Association and physical gelation of ABA triblock copolymer in selective solvent

Association behavior and physical gelation mechanism of ABA triblock copolymer dissolved in B-selective solvent have been studied systematically from dilute to moderately concentrated solutions. Static and dynamic light scattering and nuclear magnetic resonance measurements for dilute solutions of poly(methyl methacrylate)-block-poly(tert-butyl acrylate)-block-poly(methyl methacrylate) (PMMA-PtBuA-PMMA) in 1-butanol (PtBuA selective solvent) indicated that PMMA-PtBuA-PMMA chains are molecularly dissolved above 50 °C. With decreasing temperature, the triblock copolymers form associated micelles consisting PMMA associated core and PtBuA shell. Linear dynamic viscoelastic measurements for solutions with moderate concentration (3.9-12.0 wt%) revealed that the system was viscous sol state at 60 °C. Drastic increase of shear storage modulus (G′) occurred with decreasing temperature, and at 25 °C, G′ showed rubbery plateau with weak frequency dependency, means the formation of elastic physical gel. The consistency between the temperature for micelle formation and that at the increase in G′ indicates that the physical gelation is owing to the network formation as the result of the association of PMMA chains and the bridging PtBuA chains connecting the PMMA cores. Master curves for the dynamic moduli were derived by time-temperature superposition along the frequency axis. Just above sol-gel transition concentration (C_gel), the master curves suggest the existence of fairy amount of aggregate that is not incorporated in the macroscopic network. With the increase in polymer concentration, the master curves become to reveal Maxwell-type viscoelasticity with narrow relaxation time distribution, suggesting the formation of transient network with easily generation and destruction of crosslinks. Concentration dependency of the plateau modulus is stronger than the theoretically expected, means the macroscopic transient network grows with polymer concentration by increasing the fraction of elastically effective bridging PtBuA chain above C_gel.     

Large, huge or gigantic? Identifying and encoding intensity relations among adjectives in WordNet

We propose a new semantic relation for gradable adjectives in WordNet, which enriches the present, vague, similar relation with information on the degree or intensity with which different adjectives express a shared attribute. Using lexical-semantic patterns, we mine the Web for evidence of the relative strength of adjectives like “large”, “huge” and “gigantic” with respect to their attribute (“size”). The pairwise orderings we derive allow us to construct scales on which the adjectives are located. To represent the intensity relation among gradable adjectives in WordNet, we combine ordered scales with the current WordNet dumbbells based on the relation between a pair of central adjectives and a group of undifferentiated semantically similar adjectives. A new intensity relation links the adjectives in the dumbbells and their concurrent representation on scales. Besides capturing the semantics of gradable adjectives in a way that is both intuitively clear as well as consistent with corpus data, the introduction of an intensity relation would potentially result in several specific benefits for NLP.     

Human brain disturbance by methylmercury poisoning, focusing on the long-term effect on brain weight

The long-term effects of the initial methylmercury exposure in the Minamata area were examined, with focus on brain weight. Comparisons were made between the brain weights of methylmercury-contaminated persons in the Minamata area (cases) and those of Japanese who suffered sudden or accidental death without brain disease (controls). Since over thirty years have passed since the outbreak of Minamata disease, subjects aged 30 or over at death were included in the analysis. The total number of cases was 417 (273 males, 144 females) and that of controls was 2,934 (2,174 males, 760 females). The data suggest that the brain weights from Minamata cases were reduced by 80 to 200g as compared to the controls. These results may indicate that methylmercury exposure led to a decrease of nerve cells (single cell necrosis), so-called "thinning out", in the brain cortex.     

Thermodynamics of calcium and oxygen in molten titanium and titanium-aluminum alloy

The deoxidation equilibrium of molten titanium and titanium-aluminum alloys saturated with solid CaO has been measured in the temperature range from 1823 to 2023 K. The equilibrium constant of reaction CaO (s)=Ca (mass pct in Ti,Ti-Al)+O (mass pct in Ti,Ti-Al) and the interaction parameter between calcium and oxygen were determined for Ti, TiAl, and TiAl₃. The standard Gibbs energy of reaction for TiAl was obtained as follows: $$\Delta G^\circ = 279,000 - 103TJ/mol$$ The possibilities for the deoxidation of titanium and titanium-aluminum alloys by using calcium-based fluxes are discussed.     

A control method with pheromone information for a transport system

Since the control methods of a transport system between processing machines are specialized for each layout of the system, it is difficult to design prompt schedules and control logic for new complicated systems, especially in cases of machine faults or restructuring the system to modify the layout. In this article, we describe a multiagent transport control system which utilizes pheromone information. Each element of the system acts as an agent and estimates the appropriate path and time to drive out the products using information obtained by communication with other elements as well as pheromone information deposited on the tracks of the products.     

Navigation system for an autonomous robot using an ocellus camera in an indoor environment

Autonomous and mobile robots are being expected to provide various services in human living environments. However, many problems remain to be solved in the development of autonomous robots that can work like humans. When a robot moves, it is important that it be able to have self-localization abilities and recognize obstacles. For a human, the present location can be correctly checked through a comparison between memorized information assuming, it is correct, and the present situation. In addition, the distance to an object and the perception of its size can be estimated by a sense of distance based on memory or experience. Therefore, the environment for robotic activity assumed in this study was a finite-space such as a family room, an office, or a hospital room. Because an accurate estimation of position is important to the success of a robot, we have developed a navigation system with self-localization ability which uses only a CCD camera that can detect whether the robot is moving accurately in a room or corridor. This article describes how this system has been implemented and tested with our developed robot.     

Detection of environmental changes from network structure

We studied the networks of the temperature record in the atmosphere. They are made by the strength of the synchronization, including the delay between temperatures at locations on Earth. We consider these locations as nodes, and we consider a pair of locations as a link if the synchronization between them is stronger than a threshold. The network is scale-free, which is thought to contribute to the stability of the climate. This work was presented in part at the 12th International Symposium on Artificial Life and Robotics, Oita, Japan, January 25–27, 2007     

A counterexample to a proposed dynamic programming algorithm for optimal bid construction in an auction-based fully distributed manufacturing system

The paper by Veeramani and Wang (Int J Adv Manuf Technol 28:541–550, 2006) published in this journal offers a general bid construction scheme for minimizing the job flow time in auction-based manufacturing control and claims the optimality of the procedure. The purpose of this note is to provide a small example, in which their proposed new method fails to produce an optimal solution. We also address efficient correct algorithms so as to protect the readers from mistakenly believing that their new procedure is a better way of computing solutions.     

Impact of Multimedia Traffic Characteristics on ATM Network Configuration

This paper proposes a new topological designmethod, named BXCQ, which optimizes logical networkconfiguration while guaranteeing Quality-of-Service(QoS) requirements for each service class in an ATMnetwork. The BXCQ method determines the optimum logicalnetwork topology associated with each service class soas to minimize network cost. In our previously proposedFull-Net architecture these different logical topologies can be suitably mapped at the sametime on the same ATM physical network by using theVirtual Channel Handler (VCH) to create differentlogical interconnection networks. The BXCQ method allows us to clarify the relations between multimediatraffic characteristics and desirable logical networkconfigurations in Full-Net. Evaluation results suggestthat a service class that is bursty, delay tolerant, and cell loss sensitive with small demandshould be supported by a loop-like topology. This studywill be useful for designing flexible and cost-effectivemultimedia networks that can also adapt to not-yet-known services.     

Feasibility of a 1,400 m Span Steel Cable-Stayed Bridge

This paper describes the feasibility of 1,400 m steel cable-stayed bridges from both structural and economic viewpoints. Because the weight of a steel girder strongly affects the total cost of the bridge, the writers present a procedure to obtain a minimum weight for a girder that ensures safety against static and dynamic instabilities. For static instability, elastoplastic, finite-displacement analysis under in-plane load and elastic, finite-displacement analysis under displacement-dependent wind load are conducted; for dynamic instability, multimodal flutter analysis is carried out. It is shown that static critical wind velocity of lateral torsional buckling governs the dimension of the girder. Finally, the writers briefly compare a cable-stayed bridge with suspension bridge alternatives.