Vibration analysis of a planetary gear system based on the transfer matrix method

This study models a 3-dimensional planetary gear system using the transfer matrix method. The local transfer matrices between each component of the planetary gear set were derived with consideration of the tooth width, and the transfer matrix of a planetary gear system corresponding to the inertial transfer matrix was determined. The eigenvalue analysis of the transfer matrix suggested an analysis method in the form of a lambda matrix, instead of the direct search method through a characteristic polynomial. The boundary conditions at the first and the last stations of the entire transfer matrix were partitioned into known and unknown values to generate a concentrated transfer matrix and a latent equation, and the eigenvalue problem in the lambda matrix was solved. The characteristics of the responses according to the phase state of the harmonic component of the transmission error were reviewed through the steady-state response and mode shape type.     

Determination of the optimum mixture of transglutaminase,l-ascorbic acid and xylanase for the quality and consumer acceptability of bread using response surface methodology

The optimum levels of transglutaminase (TGase), l-ascorbic acid (l-AA), and xylanase (Xyl) were determined using response surface methodology to improve quality and consumer acceptability of bread made with wheat flour. A Box-Behnken design with three independent variables (TGase, l-AA, and Xyl) and three levels was used to develop models for the different responses (peak time, mixing tolerance, extensibility, resistance, specific volume, hardness, and consumer acceptability). Overall, l-AA and Xyl improved dough and bread properties, whereas the addition of TGase positively affected to texture and overall acceptability by consumer test. The optimal formulation for dough and bread properties and consumer acceptability were identified and the optimal value was 0.36 g/100 g TGase, 0.026 g/100 g Xyl, and 0.005 g/100 g l-AA. The results demonstrate that the addition of optimum amounts of TGase, Xyl, and l-AA improves the baking quality of the flour by enhancing dough properties and increase the consumer acceptability of the bread.     

Low digestion property of amylosucrase-modified waxy adlay starch

Structural and digestion properties of amylosucrase-modified waxy adlay starch were investigated. The unique reaction of amylosucrase caused a decrease and an increase in the proportion of short chains and long chains, respectively, via attachment of glucosyl units to the non-reducing ends of branch chains. The in vitro digestion profile of amylosucrase-modified starch revealed that elongated branch chains were the main reason for high contents of slowly digestible and resistant starches due to formation of a more perfect crystalline structure via easy association between elongated branch chains. The glucose response in mice after consumption of amylosucrase-modified starch was similar to the response for commercial resistant starch with a gradual increase followed by a gradual decrease in blood glucose concentrations over a prolonged time. Both in vitro and in vivo tests were used to verify increased resistance to digestive enzymes caused by amylosucrase modification.     

Non‐Volatile Polymer Electroluminescence Programmable with Ferroelectric Field‐Induced Charge Injection Gate

Electroluminescence (EL) of organic and polymeric fluorescent materials programmable in the luminance is extremely useful as a non‐volatile EL memory with the great potential in the variety of emerging information storage applications for imaging and motion sensors. In this work, a novel non‐volatile EL memory in which arbitrarily chosen EL states are programmed and erased repetitively with long EL retention is demonstrated. The memory is based on utilizing the built‐in electric field arising from the remnant polarization of a ferroelectric polymer which in turn controls the carrier injection of an EL device. A device with vertically stacked components of a transparent bottom electrode/a ferroelectric polymer/a hole injection layer/a light emitting layer/a top electrode successfully emits light upon alternating current (AC) operation. Interestingly, the device exhibits two distinctive non‐volatile EL intensities at constant reading AC voltage, depending upon the programmed direct current (DC) voltage on the ferroelectric layer. DC programmed and AC read EL memories are also realized with different EL colors of red, green and blue. Furthermore, more than four distinguishable EL states are precisely addressed upon the programmed voltage input each of which shows excellent EL retention and multiple cycle endurance of more than 10⁵ s and 10² cycles, respectively.     

Graphene Quantum Sheet Catalyzed Silicon Photocathode for Selective CO2 Conversion to CO

The reduction of carbon dioxide (CO₂) into chemical feedstock is drawing increasing attention as a prominent method of recycling atmospheric CO₂. Although many studies have been devoted in designing an efficient catalyst for CO₂ conversion with noble metals, low selectivity and high energy input still remain major hurdles. One possible solution is to use the combination of an earth‐abundant electrocatalyst with a photoelectrode powered by solar energy. Herein, for the first time, a p‐type silicon nanowire with nitrogen‐doped graphene quantum sheets (N‐GQSs) as heterogeneous electrocatalyst for selective CO production is demonstrated. The photoreduction of CO₂ into CO is achieved at a potential of ?1.53 V versus Ag/Ag⁺, providing 0.15 mA cm^?2 of current density, which is 130 mV higher than that of a p‐type Si nanowire decorated with well‐known Cu catalyst. The faradaic efficiency for CO is 95%, demonstrating significantly improved selectivity compared with that of bare planar Si. The density functional theory (DFT) calculations are performed, which suggest that pyridinic N acts as the active site and band alignment can be achieved for N‐GQSs larger than 3 nm. The demonstrated high efficiency of the catalytic system provides new insights for the development of nonprecious, environmentally benign CO₂ utilization.     

Remote‐Controllable Molecular Knob in the Mesomorphic Helical Superstructures

A programed light‐responsive chiral liquid crystal (LC) containing four photochromic azobenzene moieties covalently connected to a central bicyclic chiral core (abbreviated as AZ₄ICD) is newly designed, precisely synthesized, and efficiently applied as a remote‐controllable molecular knob for the optically tunable thin film. First of all, phase evolutions and ordered structures of AZ₄ICD are systematically investigated by a combination of thermal, microscopic, scattering, and simulation techniques. Wide‐angle X‐ray diffractions of oriented AZ₄ICD samples indicate that the AZ₄ICD molecule itself basically forms layer structures: one is a low‐ordered chiral smectic A LC phase (SmA*) with 5.61 nm layer periodicity at high temperatures, and two highly ordered smectic crystal (SmCr₁ and SmCr₂) phases are subsequently formed at lower temperatures with the anticlinically tilted molecular packing structures. The helical superstructures of chiral nematic LC phase (N*) can be spontaneously constructed by doping AZ₄ICD chiral agents into the achiral nematic molecules. Due to the bent conformational geometry of AZ₄ICD, the thermal window of blue LC phase (BP) is expanded by stabilizing the double twisted cylindrical building blocks. Remote‐controllable phase transformations in the mesomorphic helical superstructures are demonstrated by tuning the wavelength of light.     

Utilization of the Antiferromagnetic IrMn Electrode in Spin Thermoelectric Devices and Their Beneficial Hybrid for Thermopiles

The thermoelectric effect in various magnetic systems, in which electric voltage is generated by a spin current, has attracted much interest owing to its potential applications in energy harvesting, but its power generation capability has to be improved further for actual applications. In this study, the first instance of the formation of a spin thermopile via a simplified and straightforward method which utilizes two distinct characteristics of antiferromagnetic IrMn is reported: the inverse spin Hall effect and the exchange bias. The former allows the IrMn efficiently to convert the thermally induced spin current into a measurable voltage, and the latter can be used to control the spin direction of adjacent ferromagnetic materials. It is observed that a thermoelectric signal is successfully amplified in spin thermopiles with exchange‐biased IrMn/CoFeB structures, where an alternating magnetic alignment is formed using the IrMn thickness dependence of the exchange bias. The scalable signal on a number of thermopiles allowing a large‐area application paves the way toward the development of practical spin thermoelectric devices. A detailed model analysis is also provided for a quantitative understanding of the thermoelectric voltages, which consist of the spin Seebeck and anomalous Nernst contributions.     

Unsteady two-dimensional multiphysical simulation of a pressure tube model expanded to contact with the outer concentric tube

For the blind calculation of the International Collaborative Standard Problem (ICSP) experiment on heavy water reactor moderator subcooling requirements, the COMSOL Multiphysics code is used to simulate plastic deformation of a pressure tube (PT) as a result of the interaction of stress and temperature. It is shown that the thermal stress model of COMSOL is compatible to simulate the multiple heat transfers (including the radiation heat transfer and heat conduction) and stress strain in the simplified two-dimensional problem. The benchmark test result for radiation heat transfer is in good agreement with the analytical solution for the concentric configuration of PT and calandria tube (CT). Since the original strain model of COMSOL only considers an elastic deformation with thermal expansion coefficient, the PT/CT contact cannot be predicted in the ICSP. Therefore, the plastic deformation model by the Shewfelt and Godin, widely used in the fuel channel analysis of CANadian Deuterium Uranium (CANDU) reactor, is implemented to the strain equation of COMSOL. The heat-up of PT, the strain rate, and the contact time of the PT/CT are calculated with the boundary conditions (BCs) given for blind calculation of the ICSP experiment.

The result shows a sudden expansion of the inner concentric PT within a few milliseconds. This unsteady simulation should be helpful for the conceptual design of experiment as well as for the understanding of multiphysics inside the fuel channels of the CANDU reactor.