Assessment of odorous VOCs released from a main MSW landfill site in Istanbul-Turkey via a modelling approach

An air pollution modeling study was conducted to investigate the odorous effects of volatile organic compounds (VOCs) emissions from a sanitary landfill area on ambient air quality. The atmospheric dispersion of hydrogen sulfide (H₂S) and 22 VOCs was modeled. Industrial Source Complex v3 Short Term (ISCST3) model was used to estimate hourly concentrations of odorous VOCs over the nearest residential area. Odor thresholds of VOCs of interest were also found in the literature. Results showed that short-term averages of three odorous VOCs, namely ethyl mercaptan, methyl mercaptan and hydrogen sulfide, exceeded their odor thresholds, which are reported to be 0.022, 0.138 and 11.1 μg/m³, respectively, at several points within the domain. Their highest concentrations within Gokturk County were estimated to be 0.09387 μg/m³ for ethyl mercaptan, 0.07934 μg/m³ for methyl mercaptan and 6.315 μg/m³ for hydrogen sulfide. Short-term model results revealed the occasional odor problems being reported for Gokturk County. Hourly concentrations were used to obtain frequencies of odor episodes in Gokturk County via a probability analysis. The results showed that ethyl mercaptan concentrations did not exceed its odor threshold during more than 8.84% of the time. Similarly, the maximum odor episode frequencies for methyl mercaptan and hydrogen sulfide were 0.98% and 0.34% of the time, respectively.     

Using non-food information to identify food-choice segment membership

Food companies, governments, and societal organizations use an increasing number of food-choice motives to persuade consumers to buy food products, and the question which combinations of motives matter for which type of consumer has become of central relevance. In this study, we use a concomitant mixture-modeling approach to uncover consumer segments in terms of food-choice motives, using a nationwide sample in the Netherlands. The results reveal seven segments with distinct profiles and demonstrate that age and membership of environmental organizations play an essential role in segment membership probabilities. Our findings support the idea that information about non-food-related consumer behavior improves the identification of segments. In an additional analysis, we demonstrate how organizational membership also provides an effective way to access consumer segments as compared to diverse media outlets. We discuss the implications of our findings for segmentation practice.     

Geotechnical Problems of Cultural Heritage due to Floods

Flood events demonstrate devastating effects not only on materials and structures in contact with flowing surface water. Equally important is the behavior of foundations in interaction with subsoil. This contribution gives an overview of different phenomena which arise in subsoil and at the foundation level during the groundwater rise accompanied by several case histories related to cultural heritage. Possible geotechnical measures are discussed as well.     

Radiosensitization of Human Leukemic HL-60 Cells by ATR Kinase Inhibitor (VE-821): Phosphoproteomic Analysis

DNA damaging agents such as ionizing radiation or chemotherapy are frequently used in oncology. DNA damage response (DDR)—triggered by radiation-induced double strand breaks—is orchestrated mainly by three Phosphatidylinositol 3-kinase-related kinases (PIKKs): Ataxia teleangiectasia mutated (ATM), DNA-dependent protein kinase (DNA-PK) and ATM and Rad3-related kinase (ATR). Their activation promotes cell-cycle arrest and facilitates DNA damage repair, resulting in radioresistance. Recently developed specific ATR inhibitor, VE-821 (3-amino-6-(4-(methylsulfonyl)phenyl)-N-phenylpyrazine-2-carboxamide), has been reported to have a significant radio- and chemo-sensitizing effect delimited to cancer cells (largely p53-deficient) without affecting normal cells. In this study, we employed SILAC-based quantitative phosphoproteomics to describe the mechanism of the radiosensitizing effect of VE-821 in human promyelocytic leukemic cells HL-60 (p53-negative). Hydrophilic interaction liquid chromatography (HILIC)-prefractionation with TiO₂-enrichment and nano-liquid chromatography—tandem mass spectrometry (LC-MS/MS) analysis revealed 9834 phosphorylation sites. Proteins with differentially up-/down-regulated phosphorylation were mostly localized in the nucleus and were involved in cellular processes such as DDR, all phases of the cell cycle, and cell division. Moreover, sequence motif analysis revealed significant changes in the activities of kinases involved in these processes. Taken together, our data indicates that ATR kinase has multiple roles in response to DNA damage throughout the cell cycle and that its inhibitor VE-821 is a potent radiosensitizing agent for p53-negative HL-60 cells.     

Spectrophotometric investigation of the copolymerization of styrene or methyl methacrylate with 1,8‐naphthalimide dyes

The copolymerization of styrene or methyl methacrylate with 1,8‐naphthalimide dyes to yield fluorescent side‐group copolymers was investigated. During copolymerization, no changes occurred in the chromophoric systems of the dyes. Colorimetrically, it was found that more that 0.90% of the dyes were chemically bonded to the polymer chain. The effect of polymer coloration was proven by appropriate coloristic characterization. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2463–2470, 2001     

Threshold Temperature Dependence of a Quantum-Dot Laser Diode With and Without p-Doping

A study of the threshold characteristics of quantum-dot (QD) laser diodes shows how inhomogeneous broadening and p-doping influence the QD laser's temperature dependence of threshold T ₀. The analysis includes the additional parameters of homogeneous broadening, quantum state populations, and threshold gain. The results show that while the source of negative T ₀ can occur due to different effects, the transparency current plays a critical role in both undoped and p-doped QD lasers. Experimental trends of negative T ₀ and their dependence on p-doping are replicated in the calculated results. Inhomogeneous broadening is found to play a lesser role to the transparency current in setting T ₀. Homogeneous broadening is most important for uniform QDs with thermally isolated ground-state transitions.     

Comparison of additive effects on the PVA/starch cryogels: Synthesis,characterization, cytotoxicity,and genotoxicity studies

The research goal of this study is to produce suitable scaffolds for tissue engineering applications. Different ratios of polyvinyl alcohol (PVA)/starch (90:10, 70:30, 50:50) and crosslinking methods have been used to prepare cryogels. Chemically crosslinked cryogels were synthesized using glutaraldehyde as the crosslinking agent. For the physically crosslinked cryogels, sodium dodecyl sulfate was used during cryogelation as the foaming agent. Chemical structure and pore morphology were demonstrated by Fourier transform infrared spectroscopy and scanning electron microscopy (SEM). Swelling ratio and degradation profile of the scaffolds were also determined. 3-(4,5-dimethylthiazoyl-2-yl)-2,5-diphenyltetrazolium bromide assay and SEM were used to investigate the biocompatibility of the scaffolds and cell morphology. Genotoxicity test was performed to show DNA fragmentation. The overall results demonstrated that PVA/starch cryogels could have potentially appealing application as scaffolds for tissue engineering applications and additives affect the architecture and characteristic properties of the cryogels.     

Investigation of the effects of geometrical parameters on heat transfer from buried finned pipes

Heat transfer from finned pipes buried in the soil has been investigated using experimental, analytical and numerical techniques. The experimental setup consists of a ground source heat pump system and two separate ground heat exchangers. Constant surface temperature approach based on Carslaw and Jaeger’s theory study was used for calculating the heat transfer from the pipes analytically. The problem was modeled and solved using a CFD program numerically. Effects of the fin number, fin length and simulation time on the heat transfer rate have been investigated and compared with bare tube. A modified analytical formula was also proposed for finned pipes in this study.     

Determination of radiation attenuation coefficients of heavyweight- and normal-weight concretes containing colemanite and barite for 0.663 MeV γ-rays

Accurate measurements have been made to determine radiation transmission of concretes produced with barite, colemanite and normal aggregate by using beam transmission method for 0.663 MeV γ-rays energy of ¹³⁷Cs radioactive isotopes by using NaI(Tl) scintillation detector. Linear and mass attenuation coefficients of thirteen heavy- and four normal-weight concretes were calculated. It was determined that the linear attenuation coefficient (μ, cm⁻¹) decreased with colemanite concentration and increased with barite concentration in both type of the concretes. Mass attenuation coefficient values of our concretes were compared with the values proposed by the United States National Institute of Standards and Technology (NIST).     

Effects of solid retention time on anaerobic digestion of dewatered-sewage sludge in mesophilic and thermophilic conditions

Anaerobic digestion of dewatered-sewage sludge using continuous stirred tank reactors (CSTRs) in duplicates was evaluated under thermophilic (50 °C) and mesophilic (37 °C) conditions over a range of nine solid retention times (SRTs). The 35- and 30-day SRTs were designed to simulate a full-scale plant operation while 25-, 20-, 15- and 12-day SRTs were planned to evaluate process performance at the various SRTs. The 9-, 5- and 3-day SRTs were performed to push the reactors to extend their degradation capacity and test the threshold for process imbalance. The corresponding organic loading rates (OLR) varied from 1.6 to 20.5 kg VS m^?3 day^?1. Biogas production rate could be tripled when the SRT was shortened from 30 to 12 days and more than doubled from 35- to 15-day SRT because of a concomitant increase in OLR. In general, higher biogas productivity was realized under thermophilic, but methane yields were comparable due to the higher methane content in the biogas under mesophilic digestion. The methane content in biogas fluctuated between 55 and 65% and the methane yield ranged from 0.314 to 0.348 Nm³ CH₄ kg VS_added^?1 day^?1 for both thermophilic and mesophilic digestion. The VS-reduction at 12- and 15-day SRT ranged from 45 to 52% and there was no accumulation of VFAs. Increasing concentrations of VFAs, decreasing concentration of partial alkalinity and decrease in pH were noted as signs of reactor instability. Process imbalance started at 9-day SRT, souring of the reactors, cell wash-out and foaming was noted as the principal causes of process failure under both thermophilic and mesophilic conditions. This study projected the possibility of using CSTRs in treating dewatered-sewage sludge at a shorter SRT to achieve reasonable biogas production and VS-reduction without encountering adverse operation conditions as foaming and wash-out of cells.