Monte Carlo study of the evolution of diffuse scattering and coherent modulation during h.c.p. to f.c.c. martensitic transition-I. Infinitely strong repulsive interaction model

Calculation of diffuse scattering during h.c.p. to f.c.c. martensitic transition by non-random insertion of deformation faults using a Monte Carlo technique is presented. It is shown that a coherent modulation of wavelength λ = 6d₁₁₁ can result during such transitions. The intensity and sharpness of the satellite peaks are shown to depend on the volume fraction of the twin-related f.c.c. variants. The predicted satellite peaks are in good agreement with those observed in Co and Co-Ni single crystals undergoing h.c.p. to f.c.c. martensitic transition.     

Compositional and Morphological Studies of Polythiophene/Polyflorene Blends in Inverted Architecture Hybrid Solar Cells

This work investigates the composition and morphology of films of poly(3‐hexylthiophene) (P3HT), polyfluorene co‐polymer poly((9,9‐dioctylfluorene)‐2,7‐diyl‐alt‐[4,7‐bis(3‐hexylthien‐5‐yl)‐2,1,3‐benzothiadiazole]‐2′,2″‐diyl) (F8TBT) and blends thereof that are used in efficient all‐polymer solar cells. Ultraviolet photoemission spectroscopy (UPS) and X‐ray photoemission spectroscopy (XPS) studies on thin polymer and blend films on ZnO substrates reveal the existence of a 1–2 nm thick P3HT layer at the top surface of the blend films. XPS depth profiling studies reveal a density wave (λ ≈ 70 nm) originating from the air interface. As no preferential accumulation is observed at the bottom interface with ZnO, the composition at this interface is consistent with the original composition of the blend solution prior to spin‐coating. The morphology of this buried interface was studied by means of atomic force microscopy (AFM) and revealed that upon annealing the average domain size increases slightly (from 27 nm to 40 nm). It is observed that the photovoltaic performance of such inverted hybrid device improves upon annealing, however we believe this to mostly be a result of increased crystallinity in the P3HT domains leading to improved charge transport in the device, rather than changes in the blend phase separation.     

Collective osmotic shock in ordered materials

Osmotic shock in a vesicle or cell is the stress build-up and subsequent rupture of the phospholipid membrane that occurs when a relatively high concentration of salt is unable to cross the membrane and instead an inflow of water alleviates the salt concentration gradient. This is a well-known failure mechanism for cells and vesicles (for example, hypotonic shock) and metal alloys (for example, hydrogen embrittlement). We propose the concept of collective osmotic shock, whereby a coordinated explosive fracture resulting from multiplexing the singular effects of osmotic shock at discrete sites within an ordered material results in regular bicontinuous structures. The concept is demonstrated here using self-assembled block copolymer micelles, yet it is applicable to organized heterogeneous materials where a minority component can be selectively degraded and solvated whilst ensconced in a matrix capable of plastic deformation. We discuss the application of these self-supported, perforated multilayer materials in photonics, nanofiltration and optoelectronics.     

Optical and electrical features of surface ordered regioregular polyhexylthiophene

Interface morphology play an important role in controlling transport characteristics for devices based on polymer semiconductors. We modify the interface between the insulating surface and polymer film, poly(3-hexylthiophene) (P3HT), and control the interfacial molecular ordering of the polymer film by using different self assembled molecules. We correlate the changes in the optical, electrical transport, and photogenerated carrier transport to the functionalized surfaces that demonstrate different levels of molecular ordering in the polymer film at the interface of insulating surface and polymer, ranging from a uniform-disordered surface to lamella crystallite and highly oriented microdomains.     

Optically‐Pumped Lasing in Hybrid Organic–Inorganic Light‐Emitting Diodes

Here, the use of metal oxide layers both for charge transport and injection into an emissive semiconducting polymer and also for the control of the in‐plane waveguided optical modes in light‐emitting diodes (LEDs) is reported. The high refractive index of zinc oxide is used to confine these modes away from the absorbing electrodes, and include a nano‐imprinted grating in the polymer layer to introduce distributed feedback and enhance optical out‐coupling. These structures show a large increase in the luminescence efficiency over conventional devices, with photoluminescence efficiency increased by up to 45%. Furthermore, optically‐pumped lasing in hybrid oxide polymer LEDs is demonstrated. A tuneable lasing emission is also obtained in a single device structure by employing a graduated thickness of a zinc oxide inter‐layer. This demonstrates the scope for using such architectures to improve the external efficiency of organic semiconductor LEDs, and opens new possibilities for the realization of polymer injection lasers.     

Effect of symmetric distortion of the field of fluid velocity on the readings of an ultrasonic flowmeter

A numerical method is proposed for determining a discharge coefficient that relates mean velocity to the velocity measured with an ultrasonic flowmeter. Translated from Izmeritel'naya Tekhnika, No. 5, pp. 29–32, May, 1997.     

OPT++ : an object-oriented implementation for extensible database query optimization

In this paper we describe the design and implementation of OPT++, a tool for extensible database query optimization that uses an object-oriented design to simplify the task of implementing, extending, and modifying an optimizer. Building an optimizer using OPT++ makes it easy to extend the query algebra (to add new query algebra operators and physical implementation algorithms to the system), easy to change the search space, and also to change the search strategy. Furthermore, OPT++ comes equipped with a number of search strategies that are available for use by an optimizer-implementor. OPT++ considerably simplifies both, the task of implementing an optimizer for a new database system, and the task of evaluating alternative optimization techniques and strategies to decide what techniques are best suited for that database system. We present the results of a series of performance studies. These results validate our design and show that, in spite of its flexibility, OPT++ can be used to build efficient optimizers. Received October 1996 / Accepted January 1998