Mechanical properties of composites from sawdust and recycled plastics

Mechanical properties of wood plastic composites (WPCs) manufactured from sawdust and virgin and/or recycled plastics, namely high density polyethylene (HDPE) and polypropylene (PP), were studied. Sawdust was prepared from beech industrial sawdust by screening to the desired particle size and was mixed with different virgin or recycled plastics at 50% by weight fiber loading. The mixed materials were then compression molded into panels. Flexural and tensile properties and impact strength of the manufactured WPCs were determined according to the relevant standard specifications. Although composites containing PP (virgin and recycled) exhibited higher stiffness and strength than those made from HDPE (virgin and recycled), they had lower unnotched impact strengths. Mechanical properties of specimens containing recycled plastics (HDPE and PP) were statistically similar and comparable to those of composites made from virgin plastics. This was considered as a possibility to expand the use of recycled plastics in the manufacture of WPCs. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3641–3645, 2006     

Positional distribution of CLA in TAG of lamb tissues

The content and positional distribution of CLA in TAG fractions of lamb tissues was examined with either preformed CLA or the linoleic acid precursor of CLA in the diet as experimental treatments. The CLA content of phospholipid (PL) from these tissues was also examined. Thirteen lambs were randomized to the following dietary treatments: (i) control diet (no supplement); (ii) CLA supplementation (0.33 g d⁻¹ for 21 d prior to weaning) to milk-replacer of pre-ruminating lambs, or (iii) feeding linoleic acid-rich oil (6% safflower oil on a dry matter basis) to weaned ruminating lambs. At slaughter, tissue samples were procured from diaphragm, rib muscle, and subcutaneous (SC) adipose tissue. Safflower oil supplementation in the diet resulted in an increase in CLA content of the TAG from diaphragm, rib muscle, and SC adipose tissue by about threefold (P<0.05) on a mol% basis. CLA was localized to the sn-1/3 positions of TAG. Animals that received pre-formed CLA, however, had increased proportions of CLA at the sn-2 position of TAG from SC adipose tissue, suggesting that there were tissue-specific dietary effects and possible age-related effects on the mode of FA incorporation into TAG. Safflower oil supplementation in the diet had no effect on the CLA content of PL from diaphragm, rib muscle, and SC adipose tissue, suggesting that CLA was preferentially incorporated into the TAG of these tissues.     

Alternating active-phase algorithm for multimaterial topology optimization problems: a 115-line MATLAB implementation

Structural and Multidisciplinary Optimization - A new algorithm for the solution of multimaterial topology optimization problems is introduced in the present study. The presented method is based on...     

Static and dynamic mechanical properties of a kenaf fiber–wood flour/polypropylene hybrid composite

A natural fiber hybrid composite containing equal proportions of kenaf fibers (KFs) and wood flour (WF) as the reinforcements and polypropylene (PP) as the polymer matrix was prepared, and its static and dynamic mechanical properties were compared with KF/PP and WF/PP composites. Static tensile and flexural tests and dynamic mechanical analysis (DMA) were carried out. The hybrid composite exhibited tensile and flexural moduli and strength values closer to those of the KF composite, which indicated a higher reinforcing efficiency of KFs compared with WF. DMA revealed that although the glass‐transition temperature remained unchanged by the replacement of half of the WF by KFs, the α‐transition temperature of the hybrid composite was identical to that of WF composite. The magnitudes of both the α and β (glass) transitions of the hybrid composite were comparable to that of the WF/PP composite. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 665–672, 2005     

Development of dispersive liquid-liquid microextraction based on deep eutectic solvent using as complexing agent and extraction solvent: application for extraction of heavy metals

ABSTRACT

A green and efficient dispersive liquid-liquid microextraction method based on a new deep eutectic solvent has been developed for the preconcentration and extraction of cobalt and nickel ions. The deep eutectic solvent is formed by mixing choline chloride (hydrogen bond acceptor) and 4-aminophenol (hydrogen bond donor). Then, it is used as a chelating agent as well as extraction solvent. Under the optimum experimental conditions, the linear ranges for Ni(II) and Co(II) were 0.80–50 and 0.50–50 µgL^?1, respectively, by flame atomic absorption spectrometry. The obtained detection limits were 0.30 and 0.22 µg L^?1 for Ni(II) and Co(II), respectively.     

Biclustering meets triadic concept analysis

Biclustering numerical data became a popular data-mining task at the beginning of 2000’s, especially for gene expression data analysis and recommender systems. A bicluster reflects a strong association between a subset of objects and a subset of attributes in a numerical object/attribute data-table. So-called biclusters of similar values can be thought as maximal sub-tables with close values. Only few methods address a complete, correct and non-redundant enumeration of such patterns, a well-known intractable problem, while no formal framework exists. We introduce important links between biclustering and Formal Concept Analysis (FCA). Indeed, FCA is known to be, among others, a methodology for biclustering binary data. Handling numerical data is not direct, and we argue that Triadic Concept Analysis (TCA), the extension of FCA to ternary relations, provides a powerful mathematical and algorithmic framework for biclustering numerical data. We discuss hence both theoretical and computational aspects on biclustering numerical data with triadic concept analysis. These results also scale to n-dimensional numerical datasets.     

Oil thermal annealed nano‐structured indium tin oxide thin films for display applications

Indium tin oxide‐coated thin films (200 nm) are deposited on glass substrates by using R.f. sputtering technique. Here, we investigate the influence of new technique of treatment, which is called as “oil thermal annealing” on the nano‐structured indium tin oxide thin films at fixed temperature (150 °C) which improves adhesion strength, electrical conductivity and optical properties (transmittance) of the films. Oil thermal annealing is used to reduce inherent defects that may be introduced during the prepared thin film and cooling processes. Proposed technique is highly suitable for liquid crystal displays, solar cells and organic light emitting diodes, and many other display‐related applications.     

Water uptake and mechanical characteristics of natural filler–polypropylene composites

Water uptake characteristics and some mechanical properties of polypropylene composites containing three types of natural fillers, purified α‐cellulose, wastepaper fibers, and wood flour were studied. The fiber contents were 15, 25, and 35% by weight. Two percent maleic anhydride polypropylene (MAPP) was also added to the mix, as the compatibilizer agent. Mixing process was performed in a Brabender Plasticorder until a constant torque was reached. Composites made out of these combinations were then pressed in a laboratory press and ASTM standard test specimens were cut out of the sheets. Water absorption and tensile tests were performed on these specimens. The results showed a significant difference between the various filler types regarding water uptake. Water uptake also increased by the increase in filler content. Tensile strength and elongation at break in composites declined when compared with pure polypropylene, but their modulus of elasticity increased. Among the three types of fillers, no significant discrepancies were observed in terms of improving mechanical properties in composites. Filler content increase had no drastic effect regarding strength improvement. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 941–946, 2003     

Sex pheromone of tomato fruit borer, Neoleucinodes elegantalis

Five candidate pheromone components were identified by analyzing pheromone gland extracts by gas chromatography (GC), coupled GC-electroantennographic detection (EAD), and coupled GC-mass spectrometry (MS): (E)-11-hexadecenol(E11–16 : OH), (Z)-11-hexadecenol (Z11–16 : OH),(E)-11-hexadecenal, (E)-11-hexadecenyl acetate, and (Z)-3,(Z)-6,(Z)-9-tricosatriene (Z3,Z6,Z9–23 : Hy). In electroantennogram (EAG) recordings, synthetic E11–16 : OH elicited stronger antennal responses at low doses than other candidate pheromone components. Field tests demonstrated that synthetic E11–16 : OH as a trap bait was effective in attracting males, whereas addition of Z11–16 : OH inhibited the males' response. Z3,Z6,Z9–23 : Hy strongly enhanced attractiveness of E11–16 : OH, but was not attractive by itself. A pheromone blend with synergistic behavioral activity of an alcohol (E11–16 : OH) and hydrocarbon (Z3,Z6,Z9–23 : Hy) component is most unusual in the Lepidoptera. The synthetic two-component pheromone is approximately 60 times more attractive than the female-produced blend and might facilitate the control of this pest.     

Relating Sediment Yield Estimations to the Wet Front Term Using Rainfall Simulator Field Experiments

Water Resources Management - Depth to wet front is generally considered as the amount of water that penetrates into soil and wets the internal soil layer. This is an important variable especially...