ROV扭矩工具系统研制与应用

ROV扭矩工具(TT)是深水水下油气田开发过程中使用的水下机器人(ROV)作业装备。ROV扭矩工具系统是以ROV为核心,包括扭矩工具本体和控制系统,其结构尺寸和工作能力与工作效率是影响水下作业的便利性与作业成本的关键因素。依托南海某气田水下生产系统,参考ISO13628-8等规范,设计出具有多尺寸自适应接口、牙嵌离合换挡结构和锁紧机构的扭矩工具及其控制系统。采用有限元分析软件对扭矩工具关键部件进行仿真分析。完成了扭矩工具的样机研制并进行测试。测试结果表明：水下ROV扭矩工具的锁紧、解锁功能,换挡功能,马达闭环控制功能均可实现,技术参数满足设计要求。研究成果对ROV扭矩工具及其控制系统的技术发展和产品开发均有借鉴意义。     

加拿大东部斯科舍盆地塞布尔次盆下白垩统深水重力流沉积研究

针对加拿大东部斯科舍盆地重力流沉积演化研究不足的问题,综合岩心、测井、地震及磁异常等资料,明确斯科舍盆地塞布尔次盆下白垩统重力流沉积单元,揭示其沉积演化并探讨发育控制因素。研究结果表明：斯科舍盆地塞布尔次盆下白垩统密西沙加组和洛根峡谷组发育规模性重力流沉积,可以识别出块体搬运、重力流水道、天然堤及朵叶体等沉积单元;密西沙加组沉积初期（距今147 Ma）研究区西部发育小型重力流沉积,沉积末期（距今130Ma）研究区中部发育大型坡底扇;洛根峡谷组沉积初期（距今113 Ma）研究区普遍发育小型重力流沉积,沉积末期（距今101 Ma）研究区东南部发育大型坡底扇。陆架边缘三角洲进积及陆坡窄、陡,分别为重力流发育提供了物质基础和动力条件。     

Simultaneously achieved high-energy storage density and efficiency in (K,Na)NbO3-based lead-free ferroelectric films

With the development of advanced electrical and electronic devices and the requirement of environmental protection, lead-free dielectric capacitors with excellent energy storage performance have aroused great attention. However, it is a great challenge to achieve both large energy storage density and high efficiency simultaneously in dielectric capacitors. This work investigates the energy storage performance of sol-gel-processed (K,Na)NbO₃-based lead-free ferroelectric films on silicon substrates with compositions of 0.95(K_0.49Na_0.49Li_0.02)(Nb_0.8Ta_0.2)O₃-0.05CaZrO₃-x mol% Mn (KNN-LT-CZ5-x mol% Mn). The appropriate amount of Mn-doping facilitates the coexistence of orthorhombic and tetragonal phases, suppresses the leakage current, and considerably enhances the breakdown strengths of KNN-LT-CZ5 films. Consequently, large recoverable energy storage density up to 64.6 J cm⁻³ with a high efficiency of 84.6% under an electric field of 3080 kV cm⁻¹ are achieved in KNN-LT-CZ5-5 mol% Mn film. This, to the best of our knowledge, is superior to the majority of both the lead-based and lead-free films on silicon substrates and thus demonstrates great potentials of (K,Na)NbO₃-based lead-free films as dielectric energy storage materials.     

Effects of different porous fillers on interfacial properties of poly (vinyl alcohol) hybrid films

Poly(vinyl alcohol) (PVA)-based hybrids have demonstrated broad liquid separation applications but separation performances are constrained by the compatibility between fillers and polymer, and thus it is essential to study the interfacial properties of these hybrids. In this work, PVA hybrids with four different porous fillers have been fabricated and characterized with Fourier transform infrared, X-ray diffraction, Scanning electron microscope, swelling and contact angle tests. Swelling results show that PVA has a degree of swelling (DS) of 79% in water but the swelling is compressed after adding fillers and the DS for PVA hybrids has decreased by 19%, 17%, 15%, and 9% for 30 wt% loading of ZIF-8, UiO-66, Hβ and ZSM-5, respectively. For methanol and its 10 wt% aqueous solution, similar swelling results are obtained due to mutual interactions among the filler, polymer and test liquids. Based on water and glycerol contact angle results, the surface energy of PVA is estimated to be 40.56 Nm⁻¹ and it drops to 27.39 Nm⁻¹ after adding less hydrophilic ZIF-8 or rise to 48.56 Nm⁻¹ after introducing more hydrophilic ZSM-5. The high-film hydrophilicity and then large surface energy have rendered methanol/water sorption selectivity of PVA hybrids decrease to some extent or vice versa.     

Tough and self-healing hydrophobic association hydrogels with cationic surfactant

Hydrophobic association (HA) hydrogels with outstanding mechanical, rheological and recovery properties were successfully synthesized by micellar copolymerization of acrylamide with lauryl methacrylate. The synthesis occurred at room temperature and the synthesis condition was moderate by using the redox initiator system of Ammonium persulfate - sodium bisulfite as initiators. Cationic surfactant (dodecyl trimethyl ammonium bromide) was utilized to form micelles with hydrophobe, served as physical cross-linking points in the 3D networks of hydrogels. The HA hydrogels showed a high tensile strength of 181 kPa, superior stretchability of 2300% and excellent toughness of 2.16 MJ m⁻³. Moreover, they owned extraordinary self-recovery under different conditions. It is hopeful that the hydrogels with superior mechanical strength and self-healing properties would be applied to the fields of biomedicine and engineering. Meanwhile, based on above materials, HA hydrogels could also be synthesized with the combination of hydrophobic association and other synergistic effects, such as latex particles, electrostatic effect and nanoparticles.     

水性工业涂料废液的处理研究

采用混凝 -生物接触氧化 -芬顿高级氧化组合工艺对水性涂料废液进行处理研究。重点考察了该工艺对涂料废液 COD、氨氮和 SS的去除效果。结果表明, pH升高对涂料废液中的 SS、COD有去除效果并且能够避免混凝时发生板结,当 pH为 10时, COD由 148 000 mg/L降至 46 000 mg/L,SS质量浓度由 18 500 mg/L降至 2 500 mg/L,去除率分别达到 86. 4%和 68. 5%;接触氧化反应器经过 60 d的运行, COD容积负荷达到 0. 67 kg/（m3·d）出水 COD、氨氮去除率分别达到 94%、85%;经过混凝 -生物接触氧化 -芬顿高级氧化组合工艺处理最终,出水 COD为 280 mg/L左右,氨氮质量浓度为 15 mg/L, SS质量浓度为 13 mg/L左右,均可达到排放标准。     

福建电力现货市场初期模式探析

中国电力现货市场建设正在进入深入推进推广阶段,如何实现由计划模式向市场模式的安全平稳过渡是保证中国电力市场改革成功的关键问题。文中提出一种适应计划向市场转变过程的竞价空间方法以及相应的市场出清结算机制。该竞价机制分为计划模式的优化计算和市场出清两步。计划模式与市场模式的优化计算所考虑的基本约束条件保持一致,根据竞价空间比例将计划模式的计算结果作为市场模式优化出清边界条件,保证市场模式的优化出清严格在竞价空间范围内开展。通过调整竞价空间的计算比例,逐步扩大市场比例,实现由计划模式向市场模式的逐步过渡。最后,以实际算例对比验证了该竞价机制的有效性和实用性。     

Effect of different templates on conductivity and strain sensing properties of natural rubber/reduced graphene and acidified multi-walled carbon nanotubes woven fabric composites

不同模板对天然橡胶/还原石墨烯和酸化多壁碳纳米管机织物复合材料导电性能和应变传感性能的影响 章婉琪,林炎坤,王 晶,姜 宽,贾红兵 （南京理工大学 教育部软化学和功能材料重点实验室,南京 210094） 制备了天然橡胶（NR）/还原石墨烯和酸化多壁碳纳米管机织物（GMWF）-M（密集）和NR/GMWF-S（稀疏）复合材料,研究了两种疏密程度不同的棉织品模板对GMWF复合材料导电性能和应变传感性能的影响。结果表明,NR/GMWF-M复合材料的导电性能明显优于NR/GMWF-S,但NR/GMWF-S的传感性能更佳。     

考虑电池寿命损耗的园区综合能源电/热混合储能优化配置

针对园区综合能源系统(PIES)储能容量优化配置问题,为提升PIES规划-运行经济性,提出了考虑电池寿命损耗的PIES电/热混合储能优化配置方法.首先,构建了适用于PIES规划问题的电池寿命损耗模型,用于量化评估电池寿命损耗;进而,在考虑PIES多能互补特性基础上,引入电池置换成本体现电池寿命损耗的长期影响,以电/热混合储能投资置换成本与运行成本等年值最低为目标函数,建立了PIES电/热混合储能容量双层优化配置模型;最后,通过算例验证了文中混合储能配置方法对系统规划-运行经济性、电池使用寿命的提升效果,并比较分析了电/热混合储能与单一储能对系统规划-运行经济性和电池使用寿命的影响.     

牵引变电所群贯通供电系统负序补偿模型及控制策略

针对牵引变电所群贯通供电系统存在的三相电压不平衡问题,提出一种基于三相变压器与静止无功发生器(SVG)的负序集中补偿方案及控制策略.首先,根据牵引变压器的功率变换关系及不同的负荷情况,推导了2种模式下补偿装置对牵引负荷的补偿功率通用表达式.根据中国的电能质量标准,提出了以负序满意补偿为目标的双限值补偿方案,方案包括了模式选择方法、SVG容量配置方法及SVG运行方法.根据补偿方案,设计了带有模式判别的SVG双闭环补偿控制策略.然后,采用牵引变电所实测数据对补偿方案进行验证,证明了方案具有良好的补偿效果,与全补偿方案相比,所提方案需要的装置容量更小.最后,通过仿真证明了控制策略对负序补偿的有效性和较快的响应速度.