)的增加,转化率和催化效率逐渐升高;随着聚合温度的升高,转化率和催化效率先升高后降低;在氢气压力为0.2 MPa、Al/Ti为300、Ti/Bt为2×10-5、反应温度为30℃的聚合条件下,合成出转化率为80.0%的PBt TPE。随着氢气压力的升高,聚合物的特性黏数([η])和全同立构质量分数都呈下降趋势,氢气压力能较好地调节聚合物的相对分子质量;随着Al/Ti的增加,[η]逐渐下降,全同立构质量分数变化不明显;随着Ti/Bt的增加,[η]先升高后降低,最后趋于平稳,而全同立构质量分数略有降低后趋于平稳;随着聚合温度的升高,[η]和全同立构质量分数都呈下降趋势。反应温度为40℃时,PBt TPE的结晶度最高,为20.3%。     

总体模型动态灯光设计与集成

本文以某大型石化企业总体模型设计制作为例，阐述了总体模型动态灯光设计、集成和系统调试，操作及日常管理。     

十二烷基苯磺酸钠水溶液聚集性质的研究

用滴体积法测出十二烷基苯磺酸钠（ＳＤＢＳ）稀水溶液的表面张力；然后求出其临界胶束浓度（ＣＭＣ）。同时通过溶液的电导率、吸收光谱以及荧光光谱测定求出其ＣＭＣ。这样测出的ＣＭＣ值为１．２～１．６×１０－３ｍｏｌ／Ｌ，与文献值相符。也研究了部分水解的聚丙烯酰胺（ＰＨＰＡＭ）对ＳＤＢＳ聚集性质的影响；发现ＳＤＢＳ的ＣＭＣ值随ＰＨＰＡＭ的加人而减少并且ＰＨＰＡＭ水溶液的粘度随ＳＤＢＳ的存在而急剧降低（类似盐效应）。这些方法与性质对强化采油（ＥＯＲ）是重要的。     

基于ECSS平台的板式换热器计算软件

以"面向对象的通用化工流程模拟软件ECSS"为平台,在其原来模块计算父类基础上设计了板式换热器模块计算子类,做出了板式换热器计算的数学模型,开发出了基于ECSS平台的板式换热器计算软件.可以对板片形式为等边三角形波纹板、不等边三角形波纹板、带褶三角形波纹板和不带褶三角形波纹板,流体的流道形式为1/1、1/2、1/3、1/4、2/2、3/3、4/4等流形的板式换热器进行计算.通过实例表明该软件具有较高的精确度,可以应用于实际的工程计算中.     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

高校网络安全问题及对策研究

近些年,在高校校园数字化建设的逐步推进下,信息化建设取得了前所未有的进步,与此同时,高校的网络安全问题也变得日益突出。如何更好的保证高校网络安全运行,保障高校的基本网络需求,已经成为了当前高校网络研究和建设中需要重点关注的问题。为此,本文中笔者将结合自身的经验对高校校园网络的特点进行分析,从而得到其中存在的主要问题,并对提高高校网络安全的对策进行了一些阐述,以期能够更好地促进高校网络安全的发展和进步,为业内的其他研究提供借鉴和参考。     

Structure and properties of collagen‐konjac glucomannan‐sodium alginate blend films

A new kind of blend film was made by mixing the solutions of collagen, konjac glucommnnan (KGM), and sodium alginate. The structure of the blend film was characterized by FTIR, XRD, atomic absorption spectrophotometer, and SEM, respectively. The effects of weight ratio between the polymers on light transmittance, tensile strength, elongation at break, water permeability, and water absorption of the film were studied. The results showed that there were strong interactions and good compatibility between collagen, KGM, and sodium alginate in the film. The film possesses good mechanical properties. Therefore, it can be applied in biomedicine as a new type of biomaterial. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007