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101.
102.
J. Edward Hunter 《Journal of the American Oil Chemists' Society》1981,58(3):283-287
A major objective of commercial processing of soybean oil into edible products is to remove unwanted impurities from the oil
with the least possible effect on nutritional quality of the oil. Soybean oil is an excellent dietary source of essential
linoleic acid and also of tocopherols, which serve as sources of vitamin E and natural antioxidants. The data presented in
this report indicate that the nutritional quality of soybean oil is largely retained after typical commercial processing conditions.
Hydrogenation does reduce the level of essential fatty acids; however, typical commercial salad and cooking oils and shortenings
made from partially hydrogenated soybean oil retain nutritionally significant levels of essential fatty acids. Tocopherols
also are present at high levels in the finished oil. Among the unwanted components of crude soybean oil which are effectively
removed by processing are pesticide residues, phosphatides, free fatty acids, color pigments, and compounds causing objectionable
odors and flavors. 相似文献
103.
Theerythro andthreo isomers of methyl 9,10-dihydroxyoctadecanoate and thethreo isomer of methyl 12,13-dihydroxy-cis-9-octadecenoate were converted into methylcis- andtrans-9-octadecenoate and methylcis-9,rans-12-octadecadienoate, respectively, by reaction of the dihydroxy ester with triethyl orthoformate to give the 2-ethoxy-1,3-dioxolane
which was thermally decomposed to the unsaturated ester. 相似文献
104.
Summary Cholesterol is a universal constituent of all animal cells and therefore occurs in all foods of animal origin. Cholesterol
is the mother substance of bile acid and of sex hormones and has other important physiological roles. Cholesterol is synthesized
in the body from acetate obtainable from ingested carbohydrate, fat. or protein, of animal or vegetable origin.
The fate of cholesterol in the body has not been definitely established. The cause of atherosclerosis is unknown. Atherosclerosis
occurs in young as well as old individuals. Atherosclerosis is the number-one killer today.
Diagnosis of atherosclerosis in the healthy individual is not possible. Treatment of atherosclerosis is empirical. Reduction
of blood cholesterol levels by dietary means is difficult under conditions consonant with good nutrition. A well-balanced
intake of all available foods on a modified total caloric basis appears to be the practical approach to the problem of fat,
cholesterol, and atherosclerosis.
Presented at the 47th Annual, Meeting, American Oil Chemists’ Society, Houston, Tex., April 23–25, 1956. 相似文献
105.
This paper presents a simplified method for the chemical synthesis of cholest-4-en-3-one, which is a naturally occurring steroid
and a salient intermediate in steroid chemistry. Pyridinium chlorochromate (PCC) in refluxing benzene has been found to be
an effective and convenient reagent for the oxidation and concomitant isomerization of cholest-5-en-3β-ol (cholesterol) to
cholest-4-en-3-one in high yield. Also described are the carbon-13 nuclear magnetic resonance spectral properties of cholest-4-en-3-one
and of the isolated reaction intermediate cholest-5-en-3-one.
Based on a paper presented at the Symposium on Plant and Fungal Sterols: Biosynthesis Metabolism and function held at the
AOCS Annual Meeting, Baltimore, MD, April 1990. 相似文献
106.
Edward J. Rode Paul E. Gee Linda N. Marquez Tetsuji Uemura Mohammad Bazargani 《Catalysis Letters》1991,9(1-2):103-113
Alkali metal zeolites and metal oxides were used for the aldol condensation of n-butanal to 2-ethyl-2-hexenal. The order of activity at 150 °C and 1 atm. was: CsNaY > NaY > LiNaY > MgO >Al2O3. Selectivity to 2-ethyl-2-hexenal was 100% for both pure and mixed isomer feed. Infrared spectroscopic studies showed that stable catalysts were produced by propene pretreatments which blocked Lewis acid sites. Adsorption of ammonia and carbon dioxide on CsNaY during aldol condensation of n-butanal causes a decrease in rate. This result, along with the order of activity, suggests that the presence of both acid and basic sites produce higher activity than strongly basic MgO.Work performed at San Jose State University. 相似文献
107.
时尚是有规律的.它不是以进步的形式运动,而是在循环中运动.外在的一致性通常会破坏内在的一致性.本文就时尚的规律、时尚的产生与运动过程、时尚与限制性规则、现代时尚的新变革等方面展开讨论. 相似文献
108.
John W. Drazin James A. Wollmershauser Heonjune Ryou Mason A. Wolak Edward P. Gorzkowski 《Journal of the American Ceramic Society》2020,103(1):60-69
Pressureless sintering approaches provide a simple avenue to manufacture dense ceramic parts with minimal processing equipment, but current pressureless sintering techniques have yet to demonstrate capabilities of producing dense ceramics while maintaining sub-50 nm grain sizes. Nanocrystalline yttria stablized zirconia ceramics were process from 4 mol% yttria stablized zirconia (4YSZ) nanopowders with a crystallite size of 7.5 nm using dry cold isostatic pressing (CIP) where powders are dried immediately prior to green compact formation and CIP vacuum bagging. It is shown that CIP pressures >75 000 psi (517 MPa) effectively remove pores larger than 100 nm and that pressureless sintering occurs at reduced temperatures for green densities ≥50%. Though the sintering kinetics are shown to be similar to other zirconia nanopowder sintering studies, the small initial crystallize size and reduced sintering temperature allowed densities as high as 97.2%, while retaining a ceramic grain size at or below 40 nm. Produced nanocrystalline 4YSZ ceramics with a grain size of 30.3 nm and a density of 96.3% had Vicker's hardnesses as high as 14.2 GPa and Vicker's indentation fracture resistance of 3.43 MPa·, demonstrating that simple processing approaches can be refined to fabricate nanocrystalline ceramics while maintaining high hardness and indentation fracture resistance. 相似文献
109.
Daniel Caurant Odile Majérus Edward Fadel Marion Lenoir Christel Gervais Olivier Pinet 《Journal of the American Ceramic Society》2007,90(3):774-783
Crystallization of the poorly durable Na2 MoO4 phase able to incorporate radioactive cesium must be avoided in SiO2 –Al2 O3 –B2 O3 –Na2 O–CaO glasses developed for the immobilization of Mo-rich nuclear wastes. Increasing amounts of B2 O3 and MoO3 were added to a SiO2 –Na2 O–CaO glass, and crystallization tendency was studied. Na2 MoO4 crystallization tendency decreased with the increase of B2 O3 concentration whereas the tendency of CaMoO4 to crystallize increased due to preferential charge compensation of BO4 − entities by Na+ ions. 29 Si MAS NMR showed that molybdenum acts as a reticulating agent in glass structure. Trivalent actinides surrogate (Nd3+ ) were shown to enter into CaMoO4 crystals formed in glasses. 相似文献
110.
Walter J. Thomas Mohamed A. El-Sawy Edward W. Palmer 《Chemical Engineering Communications》1982,16(1):53-78
Two published theoretical models are examined and applied to experimental results for absorption and desorption. The system used was CO2/H2O and studies were made for liquid film flow down inclined planes. Experimental results give “Reduced” values of mass ransfer rates.
Interferometric studies give interfacial concentration, penetration and film depths, and take-up of carbon dioxide. In the case of desorption the interferograms are distorted by “deflections.”
All the experimental values for absorption and desorption differ from those calculated from theoretical models.
Desorption is not a mirror image of absorption, and it is approximately 75% of the transfer rate of absorption over a wide operating range.
A comparison is made of the behaviour of static pools and flowing liquid films. 相似文献
Interferometric studies give interfacial concentration, penetration and film depths, and take-up of carbon dioxide. In the case of desorption the interferograms are distorted by “deflections.”
All the experimental values for absorption and desorption differ from those calculated from theoretical models.
Desorption is not a mirror image of absorption, and it is approximately 75% of the transfer rate of absorption over a wide operating range.
A comparison is made of the behaviour of static pools and flowing liquid films. 相似文献