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141.
晶闸管逆变式弧焊电源的主回路分析和设计 总被引:1,自引:0,他引:1
本文分析了晶闸管逆变式下降特性弧焊电源主回路的工作原理,指出了现有文献分析的不足之处,提出了逆变变压器的设计方法和换向电容、输出滤波电感电容的参数计算公式,并给出了设计实例。 相似文献
142.
旋风管内气相的湍流运动特性 总被引:2,自引:1,他引:2
利用二维激光多普勒测速仪(LDV)测量了旋风管内湍流运动的时均速度、脉动速度、能谱函数、微分尺度及湍流耗散等参数,对湍流特性参数分布进行了详细的描述,并初步分析了旋风管内湍流运动特性对颗粒分离的影响. 相似文献
143.
A new short-path distillation system applied to the reduction of cholesterol in butter and lard 总被引:5,自引:0,他引:5
Armando Lanzani Paolo Bondioli Carlo Mariani Liliana Folegatti Stefania Venturini Enzo Fedeli Pierre Barreteau 《Journal of the American Oil Chemists' Society》1994,71(6):609-614
A molecular distillation plant, built particularly to increase the separation efficiency and to obtain safer working conditions,
was tested to remove cholesterol from anhydrous butter and lard. A preliminary experiment was carried out with butter to evaluate
the fractionation obtained at temperatures between 190 and 250°C and residual pressures between 10−3 and 10−4 torr. A second experiment was carried out at 185°C and at the maximum operational vacuum, evaluating the fractionation achieved
within a time scale between 30 and 180 min. Cholesterol was almost completely removed during the second hour with minimal
loss of low-molecular weight triglycerides. An experiment was carried out with lard at 250°C and maximum achievable operational
vacuum (10−4 Torr), lasting approximately 6 h, and cholesterol was removed almost completely during the second hour without significant
modifications in the triglyceride composition. This situation remained constant throughout the duration of the test. 相似文献
144.
Cable-direct-driven-robots (CDDRs) provided with a passive serial support represent an interesting and rising evolution of planar cable robots. The paper is devoted to present and analyze a novel CDDR robot. The robot consists in a fully actuated CDDR supported against loading normal to the motion plane with a 3-link passive planar serial manipulator. This hybrid structure combines positive features of both parallel and serial architectures, and prevents out-of-plane movements without the necessity for the robot to be supported on the motion plane. The adoption of a 3-link serial manipulator ensures a greater workspace area compared with similar structures that adopt a smaller number of links, and improves specific characteristics of their dynamics. Nevertheless undesired oscillations may occur since the serial manipulator is underconstrained. For this reason damping elements are inserted in the structure. Simulation examples are presented to demonstrate the novel CDDR concept and its dynamics. In addition, a strategy to select proper values of damping coefficients is presented. 相似文献
145.
Maria?Antonietta BresciaEmail author Vincenzo?Mazzilli Angela?Sgaramella Stefano?Ghelli Francesco?Paolo Fanizzi Antonio?Sacco 《Journal of the American Oil Chemists' Society》2004,81(5):431-436
Characterization of the lipid fraction of raw cow and buffalo milk samples, collected in different breeding areas in Apulia,
a region of southern Italy, were performed by means of 1H NMR. The aim of this work was to establish whether FA composition data obtained by 1H NMR can be used in the differentiation of buffalo and cow milk samples according to species. A complete assignment of the
signals present in the spectrum was attempted by COSY, heteronuclear coherence spectra. Quantification of FA was carried out
by inserting the integrals of particular peaks in suitable calculations. Multivariate statistical analysis, conducted on the
results of the quantification, permitted buffalo and cow milks to be distinguished. 相似文献
146.
John F. Quinn Author Vitae Author Vitae Leonie Barner Author Vitae Author Vitae 《Polymer》2007,48(22):6467-6480
Ionizing radiation, such as γ, ultraviolet, microwave and X-ray radiation, has long been used in polymer chemistry as a means of initiating polymerization, crosslinking gels and decomposing particular polymer components. More recently, ionizing radiation has found application in tandem with living radical polymerization to form novel polymeric materials with defined molecular weight and narrow molecular weight distribution. In particular, γ-rays and ultraviolet light both have shown promise as sources of initiation in reversible addition-fragmentation chain transfer (RAFT) polymerization. The ability to apply these sources of initiation at low temperatures is useful in applications where elevated temperature is likely to be detrimental to the system, for instance, in preparing protein-polymer conjugates. Similarly, the use of these initiating sources at low temperature is particularly suitable for some monomers, such as allyl compounds, which have not been synthesized using any other living radical approach. The current review examines the development of ionizing radiation as a tool in RAFT polymerization, with particular reference to the elucidation of the polymerization mechanism, the synthesis of high functionality polymers and probing the kinetic parameters of the RAFT process. 相似文献
147.
Poly[3-3′(vinylcarbazole)] (PVK) was synthetized with N-vinylcarbazole as monomer by oxidative polymerization with ferric chloride. The resulting polymer was then deposited on various solid supports by using Langmuir-Schaefer (LS) method. The pressure-area isotherm of PVK revealed the possibility of compact monolayer formation at air-water interface. Different layers of PVK were doped with iodine vapours. Both scanning probe microscopy and optical microscopy images indicated a good uniformity of the films. The morphology and the thickness of PVK films were investigated using atomic force microscopy. The voltammetric investigation of I2 doped PVK showed a distinctive electrochemical behaviour. The photoinduced charge transfer across a donor/acceptor (D/A) hybrid interface provided an effective method to study the photoelectrochemical properties of the composite LS films. 相似文献
148.
The reactivity of AlN powder with water in supernatants obtained from centrifuged Si3 N4 and SiC slurries was studied by monitoring the pH versus time. Various Si3 N4 and SiC powders were used, which were fabricated by different production routes and had surfaces oxidized to different degrees. The reactivity of the AlN powder in the supernatants was found to depend strongly on the concentration of dissolved silica in these slurries relative to the surface area of the AlN powder in the slurry. The hydrolysis of AlN did not occur if the concentration of dissolved silica, with respect to the AlN powder surface, was high enough (1 mg SiO2 /(m2 AlN powder)) to form a layer of aluminosilicates on the AlN powder surface. This assumption was verified by measuring the pH of more concentrated (31 vol%) Si3 N4 and SiC suspensions also including 5 wt% of AlN powder (with respect to the solids). 相似文献
149.
An Adaptive and Optimized Switching Observer for Sensorless Control of an Electromagnetic Valve Actuator in Camless Internal Combustion Engines 下载免费PDF全文
Paolo Mercorelli 《Asian journal of control》2014,16(4):959-973
In this paper, the design and operation of a special electromagnetic actuator as a variable engine valve actuator are presented. Further, this paper describes a feasible approximated velocity switching estimator based on measurements of current and input voltage to achieve sensorless control. The proposed concept allows a reduced‐order observer to be conceived and yields a specific control strategy with an acceptable performance. In general, this approach represents a viable strategy to build reduced‐order observers for estimating the velocity of systems through the measurement of input current and voltage. The robustness of the velocity tracking is explored using a minimum variance approach. The effect of the noise is minimized, and the position can be achieved through an adaptive and optimized structure by combining this particular velocity estimator and an observer based on the electromechanical system. Position control is achieved through an inversion of the model. This approach avoids a more complex structure for the observer and yields an acceptable performance as well as eliminating bulky position‐sensor systems. In addition, a control strategy is presented and discussed. Computer simulations of the sensorless control structure are presented in which the positive effects of the observer with optimized parameter setting are visible in the closed‐loop control. 相似文献
150.
Electrochemical characterization of 8-hydroxyquinoline-5-sulphonate/aluminium(III) aqueous solutions
Denis Badocco Annalisa Dean Valerio Di Marco Paolo Pastore 《Electrochimica acta》2007,52(28):7920-7926
8-Hydroxyquinoline-5-sulphonate/Al(III) aqueous solutions were studied both by potentiometric titrations and voltammetric measurements, in order to obtain the number, the stoichiometry and the stability constants of the complexes formed at equilibrium, and to evaluate the redox and (electro)kinetic properties of the free ligand and of the metal/ligand complexes. The complexes formed in 0.2 m (Na)Cl aqueous solution (stability log beta values ± standard deviation) are AlL+ (8.95 ± 0.05), AlL2− (17.43 ± 0.03) and AlL33− (24.58 ± 0.05), where “L” denotes the free ligand in the completely deprotonated form (L2−, pKa1 = 3.910 ± 0.008, pKa2 = 8.319 ± 0.004). AlL33− is the predominant Al(III) species in a very wide range of pH, metal and ligand concentrations and metal-to-ligand ratios. The free ligand shows an oxidation wave at 0.62 V versus SCE. The proposed oxidation mechanism includes a first reversible one-electron oxidation of the ligand, followed by a coupling reaction and by a second reversible one-electron oxidation, and finally by a decomposition reaction. The addition of Al(III) lowers the intensity of the oxidation wave due to the formation of the redox-inactive complex AlL33−. A residual low signal was attributed to the free ligand produced by the complex dissociation, AlL33− = AlL2− + L2−. All the kinetic parameters involved in the ligand oxidation and in the complex disruption were calculated on the basis of the agreement between experimental and simulated linear sweep and cyclic voltammetries. Correctness of the mechanisms proposed was further confirmed “a posteriori” by the agreement between potentiometric and linear sweep voltammetric results. The low residual signal observed in the presence of fully formed complex was attributed to the free ligand produced by the complex dissociation, having a kinetic constant estimated 0.2 s−1. 相似文献