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排序方式: 共有1311条查询结果,搜索用时 281 毫秒
21.
22.
E. I. Basaldella J.C. Tara G. Aguilar Armenta M. E. Patiño Iglesias 《Journal of Porous Materials》2007,14(3):273-278
Samples of mesoporous silica SBA-15 were prepared under hydrothermal conditions where Cu cations were incorporated to the
structure by impregnation in order to compare the adsorption behavior in the presence and absence of this element. The adsorption/desorption
equilibrium isotherms of propylene, propane, and N2 were measured to evaluate their usefulness in the propane/propylene separation.
All the adsorption isotherms of SBA-15 measured in the absence of Cu cations were described by the Freundlich equation, while
the adsorption isotherms of propane on Cu/SBA-15 were better represented by the Henry equation and those of propylene were
satisfactorily described by the Langmuir model in the range P < 100 Torr. The adsorption uptake of propylene increased and that of propane decreased in Cu/SBA-15 as compared to the amounts
observed in the SBA-15 sample. The presence of Cu atoms in the adsorbent lattice increased the selectivity towards propylene.
Under some working conditions the adsorbed amount of propylene in Cu/SBA-15 sample was totally reversible and the propane
uptake, negligible. 相似文献
23.
The feasibility of chromium(VI) to induce graft polymerization of methyl methacrylate onto silk was investigated. The rate of grafting was determined by varying monomer concentration, chromium(VI) concentration, temperature, acidity of the medium, nature of the silk, reaction medium, and redox system. The graft yield increased with increasing monomer concentration up to 0.65M, and with further increase of monomer the graft yield decreased. The graft yield increased with increasing chromium(VI) concentration. The grafting is considerably influenced by chemical modification of silk prior to grafting. The graft yield is influenced by thiourea concentration, decreasing with increasing thiourea concentration. The effect of certain inorganic salts and anionic surfactants on the rate of grafting was investigated. 相似文献
24.
The simulation and experimental studies of an aperture‐coupled wideband dual segment rectangular dielectric resonator antenna with metamaterial for C‐band applications are presented in this paper. The antenna consists of Alumina (Al2O3) ceramic as upper segment and Teflon as lower segment. The combination of circular‐shaped coplanar split‐ring resonator and conducting strip has been used as metamaterial superstrate. With the use of metamaterial superstrate, the bandwidth of the antenna is increased by 48% through simulation and 22% experimentally. The broadside radiation pattern of the antenna is converted into directive radiation pattern with reduced beamwidth when metamaterial superstrate is used. The peak gain of the antenna is also enhanced by 33% through simulation and 31% experimentally with the use of metamaterial superstrate. © 2014 Wiley Periodicals, Inc. Int J RF and Microwave CAE 24:646–655, 2014. 相似文献
25.
Raghunath P. Tripathi Jogindar S. Bahl Ramesh C. Purohit 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1974,24(9):505-514
In the present investigation, the effect of three process variables viz., air rate, temperature and time of oxidation has been studied to determine the possibility of making paving bitumens from North Rumaila Crude Oil. In order to have flexibility in the choice of proper feedstock for bitumen production, the effect of these process parameters was studied on three different vacuum residues. Air rate and temperature of oxidation were optimised to produce a bitumen product having less temperature susceptibility. The composition studies of typical feeds and oxidised products indicate that mainly “saturates” components get converted to “asphaltics” on air blowing. 相似文献
26.
H. S. Tripathi B. Mukherjee S. Das M. K. Haldar S. K. Das A. Ghosh 《Ceramics International》2003,29(8):915-918
Stoichiometric magnesium aluminate spinel was synthesized by reaction sintering of alumina with caustic and sintered magnesia. The volume expansion of 5–7% during MgAl2O4 formation was utilized to identify the starting temperature of spinel formation and densification by high temperature dilatometry. The magnesia reactivity was determined by measurement of crystallite size and specific surface area. Caustic magnesia and sintered magnesia behave differently vis-à-vis phase formation and densification of spinel. Densification of stoichiometric Mag-Al spinel was carried out between 1650 and 1750 °C. Attempts were made to correlate the MgO reactivity with microstructure and densification of spinel. 相似文献
27.
A simplified method was proposed for the design of concrete lining in underground rock cavern/tunnel against shock loading.
The loading may result from the detonation of explosives on ground surface or ground penetration projectiles exploding adjacent
to the cavern/tunnel. The resulting problem necessitates the solution of the dynamics of a beam loaded by a transient pressure
uniformly distributed over the span. According to mechanical characteristics of the system with rock bolt and shotcrete, a
dynamic support design method based on equivalent single degree of freedom (SDOF) was put forward. The SDOF method was applied
to obtaining the maximum displacement at the mid-span of the beam, which is often the controlling factor in the blast-resistant
design. In the formulation of the problem, the proposed method combines the phenomena of spalling and structural dynamics
theory. An example is provided to demonstrate the applicability of this simplified method. 相似文献
28.
Tripathi Kuldeep Narayan Yadav Ashish Mohan Sharma S. C. 《Wireless Personal Communications》2022,124(3):2475-2504
Wireless Personal Communications - This work aims to implement a clustering scheme to separate vehicles into a cluster that is based on various parameters, such as the total number of relay nodes,... 相似文献
29.
Rashmi Mahajan Akhshay Singh Bhadwal Nishant Kumar Mukil Madhusudanan Ramesh Namdeo Pudake Ravi Mani Tripathi 《IET nanobiotechnology / IET》2017,11(4):360
The present study reports a novel, facile, biosynthesis route for the synthesis of carbon nanodots (CDs) with an approximate quantum yield of 38.5%, using Musk melon extract as a naturally derived‐precursor material. The synthesis of CDs was established by using ultraviolet–visible (UV–vis) spectroscopy, Dynamic light scattering, photoluminescence spectroscopy, X‐ray diffraction, transmission electron microscopy and Fourier transform infrared (FTIR) spectroscopy. The as‐prepared CDs possess an eminent fluorescence under UV–light (λ ex = 365 nm). The size range of CDs was found to be in the range of 5–10 nm. The authors further explored the use of such biosynthesised CDs as a photocatalyst material for removal of industrial dye. Degradation of methylene blue dye was performed in a photocatalytic reactor and monitored using UV–vis spectroscopy. The CDs show excellent dye degradation capability of 37.08% in 60 min and reaction rate of 0.0032 min−1. This study shows that synthesised CDs are highly stable in nature, and possess potential application in wastewater treatment.Inspec keywords: carbon, nanostructured materials, nanofabrication, catalysis, photochemistry, ultraviolet spectra, visible spectra, photoluminescence, X‐ray diffraction, transmission electron microscopy, Fourier transform infrared spectra, fluorescence, dyesOther keywords: green synthesis, highly stable CD, photocatalytic performance, biosynthesis route, carbon nanodots, quantum yield, Musk melon extract, naturally derived‐precursor material, ultraviolet‐visible spectroscopy, dynamic light scattering, photoluminescence spectroscopy, X‐ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, FTIR spectroscopy, fluorescence, biosynthesised CD, photocatalyst material, industrial dye, methylene blue dye degradation, photocatalytic reactor, UV‐vis spectroscopy, wastewater treatment, size 5 nm to 10 nm, time 60 min 相似文献
30.