Chloroform-extractable material from bituminous coals

Material soluble in chloroform has been extracted from bright bituminous coals of two different ranks

1. (1) following preheating to the temperatures of maximal plasticity;

2. (2) after treatment with sodium in liquid ammonia;

3. (3) by fractionating the pyridine extracts;

4. (4) after preliminary acetylation with acetic anhydride in the presence of pyridine.

The extracts were characterized by elemental analysis, average molecular weights, and n.m.r. and i.r. spectroscopy. The spectroscopic data afforded quantitative information on the distribution of hydrogen between various structural groups and some statistically averaged structural parameters. The results are discussed with regard to the mechanism of formation of the chloroform-extractable material during the various preliminary treatments of the coals.     

Special Issue on Deep Learning for Robotic Vision

International Journal of Computer Vision -     

Heavy metals (Pb,Cu, Zn and Cd) in the system soil – grapevine – grape

An Erratum has been published for this article in Journal of the Science of Food and Agriculture 79(15)1999, 2122. The investigation was carried out in the period 1991–1995 in a region with a major industrial pollutant, the Non‐Ferrous‐Metal Works, and a region with no industrial pollutants (as a control). The heavy metal content in soil, roots, annual shoots and perennial parts of grapevine, leaves, grapes and wine, was determined. Soil samples and roots of the rootstock Kober 5BB were taken at 10 cm intervals from depths of 0–100 cm. Roots were divided by thickness in fractions at 1 mm intervals. The shoots, bark, vascular tissue, wood, core and diaphragm were investigated. The leaf analyses included leaf blade and leaf petioles, and those of grapes, berry‐free raceme (washed in a lot of water and unwashed). Berries were analysed (the berry skin, the pulp and the seeds). The results obtained for the Pb, Cu, Zn and Cd contents in the grapevine roots show that they depend significantly both on their amounts in the soil and the age of the roots. The main parts of the heavy metal amounts taken by the roots of the grapevine from the soil are fixed and accumulated in the young feed rootlets (with diameters of 1 mm), and small amounts of them move through the conducting system to the older, larger diameter root system. The experimental data obtained for the presence of Pb, Cu, Zn and Cd in the separate tissues and organs of grapevines grown in an industrially polluted region showed that their amounts were mainly due to the heavy‐metal‐containing aerosols falling from the atmosphere. Part of them, however, got into the soil, and from there, even if in minimal amounts, penetrated via the root system into the grapevine plants and accumulated into their different overground parts. © 1999 Society of Chemical Industry     

Self-assembled multicompartment liquid crystalline lipid carriers for protein, peptide, and nucleic acid drug delivery

Lipids and lipopolymers self-assembled into biocompatible nano- and mesostructured functional materials offer many potential applications in medicine and diagnostics. In this Account, we demonstrate how high-resolution structural investigations of bicontinuous cubic templates made from lyotropic thermosensitive liquid-crystalline (LC) materials have initiated the development of innovative lipidopolymeric self-assembled nanocarriers. Such structures have tunable nanochannel sizes, morphologies, and hierarchical inner organizations and provide potential vehicles for the predictable loading and release of therapeutic proteins, peptides, or nucleic acids. This Account shows that structural studies of swelling of bicontinuous cubic lipid/water phases are essential for overcoming the nanoscale constraints for encapsulation of large therapeutic molecules in multicompartment lipid carriers. For the systems described here, we have employed time-resolved small-angle X-ray scattering (SAXS) and high-resolution freeze-fracture electronic microscopy (FF-EM) to study the morphology and the dynamic topological transitions of these nanostructured multicomponent amphiphilic assemblies. Quasi-elastic light scattering and circular dichroism spectroscopy can provide additional information at the nanoscale about the behavior of lipid/protein self-assemblies under conditions that approximate physiological hydration. We wanted to generalize these findings to control the stability and the hydration of the water nanochannels in liquid-crystalline lipid nanovehicles and confine therapeutic biomolecules within these structures. Therefore we analyzed the influence of amphiphilic and soluble additives (e.g. poly(ethylene glycol)monooleate (MO-PEG), octyl glucoside (OG), proteins) on the nanochannels' size in a diamond (D)-type bicontinuous cubic phase of the lipid glycerol monooleate (MO). At body temperature, we can stabilize long-living swollen states, corresponding to a diamond cubic phase with large water channels. Time-resolved X-ray diffraction (XRD) scans allowed us to detect metastable intermediate and coexisting structures and monitor the temperature-induced phase sequences of mixed systems containing glycerol monooleate, a soluble protein macromolecule, and an interfacial curvature modulating agent. These observed states correspond to the stages of the growth of the nanofluidic channel network. With the application of a thermal stimulus, the system becomes progressively more ordered into a double-diamond cubic lattice formed by a bicontinuous lipid membrane. High-resolution freeze-fracture electronic microscopy indicates that nanodomains are induced by the inclusion of proteins into nanopockets of the supramolecular cubosomic assemblies. These results contribute to the understanding of the structure and dynamics of functionalized self-assembled lipid nanosystems during stimuli-triggered LC phase transformations.     

The Challenge of Wall–Plasma Interaction with Pulsed Megagauss Magnetic Fields

A method is described for choosing experimental parameters in studies of high-energy-density (HED) physics relevant to fusion energy, as well as other applications. An important HED issue for magneto-inertial fusion (MIF) is the interaction of metal pusher materials with megagauss (MG) magnetic fields during liner compression of magnetic flux and fusion fuel. The experimental approach described here is to study a stationary conductor when a pulsed current generates MG fields at the surface, instead of studying the inner surface of a moving liner. This places less demand upon the pulsed power system, and significantly improves diagnostic access. Thus the deceptively simple geometry chosen for this work is that of a z pinch composed of a metal cylinder carrying large current. Consideration of well known stability issues for the z pinch shows that for given peak current and rise time from a particular power supply, there is a minimum radius and thus maximum B field that can be created without disruption of the conductor before peak current. The reasons are reviewed why MG levels of magnetic field, as required for MIF, result in high temperatures and plasma formation at the surface of the metal in response to Ohmic heating. The distinction is noted between the liner regime obtained with cylindrical rods, which have a skin depth small compared to the conductor radius, and the exploding thin-wire regime, which has skin depth larger than the wire radius. A means of diagnostic development is described using a small facility (DPM15) built at the University of Nevada, Reno. It is argued that surface plasma temperature measurements in the 10-eV range are feasible based on the intensity of visible light emission.     

Chemical depolymerization of oil shale

The chemical structure of the organic matter from Krassava oil shale has been investigated by means of chemical degradation with metallic sodium in liquid ammonia and with phenol in the presence p-toluenesulphonic acid. The former reaction yielded 20 wt% of pyridine-soluble material and the latter ≈ 65 wt%. Extensive depolymerization of the oil shale was achieved by a combination of both methods in which case the solubility of the organic matter was increased to 85–95 wt%. The characterization of soluble and insoluble products by pyrolysis g.c. and elemental analysis indicated that aliphatic chains were prevalent in the organic matter of the Krassava oil shale.     

Numerical investigation of the heat transfer through woven textiles by the jet system theory

The paper presents a numerical study on the heat transfer in through-thickness direction of single woven layers, based on the jet system theory. A mathematical model, involving the Reynolds-Averaged Navier-Stokes partial differential equations is used, and two turbulence models (k ? ? and RSM) are applied to solve the closure problem. Numerical results for the temperature distribution, heat rate, heat flux and thermal resistance of the samples are obtained, analyzed, and validated by experimental data. The presented approach for modeling the heat transfer through woven macrostructures is concluded to be a working numerical tool that has the potential to replace costly design iterations and experiments to produce woven textiles with desired performance.