Effects of breed and age at slaughter on degradation of muscle lipids during processing of dry‐cured hams

Hams from Landrace, Duroc and Hampshire pigs slaughtered at ages 6, 7.5 and 9 months were processed to generate Norwegian Parma‐style hams. Lipid contents and the compositions of fatty acid classes (ΣSFA, ΣMUFA, ΣPUFA) within neutral lipids, phospholipids and free fatty acids were determined. Small differences in lipid degradation and composition of the classes were revealed. However, significant sensory differences related to lipids were observed. Breed was more important than age. Dry‐cured Hampshire hams gave a more intense mature odour that may be associated with higher overall lipid degradation. Unexpectedly, these hams also demonstrated high juiciness and tenderness, which could be related to the melting characteristics of the fat. Dry‐cured Duroc hams showed a higher susceptibility towards rancidity, presumably associated with preferential oxidation of n‐6 fatty acids relative to C18:1 n‐9. Dry‐cured Landrace hams showed the lowest juiciness and tenderness, likely due to their lower fat content (marbling).     

FLOCCULATION OF ASPHALTENES AT HIGH PRESSURE. II. CALCULATION OF THE ONSET OF FLOCCULATION

The influence of pressure on the onset of flocculation of asphaltenes was calculated in the region from 1 to 300 bar and from 50 to 100°C. These calculations are the counterpart to our experimental data which, recently, have been reported in part 1 of an equally titled article [9]. As gas component methane and as precipitant i-octane were used. The asphaltene flocculation was considered to be a liquid-liquid equilibrium. For modelling the van der Waals equation of state (vdW-EOS) in the framework of continuous thermodynamics was applied. The composition of the crude oil was described by a continuous distribution function with respect to the solubility parameter δ of the Scatchard-Hildebrand theory. Within the distribution the asphaltenes represent the species with the highest δ-values. For oils with a very low content of asphaltenes the model developed describes the experimental flocculation data reasonably. In accordance to the experimental data the model predicts that, in the considered pressure range, without addition of i-octane asphaltene flocculation does not occur. However, on contrary to the experimental results, the model predicts the asphaltenes to show a higher flocculation tendency with increasing asphaltene content of the crude oil. For very high asphaltene contents the model even completely fails. Probably, the reason of this lack is the disregarding of asphaltene association.     

Design and evaluation of an active electromechanical wheel suspension system

This paper presents an electromechanical wheel suspension, where the upper arm of the suspension has been provided with an electric levelling and a damper actuator, both are allowed to work in a fully active mode. A control structure for the proposed suspension is described. The complex design task involving the control of the electric damper and its machine parameters is tackled by genetic optimisation. During this process, these parameters are optimised to keep the power dissipation of the electric damper as low as possible, while maintaining acceptable comfort and road-holding capabilities. The results of the evaluations carried out demonstrate that the proposed suspension can easily adopt its control parameters to obtain a better compromise of performance than that offered by passive suspensions. If the vehicle is to maintain acceptable performance during severe driving conditions, the damper has to be unrealistically large. However, if the electric damper is combined with a hydraulic damper, the size of the electric damper is significantly reduced. In addition, the design of the electric damper with the suggested control structure, including how it regenerates energy, is discussed.     

Improved methods for evaluating the molar mass distributions of cellulose in kraft pulp

Multi‐angle laser light scattering (MALLS) was used to characterize birch kraft pulps with respect to their absolute molecular mass distributions (MMDs). The pulps were dissolved in lithium chloride/N,N‐dimethylacetamide and separated by size exclusion chromatography (SEC). The weight‐average and number‐average molecular masses of the cellulose fractions of the pulps obtained from the absolute MALLS measurements were compared with the molar masses obtained by direct‐standard‐calibration relative pullulan standards. Discrepancies between the two detection methods were found, and two ways of correlating the relative pullulan molar masses to the absolute molar masses were examined. In the first method, the correlation was made over a large range of molecular masses. The second method correlated the molecular masses of the standards to the molecular masses of samples by the calculation of fictitious, cellulose‐equivalent molar masses of the standards. With the preferred second method, a more correct MMD of kraft pulp samples could, therefore, be obtained from an SEC system calibrated with narrow standards. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1170–1179, 2003     

Syntheses of female sex pheromone precursors of pine sawfly species and of some structurally related methyl-branched long-chain 2-alkanols

3,7-Dimethyl-2-undecanol, 3,7,9-trimethyl-2-tridecanol, and 3,7, 11-trimethyl-2-tridecanol were synthesized as racemic mixtures in moderate yields. The alcohols are known precursors of the female sex pheromones of the pine sawfly species Diprion nipponica, Macrodiprion nemoralis, and Microdiprion pallipes, respectively. Stereoisomeric mixtures of 3,8,12-trimethyl-2-tridecanol, erythro-(2R,3R,11R/S)-3,11-dimethyl-2-tetradecanol, 3,5-dimethyl-2-tetradecanol, and 5,7-dimethyl-2-tetradecanol, structurally related to sex pheromone alcohol precursors of pine sawfly species, were also synthesized in moderate yields. The key reaction in the syntheses was the ring opening of -butyrolactones by using different alkyl lithiums as nucleophiles.     

Open to a Select Few? Matching Partners and Knowledge Content for Open Innovation Performance

The purpose of the paper is to illuminate the costs and benefits of crossing firm boundaries in inbound open innovation (OI) by determining the relationships among partner types, knowledge content and performance. The empirical part of the study is based on a survey of OI collaborations answered by R&D managers in 415 Italian, Finnish and Swedish firms. The results show that the depth of collaboration with different partners (academic/consultants, value chain partners, competitors and firms in other industries) is positively related to innovation performance, whereas the number of different partners and size have negative effects. The main result is that the knowledge content of the collaboration moderates the performance outcomes and the negative impact of having too many different kinds of partners. This illustrates how successful firms use selective collaboration strategies characterized by linking explorative and exploitative knowledge content to specific partners, to leverage the benefits and limit the costs of knowledge boundary crossing processes.     

Application of particle swarm optimization in epileptic spike EEG source localization

Surgical therapy has become an important therapeutic alternative for patients with medically intractable epilepsy. Correct and anatomically precise localization of an epileptic focus is essential to decide if resection of brain tissue is possible. The inverse problem in EEG-based source localization is to determine the location of the brain sources that are responsible for the measured potentials at the scalp electrodes. We propose a new global optimization method based on particle swarm optimization (PSO) to solve the epileptic spike EEG source localization inverse problem. In a forward problem a modified subtraction method is proposed to reduce the computational time. The good accuracy and fast convergence are demonstrated for 2D and 3D cases with realistic head models. The results from the new method are promising for use in the pre-surgical clinic in the future.     

A flux-free a posteriori error estimator for the incompressible Stokes problem using a mixed FE formulation

In this contribution, we present an a posteriori error estimator for the incompressible Stokes problem valid for a conventional mixed FE formulation. Due to the saddle-point property of the problem, conventional error estimators developed for pure minimization problems cannot be utilized straight-forwardly. The new estimator is built up by two key ingredients. At first, a computed error approximation, exactly fulfilling the continuity equation for the error, is obtained via local Dirichlet problems. Secondly, we adopt the approach of solving local equilibrated flux-free problems in order to bound the remaining, incompressible, error. In this manner, guaranteed upper and lower bounds, of the velocity “energy norm” of the error as well as goal-oriented (linear) output functionals, with respect to a reference (overkill) mesh are obtained. In particular, it should be noted that this approach requires no computation of hybrid fluxes. Furthermore, the estimator is applicable to mixed FE formulations using continuous pressure approximations, such as the Mini and Taylor–Hood class of elements. In conclusion, a few simple numerical examples are presented, illustrating the accuracy of the error bounds.     

Faster Deterministic Communication in Radio Networks

We study the communication primitives of broadcasting (one-to-all communication) and gossiping (all-to-all communication) in known topology radio networks, i.e., where for each primitive the schedule of transmissions is precomputed based on full knowledge about the size and the topology of the network. We show that gossiping can be completed in time units in any radio network of size n, diameter D, and maximum degree Δ=Ω(log n). This is an almost optimal schedule in the sense that there exists a radio network topology, specifically a Δ-regular tree, in which the radio gossiping cannot be completed in less than units of time. Moreover, we show a schedule for the broadcast task. Both our transmission schemes significantly improve upon the currently best known schedules by Gąsieniec, Peleg, and Xin (Proceedings of the 24th Annual ACM SIGACT-SIGOPS PODC, pp. 129–137, 2005), i.e., a O(D+Δlog n) time schedule for gossiping and a D+O(log ³ n) time schedule for broadcast. Our broadcasting schedule also improves, for large D, a very recent O(D+log ² n) time broadcasting schedule by Kowalski and Pelc. A preliminary version of this paper appeared in the proceedings of ISAAC’06. F. Cicalese supported by the Sofja Kovalevskaja Award 2004 of the Alexander von Humboldt Stiftung. F. Manne and Q. Xin supported by the Research Council of Norway through the SPECTRUM project.