Green synthesis of silver nanoparticles using flower extract of Malva sylvestris and investigation of their antibacterial activity

High‐quality colloidal silver nanoparticles (AgNP) were synthesised via a green approach by using hydroalcoholic extracts of Malva sylvestris. Silver nitrate was used as a substrate ion while the plant extract successfully played the role of reducing and stabilising agents. The synthesised nanoparticles were carefully characterised by using transmission electron microscopy, atomic‐force microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy and UV–vis spectroscopy. The maximum absorption wavelengths of the colloidal solutions synthesised using 70 and 96% ethanol and 100% methanol, as extraction solvents, were 430, 485 and 504 nm, respectively. Interestingly, the size distribution of nanoparticles depended on the used solvent. The best particle size distribution belonged to the nanoparticles synthesised by 70% ethanol extract, which was 20–40 nm. The antibacterial activity of the synthesised nanoparticles was studied on Escherichia coli, Staphylococcus aureus and Streptococcus pyogenes using disk diffusion, minimum inhibitory concentrations and minimum bactericidal concentrations assays. The best antibacterial activity obtained for the AgNPs produced by using 96% ethanolic extract.Inspec keywords: silver, nanoparticles, nanofabrication, antibacterial activity, colloids, particle size, transmission electron microscopy, atomic force microscopy, X‐ray chemical analysis, Fourier transform spectra, infrared spectra, ultraviolet spectra, visible spectra, microorganisms, nanomedicine, biomedical materialsOther keywords: Green synthesis, flower extract, Malva sylvestris, antibacterial activity, high‐quality colloidal silver nanoparticles, hydroalcoholic extracts, plant extract, reducing agents, stabilising agents, transmission electron microscopy, atomic‐force microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy, UV– vis spectroscopy, colloidal solutions, particle size distribution, Escherichia coli, Staphylococcus aureus, Streptococcus pyogenes, disk diffusion, minimum inhibitory concentrations, minimum bactericidal concentrations assays, ethanolic extract, size 430 nm, size 485 nm, size 504 nm, size 20 nm to 40 nm, Ag     

Engineering carbon quantum dots for photomediated theranostics

Carbon quantum dots (CQDs) have emerged as potential alternatives to classical metal-based semiconductor quantum dots (QDs) due to the abundance of their precursors, their ease of synthesis, high biocompatibility, low cost, and particularly their strong photoresponsiveness, tunability, and stability. Light is a versatile, tunable stimulus that can provide spatiotemporal control. Its interaction with CQDs elicits interesting responses such as wavelength-dependent optical emissions, charge/electron transfer, and heat generation, processes that are suitable for a range of photomediated bioapplications. The carbogenic core and surface characteristics of CQDs can be tuned through versatile engineering strategies to endow specific optical and physicochemical properties, while conjugation with specific moieties can enable the design of targeted probes. Fundamental approaches to tune the responses of CQDs to photo-interactions and the design of bionanoprobes are presented, which enable biomedical applications involving diagnostics and therapeutics. These strategies represent comprehensive platforms for engineering multifunctional probes for nanomedicine, and the design of QD probes with a range of metal-free and emerging 2D materials.

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Quantum Inspired Broadband Photonic Absorber: Potential Application as Solar Sail along with Mobility Analysis

Electromagnetic wideband absorption is still perceived as a critical and formidable challenge to address with an unambiguous photonic absorber. Subwavelength metamaterial (MM) unit cells with unique and controlled features have recently gained considerable interest. However, meta-atoms, generated using a quantum-inspired pattern distribution, are underwhelming in existing literature to design photonic absorbers and their potential application to manufacture solar sails is still quite uncommon. In this article, to create a flexible, polarization-insensitive, ultrathin, and broadband MM absorber, quantum interference pattern-inspired design is utilized. Herein, a novel approach to fabricating solar sails for the space exploration incorporates the proposed broadband photonic absorber rather than conventional reflectors. The quantum-inspired meta-absorber (QIMA) exhibits an absorption of over 91% for the visible domain, i.e., 380–800 nm under a conventional plane-polarized source. It is shown in the study that broadband absorbers are almost equivalent to excellent reflectors to design the solar sails in terms of the time-averaged force calculated by utilizing the Maxwell stress tensor method. Thus, the QIMA has the potential to be a viable alternative to reflectors in the design of futuristic solar sails for space exploration. The interference theory model is also utilized to assure the dependability of calculated data, and additionally, the standard AM1.5 solar spectrum is utilized to demonstrate the QIMA's solar-harvesting potentiality.     

Leveraging Transfer Learning for Spatio-Temporal Human Activity Recognition from Video Sequences

Human Activity Recognition (HAR) is an active research area due to its applications in pervasive computing, human-computer interaction, artificial intelligence, health care, and social sciences. Moreover, dynamic environments and anthropometric differences between individuals make it harder to recognize actions. This study focused on human activity in video sequences acquired with an RGB camera because of its vast range of real-world applications. It uses two-stream ConvNet to extract spatial and temporal information and proposes a fine-tuned deep neural network. Moreover, the transfer learning paradigm is adopted to extract varied and fixed frames while reusing object identification information. Six state-of-the-art pre-trained models are exploited to find the best model for spatial feature extraction. For temporal sequence, this study uses dense optical flow following the two-stream ConvNet and Bidirectional Long Short Term Memory (BiLSTM) to capture long-term dependencies. Two state-of-the-art datasets, UCF101 and HMDB51, are used for evaluation purposes. In addition, seven state-of-the-art optimizers are used to fine-tune the proposed network parameters. Furthermore, this study utilizes an ensemble mechanism to aggregate spatial-temporal features using a four-stream Convolutional Neural Network (CNN), where two streams use RGB data. In contrast, the other uses optical flow images. Finally, the proposed ensemble approach using max hard voting outperforms state-of-the-art methods with 96.30% and 90.07% accuracies on the UCF101 and HMDB51 datasets.     

Classification of Electroencephalogram Signals Using LSTM and SVM Based on Fast Walsh-Hadamard Transform

Classification of electroencephalogram (EEG) signals for humans can be achieved via artificial intelligence (AI) techniques. Especially, the EEG signals associated with seizure epilepsy can be detected to distinguish between epileptic and non-epileptic regions. From this perspective, an automated AI technique with a digital processing method can be used to improve these signals. This paper proposes two classifiers: long short-term memory (LSTM) and support vector machine (SVM) for the classification of seizure and non-seizure EEG signals. These classifiers are applied to a public dataset, namely the University of Bonn, which consists of 2 classes –seizure and non-seizure. In addition, a fast Walsh-Hadamard Transform (FWHT) technique is implemented to analyze the EEG signals within the recurrence space of the brain. Thus, Hadamard coefficients of the EEG signals are obtained via the FWHT. Moreover, the FWHT is contributed to generate an efficient derivation of seizure EEG recordings from non-seizure EEG recordings. Also, a k-fold cross-validation technique is applied to validate the performance of the proposed classifiers. The LSTM classifier provides the best performance, with a testing accuracy of 99.00%. The training and testing loss rates for the LSTM are 0.0029 and 0.0602, respectively, while the weighted average precision, recall, and F1-score for the LSTM are 99.00%. The results of the SVM classifier in terms of accuracy, sensitivity, and specificity reached 91%, 93.52%, and 91.3%, respectively. The computational time consumed for the training of the LSTM and SVM is 2000 and 2500 s, respectively. The results show that the LSTM classifier provides better performance than SVM in the classification of EEG signals. Eventually, the proposed classifiers provide high classification accuracy compared to previously published classifiers.     

A recursive state estimator in the presence of state inequality constraints

This paper proposes an optimal recursive estimator to estimate the states of a stochastic discrete time linear dynamic system when the states of the system are constrained with inequality constraints. The case when the constraints are strictly satisfied is treated independently from the case when some of the constraints are violated. For the first case, the well known Kalman filter estimator is used. In the second case, an algorithm which uses a series of successive orthogonalizations on the measurement subspaces is employed to obtain the optimal estimate. It is shown that the proposed estimator has several attractive properties such that it is an unbiased estimator. More importantly, compared to other estimator found in the literature, the proposed estimator needs less computational efforts, is numerically more stable and it leads to a smaller variance. To show the effectiveness of the proposed estimator, several simulation results are presented and discussed.     

Determining malicious executable distinguishing attributes and low-complexity detection

Detection of rapidly evolving malware requires classification techniques that can effectively and efficiently detect zero-day attacks. Such detection is based on a robust model of benign behavior and deviations from that model are used to detect malicious behavior. In this paper we propose a low-complexity host-based technique that uses deviations in static file attributes to detect malicious executables. We first develop simple statistical models of static file attributes derived from the empirical data of thousands of benign executables. Deviations among the attribute models of benign and malware executables are then quantified using information-theoretic (Kullback-Leibler-based) divergence measures. This quantification reveals distinguishing attributes that are considerably divergent between benign and malware executables and therefore can be used for detection. We use the benign models of divergent attributes in cross-correlation and log-likelihood frameworks to classify malicious executables. Our results, using over 4,000 malicious file samples, indicate that the proposed detector provides reasonably high detection accuracy, while having significantly lower complexity than existing detectors.     

A PDE method for patchwise approximation of large polygon meshes

Three-dimensional (3D) representations of complex geometric shapes, especially when they are reconstructed from magnetic resonance imaging (MRI) and computed tomography (CT) data, often result in large polygon meshes which require substantial storage for their handling, and normally have only one fixed level of detail (LOD). This can often be an obstacle for efficient data exchange and interactive work with such objects. We propose to replace such large polygon meshes with a relatively small set of coefficients of the patchwise partial differential equation (PDE) function representation. With this model, the approximations of the original shapes can be rendered with any desired resolution at interactive rates. Our approach can directly work with any common 3D reconstruction pipeline, which we demonstrate by applying it to a large reconstructed medical data set with irregular geometry.     

Integration of genetic fuzzy systems and artificial neural networks for stock price forecasting

Stock market prediction is regarded as a challenging task in financial time-series forecasting. The central idea to successful stock market prediction is achieving best results using minimum required input data and the least complex stock market model. To achieve these purposes this article presents an integrated approach based on genetic fuzzy systems (GFS) and artificial neural networks (ANN) for constructing a stock price forecasting expert system. At first, we use stepwise regression analysis (SRA) to determine factors which have most influence on stock prices. At the next stage we divide our raw data into k clusters by means of self-organizing map (SOM) neural networks. Finally, all clusters will be fed into independent GFS models with the ability of rule base extraction and data base tuning. We evaluate capability of the proposed approach by applying it on stock price data gathered from IT and Airlines sectors, and compare the outcomes with previous stock price forecasting methods using mean absolute percentage error (MAPE). Results show that the proposed approach outperforms all previous methods, so it can be considered as a suitable tool for stock price forecasting problems.     

Deriving operating policies for multi-objective reservoir systems: Application of Self-Learning Genetic Algorithm

Optimal multi-reservoir operation is a multi-objective problem in nature and some of its objectives are nonlinear, non-convex and multi-modal functions. There are a few areas of application of mathematical optimization models with a richer or more diverse history than in reservoir systems optimization. However, actual implementations remain limited or have not been sustained.Genetic Algorithms (GAs) are probabilistic search algorithms that are capable of solving a variety of complex multi-objective optimization problems, which may include non-linear, non-convex and multi-modal functions. GA is a population based global search method that can escape from local optima traps and find the global optima. However GAs have some drawbacks such as inaccuracy of the intensification process near the optimal set.In this paper, a new model called Self-Learning Genetic Algorithm (SLGA) is presented, which is an improved version of the SOM-Based Multi-Objective GA (SBMOGA) presented by Hakimi-Asiabar et al. (2009) [45]. The proposed model is used to derive optimal operating policies for a three-objective multi-reservoir system. SLGA is a new hybrid algorithm which uses Self-Organizing Map (SOM) and Variable Neighborhood Search (VNS) algorithms to add a memory to the GA and improve its local search accuracy. SOM is a neural network which is capable of learning and can improve the efficiency of data processing algorithms. The VNS algorithm can enhance the local search efficiency in the Evolutionary Algorithms (EAs).To evaluate the applicability and efficiency of the proposed methodology, it is used for developing optimal operating policies for the Karoon-Dez multi-reservoir system, which includes one-fifth of Iran's surface water resources. The objective functions of the problem are supplying water demands, generating hydropower energy and controlling water quality in downstream river.