The quantitative assessment of domino effects caused by overpressure. Part I. Probit models

Accidents caused by domino effect are among the more severe that took place in the chemical and process industry. However, a well established and widely accepted methodology for the quantitative assessment of domino accidents contribution to industrial risk is still missing. Hence, available data on damage to process equipment caused by blast waves were revised in the framework of quantitative risk analysis, aiming at the quantitative assessment of domino effects caused by overpressure. Specific probit models were derived for several categories of process equipment and were compared to other literature approaches for the prediction of probability of damage of equipment loaded by overpressure. The results evidence the importance of using equipment-specific models for the probability of damage and equipment-specific damage threshold values, rather than general equipment correlation, which may lead to errors up to 500%.     

The local spatial autocorrelation and the kernel method for identifying black zones. A comparative approach

This article aims to determine the location and the length of road sections characterized by a concentration of accidents (black zones). Two methods are compared: one based on a local decomposition of a global autocorrelation index, the other on kernel estimation. After explanation, both methods are applied and compared in terms of operational results, respective advantages and shortcomings, as well as underlying conceptual elements. The operationality of both methods is illustrated by an application to one Belgian road.     

O-Buffer based IFT watershed from markers for large medical datasets

The watershed transform from markers is a very popular image segmentation operator. The image foresting transform (IFT) watershed is a common method to compute the watershed transform from markers using a priority queue, but which can consume too much memory when applied to three-dimensional medical datasets. This is a considerable limitation on the applicability of the IFT watershed, as the size of medical datasets keeps increasing at a faster pace than physical memory technologies develop. This paper presents the O-IFT watershed, a new type of IFT watershed based on the O-Buffer framework, and introduces an efficient data representation which considerably reduces the memory consumption of the algorithm. In addition, this paper introduces the O-Buckets, a new implementation of the priority queue which further reduces the memory consumption of the algorithm. The new O-IFT watershed with O-Buckets allows the application of the watershed transform from markers to large medical datasets.     

Numerical Modeling of Inclusion Removal in Electromagnetic Stirred Steel Billets

To investigate the inclusion removal in billets cast under electromagnetic stirring (EMS) influence, a numerical model has been developed to compute the magnetic field, the Lorentz force, the steel flow velocities, and the particle transport within the liquid pool. The electromagnetic field was described by the Maxwell equations and the finite element method was applied using a commercial package. The turbulent fluid flow was described by the Navier‐Stokes equation and by the Reynolds Stress model and the finite volume method was applied using another numerical package. The time average of the Lorentz force was calculated in each element center and this value was applied as a body force in the Navier‐Stokes equation. The magnetic flux density profile was compared with the data obtained in the stirrer of the steel plant. The particle transport model includes the drag force, the buoyancy force and the random walk model, to include the turbulence effects on the particle trajectory. The inclusion removal was calculated and analysed in function of casting speed and stirring current for one size section of mold. The inclusions considered in the calculations have a fixed density and four values of diameter. The numerical results of the electromagnetic model are in agreement with the experimental measurements. A good relationship between the electromagnetic model and the fluid flow model could be shown. An interesting effect is the break of the rotation motion due to the EMS by the jet from the nozzle. The fraction of inclusions removed by the top surface of the mold was improved due to the EMS.     

AFM characterization of the structure of Au-colloid monolayers and their chemical etching

Modification of a glass support with triethoxy propylaminosilane yields an active interface for the assembly of Au colloids. The colloids are imaged by AFM using a low applied load (0.5–0.7 nN). The lateral Au-colloid dimensions, 33±3 nm, deviate from the particle dimensions determined by TEM (19±2 nm) and absorption spectroscopy (15 nm). This deviation is attributed to the intrinsic curvature of the AFM tip. Application of higher loads on the tip (3 nN) results in the sweeping of Au colloids from the monolayer. The Au colloid monolayer is etched in the presence of CN⁻. The etching proceeds by the initial coincidental etching of Au particles followed by the kinetically favored etching of particles at the edges of the etched domains. This provides means for the micro machining and the chemical manipulation of Au colloids of controlled spatial arrangement.     

A Procedure for Evaluating the Compatibility of Surface Water Resources with Environmental and Human Requirements

This paper presents a novel and easy-to-use procedure for controlling and licensing water abstractions from a river based on establishing a balance between surface water resources and environmental and human requirements. Unlike other approaches relying on complex and detailed basin models, this is based simply on the use of the discharge duration curve to represent the available water resources. In particular, the scheme of analysis presented here is composed of four steps: 1) subdivision of a particular river reach into sub-reaches; 2) estimation of the availability of water along each sub-reach over a particular period of time by means of duration curves; 3) estimation of the environmental requirements (minimum instream flow—MIF) and quantities necessary for civil, agricultural and industrial uses over the same period, and 4) establishing a water balance model for each sub-reach, taking into consideration the effects produced by water resource use in the upstream sub-reaches. In particular, this procedure consents (a) quantification of the duration when abstractions are possible along each sub-reach, (b) quantification of the maximum abstraction needed to satisfy the volume requested (thereby enabling comparison with the amount the users can actually obtain through their structures and/or pumps) and (c) identification of situations in which users need to avail themselves of reservoirs for temporarily storing the water abstracted so that they do not exceed the availability on non-abstraction days. The procedure was successfully applied to a basin located in Emilia-Romagna, the Enza River, along which 9 sub-reaches were identified.