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Science China Technological Sciences - We use 9 years data of Cluster to study the dependencies of plasma parameters and energy transport in the plasma sheet on the lasting time of... 相似文献
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Refractive index increments and density increments have been measured at 307.6K for polystyrene in binary solvents of 1,2,3,4-tetrahydronaphthalene (tetralin, TET) and cyclohexane over the whole range of solvent composition. Comparison of these increments with the corresponding values obtained at dialysis equilibrium (i.e. at constant chemical potential of low molecular weight species) yielded the coefficients of selective adsorption (γ1) of TET by the polymer. Positive values of γ1 were exhibited at solvent compositions up to 78% (v/v) of the thermodynamically better solvent, TET. Theoretical curves of γ1 vs. composition were calculated on the basis of, firstly, relevant interaction parameters and, secondly, interaction parameters in conjunction with solubility parameters. Both procedures afforded self-consistent results, which were, however, uniformly lower than the experimental values of γ1. 相似文献
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Previously obtained cloud point curves for mixtures of oligomeric poly(dimethyl siloxanes) (weight fraction W1) with oligomeric polyethylenes have been supplemented by the use of samples of higher molecular weight. Initial flat regions at low-medium W1 as well as a slight shoulder at extremely high W1 are now considered to be due to crystallization, since the temperatures at which they occur are the melting points of the oligoethylenes. The actual cloud point curves were of an unsymmetrical dome shape, the form of which could not be simulated by using a concentration-independent interaction parameter g in the Flory-Huggins equation. However, spinodals calculated by assuming a quadratic dependence of g on composition were of the same shape as the experimental cloud point curves. The critical compositions calculated on this basis were also close to the experimental ones. 相似文献
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The synthesis of a series of dyes derived from reaction of 2-methyl-4-(N-ethyl-N-hydroxyethyl)amino, lidicyano-styrene with acid chlorides, chloroformates, isocyanates and isothiocyanates is described. Data relevant to dye characterization by electron-impact induced fragmentation is reported. Dyeing and fastness properties of the dyes on cellulose secondary acetate, cellulose triacetate, nylon 6.6 and polyester fibres are discussed in terms of dye structure. Comparison is made between some related dyes derived from 2-methyl-4-(N-ethyl-N-β-aminoethyljamino-β,βdicyanostyrene. 相似文献
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The honey bee,Apis mellifera, is one of only a few species of phytophagous insects known to be unable to convert C-24 alkyl phytosterols to cholesterol.
Regardless of the dietary sterols available to worker bees, the major tissue sterol of brood reared by the workers is always
24-methylenecholesterol, followed by sitosterol and isofucosterol. Normally, little or no cholesterol is present in honey
bee sterols. The maintenance of high levels of certain sterols is accomplished through a selective transfer of sterols from
the endogenous sterol pools of the workers to the developing larvae through the brood food material secreted from the hypopharyngeal
and mandibular glands and/or the honey stomach of the workers. The selective uptake and transfer of radiolabeled C27, C28 and C29 sterols have been studied to correlate these aspects of sterol utilization with the discovery of an unusual molting hormone
(ecdysteroid) in honey bee pupae as the major ecdysteroid of this stage of development. The phylogenetic implications of this
selective transfer phenomenon in the honey bee and comparison with sterol metabolism in certain other hymenopteran species
emphasize the diversity of steroid biochemistry in insects. 相似文献
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Acrylic acid has been grafted onto nylon 6 by the mutual γ-irradiation technique. Methods are described for removing poly(acrylic acid) homopolymer and ungrfted nylon, the latter involving intermediate conversion to the calcium ionomer. The pure graft copolymer in its methylated form, viz., nylon 6/poly(methyl acrylate), NY/PMA, was characterized by light scattering in mixed solvents to yield the true molecular weight (3.2 × 106) as well as the molecular weights MPMA(domain) and MNY(domain) of the PMA and NY portions, respectively. The molecular weight MPMA of the grafts was measured after hydrolysis of the backbone, and the molecular weight MNY of the backbone was determined via a previously devised indirect procedure. Comparisons of MPMA(domain) with MPMA and of MNY(domain) with MNY gave ? 7 nylon chains and ? 17 poly(methyl acrylate) chains per copolymer molecule. Chain transfer and bimolecular terminatin during grafting are proposed as probable contributory factors to the branched structure of the copolymer. 相似文献