Introducing anionic redox in layered oxides is an effective approach to breaking the capacity limit of conventional cationic redox. However, the anionic redox reaction generally suffers from excessive oxidation of lattice oxygen to O2 and O2 release, resulting in local structural deterioration and rapid capacity/voltage decay. Here, a Na0.71Li0.22Al0.05Mn0.73O2 (NLAM) cathode material is developed by introducing Al3+ into the transition metal (TM) sites. Thanks to the strong Al–O bonding strength and small Al3+ radius, the TMO2 skeleton and the holistic TM–O bonds in NLAM are comprehensively strengthened, which inhibits the excessive lattice oxygen oxidation. The obtained NLAM exhibits a high reversible capacity of 194.4 mAh g-1 at 20 mA g-1 and decent cyclability with 98.6% capacity retention over 200 cycles at 200 mA g−1. In situ characterizations reveal that the NLAM experiences phase transitions with an intermediate OP4 phase during the charge–discharge. Theoretical calculations further confirm that the Al substitution strategy is beneficial for improving the overlap between Mn 3d and O 2p orbitals. This finding sheds light on the design of layered oxide cathodes with highly reversible anionic redox for sodium storage. 相似文献
Photo-electrochemical (PEC) water splitting is a promising method for converting solar energy into clean energy, but the mechanism of improving PEC efficiency through the interfacial contact and defect strategy remains highly controversial. Herein, reduced graphene oxide (rGO) and oxygen vacancies are introduced into α-Fe2O3 nanorod (NR) arrays using a simple spin-coating method and acid treatment. The resultant oxygen vacancy–α-Fe2O3/rGO-integrated system exhibits a higher photocurrent, four times than the pristine α-Fe2O3. It is well evidenced that the electronic interface interaction between α-Fe2O3 and rGO is boosted with the oxygen vacancies, facilitating electron transfer from α-Fe2O3 to rGO. Moreover, the oxygen vacancies not only create interband states in α-Fe2O3 that can trap photogenerated holes and thus facilitate charge separation but significantly also strengthen the adsorption of oxidative intermediates and reduce the energy barrier of rate-determining step during oxygen evolution reaction (OER). This study demonstrates an rGO–oxygen vacancy synergistic interfacial contact and defect modification approach to design semiconducting photocatalysts for high-efficiency solar energy capture and conversion. The generated principle is expected to be extendable to another material system. 相似文献
Using time-series data analysis for stock-price forecasting (SPF) is complex and challenging because many factors can influence stock prices (e.g., inflation, seasonality, economic policy, societal behaviors). Such factors can be analyzed over time for SPF. Machine learning and deep learning have been shown to obtain better forecasts of stock prices than traditional approaches. This study, therefore, proposed a method to enhance the performance of an SPF system based on advanced machine learning and deep learning approaches. First, we applied extreme gradient boosting as a feature-selection technique to extract important features from high-dimensional time-series data and remove redundant features. Then, we fed selected features into a deep long short-term memory (LSTM) network to forecast stock prices. The deep LSTM network was used to reflect the temporal nature of the input time series and fully exploit future contextual information. The complex structure enables this network to capture more stochasticity within the stock price. The method does not change when applied to stock data or Forex data. Experimental results based on a Forex dataset covering 2008–2018 showed that our approach outperformed the baseline autoregressive integrated moving average approach with regard to mean absolute error, mean squared error, and root-mean-square error. 相似文献
This study aims to propose a more efficient hybrid algorithm to achieve favorable control performance for uncertain nonlinear systems. The proposed algorithm comprises a dual function-link network-based multilayer wavelet fuzzy brain emotional controller and a sign(.) functional compensator. The proposed algorithm estimates the judgment and emotion of a brain that includes two fuzzy inference systems for the amygdala network and the prefrontal cortex network via using a dual-function-link network and three sub-structures. Three sub-structures are a dual-function-link network, an amygdala network, and a prefrontal cortex network. Particularly, the dual-function-link network is used to adjust the amygdala and orbitofrontal weights separately so that the proposed algorithm can efficiently reduce the tracking error, follow the reference signal well, and achieve good performance. A Lyapunov stability function is used to determine the adaptive laws, which are used to efficiently tune the system parameters online. Simulation and experimental studies for an antilock braking system and a magnetic levitation system are presented to verify the effectiveness and advantage of the proposed algorithm.
It is of great importance to exploit electrode materials for sodium‐ion batteries (SIBs) with low cost, long life, and high‐rate capability. However, achieving quick charge and high power density is still a major challenge for most SIBs electrodes because of the sluggish sodiation kinetics. Herein, uniform and mesoporous NiS2 nanospheres are synthesized via a facile one‐step polyvinylpyrrolidone assisted method. By controlling the voltage window, the mesoporous NiS2 nanospheres present excellent electrochemical performance in SIBs. It delivers a high reversible specific capacity of 692 mA h g?1. The NiS2 anode also exhibits excellent high‐rate capability (253 mA h g?1 at 5 A g?1) and long‐term cycling performance (319 mA h g?1 capacity remained even after 1000 cycles at 0.5 A g?1). A dominant pseudocapacitance contribution is identified and verified by kinetics analysis. In addition, the amorphization and conversion reactions during the electrochemical process of the mesoporous NiS2 nanospheres is also investigated by in situ X‐ray diffraction. The impressive electrochemical performance reveals that the NiS2 offers great potential toward the development of next generation large scale energy storage. 相似文献
Introduction : We evaluated the associated factors of serum magnesium in patients on maintenance hemodialysis (MHD). Furthermore, we evaluated the relationship between low serum magnesium and arteriosclerosis in these patients. Methods : In 129 patients on MHD, we evaluated the blood levels of magnesium, brachial‐ankle pulse wave velocity (ba‐PWV), ankle‐brachial index (ABI), and intima‐media thickness of the common carotid artery (IMT). Findings : In MHD patients, the serum level of magnesium was significantly correlated with age, calcium, TNF‐α, albumin, and ba‐PWV but not with ABI or IMT. In the multiple regression analysis, albumin (P = 0.0001, β = 0.31) and calcium (P = 0.029, β = 0.18) were selected as significant predictors of the magnesium level in MHD patients. Furthermore, the serum level of magnesium, as well as systolic blood pressure (P = 0.0001, β = 0.32) and age (P = 0.005, β = 0.25), were selected as significant (P = 0.012, β = ?0.22) predictors of ba‐PWV in MHD patients. Discussion : In MHD patients, the serum magnesium level was associated with the serum levels of calcium and albumin. Furthermore, a low serum magnesium level in MHD patients was associated with the index of vascular stiffness. 相似文献
Mixed transition metal oxides (MTMOs) have received intensive attention as promising anode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). In this work, we demonstrate a facile one-step water-bath method for the preparation of graphene oxide (GO) decorated Fe2(MoO4)3 (FMO) microflower composite (FMO/GO), in which the FMO is constructed by numerous nanosheets. The resulting FMO/GO exhibits excellent electrochemical performances in both LIBs and SIBs. As the anode material for LIBs, the FMO/GO delivers a high capacity of 1,220 mAh·g–1 at 200 mA·g–1 after 50 cycles and a capacity of 685 mAh·g–1 at a high current density of 10 A·g–1. As the anode material for SIBs, the FMO/GO shows an initial discharge capacity of 571 mAh·g–1 at 100 mA·g–1, maintaining a discharge capacity of 307 mAh·g–1 after 100 cycles. The promising performance is attributed to the good electrical transport from the intimate contact between FMO and graphene oxide. This work indicates that the FMO/GO composite is a promising anode for high-performance lithium and sodium storage. 相似文献