Remediation of groundwater contaminated with MTBE and benzene: the potential of vertical-flow soil filter systems

Field investigations on the treatment of MTBE and benzene from contaminated groundwater in pilot or full-scale constructed wetlands are lacking hugely. The aim of this study was to develop a biological treatment technology that can be operated in an economic, reliable and robust mode over a long period of time. Two pilot-scale vertical-flow soil filter eco-technologies, a roughing filter (RF) and a polishing filter (PF) with plants (willows), were operated independently in a single-stage configuration and coupled together in a multi-stage (RF + PF) configuration to investigate the MTBE and benzene removal performances. Both filters were loaded with groundwater from a refinery site contaminated with MTBE and benzene as the main contaminants, with a mean concentration of 2970 ± 816 and 13,966 ± 1998 μg L⁻¹, respectively. Four different hydraulic loading rates (HLRs) with a stepwise increment of 60, 120, 240 and 480 L m⁻² d⁻¹ were applied over a period of 388 days in the single-stage operation. At the highest HLR of 480 L m⁻² d⁻¹, the mean concentrations of MTBE and benzene were found to be 550 ± 133 and 65 ± 123 μg L⁻¹ in the effluent of the RF. In the effluent of the PF system, respective mean MTBE and benzene concentrations of 49 ± 77 and 0.5 ± 0.2 μg L⁻¹ were obtained, which were well below the relevant MTBE and benzene limit values of 200 and 1 μg L⁻¹ for drinking water quality. But a dynamic fluctuation in the effluent MTBE concentration showed a lack of stability in regards to the increase in the measured values by nearly 10%, which were higher than the limit value. Therefore, both (RF + PF) filters were combined in a multi-stage configuration and the combined system proved to be more stable and effective with a highly efficient reduction of the MTBE and benzene concentrations in the effluent. Nearly 70% of MTBE and 98% of benzene were eliminated from the influent groundwater by the first vertical filter (RF) and the remaining amount was almost completely diminished (∼100% reduction) after passing through the second filter (PF), with a mean MTBE and benzene concentration of 5 ± 10 and 0.6 ± 0.2 μg L⁻¹ in the final effluent. The emission rate of volatile organic compounds mass into the air from the systems was less than 1% of the inflow mass loading rate. The results obtained in this study not only demonstrate the feasibility of vertical-flow soil filter systems for treating groundwater contaminated with MTBE and benzene, but can also be considered a major step forward towards their application under full-scale conditions for commercial purposes in the oil and gas industries.     

指标的抉择:概念、方法与应用

本文概述了指标的发展历程,着重介绍了英固城市与区域规划背景下指标的发展情况,并为未来的指标研究和深入发展提供了线索.本文的观点和建议是对经济与社会研究理事会(ESRC:Economic and Social Research Council)所资助的一项研究项目成果的阐释,该研究项目旨在识别出用于衡量地方经济发展潜力的指标,以及用于建立一个城镇指标数据库的方法,这一数据库用来帮助副首相办公室(ODPM:the Office of Deputy Prime Minister)监测城市白皮书(Urban White Paper)执行的力度.文章讨论的内容主要围绕五大问题:城市与区域规划评价指标发展的理论、概念与度量之间的关系;政策背景的重要性与指标研究的价值;社会科学家在指标演化过程中所扮演的角色;指标在为政策制定以及数据建设提供信息上的作用;最后综合评价了不同分析方法的优缺点.     

Effect of a crack on strength of fibre-reinforced plastics

In unidirectionally reinforced composites with an elastic-plastic matrix, there is a plastic zone with lengthY ₀ proportional to the crack lengthC (Y ₀ C) at the tip of a crack. This results in a new logarithmic dependence of glass and aramid PABI fibre-reinforced plastics (FRP) on crack length and non-fulfilment of the Griffith criterion. In glass and PABI FRP without an artificial notch, defects already exist equivalent to a crack with a length depending on composite fabrication practice. In GFRP, the epoxy matrix shear yield stress grows 2.0 to 2.5 times, compared to the yield in thin films due to fibre constraint of matrix yielding. The stress distribution in front of a crack in a highly anisotropic composite with an elastic-plastic matrix is derived. The stress concentration at the tip of a crack grows with increasing matrix yield stress, resulting in a change of failure mode from accumulation of fibre breaks at low matrix strength, to brittle failure at high matrix strength. The following factors lead to composite embrittlement: (1) increase of matrix yield stress and composite shear strength; (2) decrease of temperature; (3) increase of Young's modulus of the fibre; (4) reduction of fibre strength. The dependence of aramid PPTA FRP strength on temperature exhibits a maximum. Epoxy matrix plastification leads to some increase of aramid PPTA FRP strength.