全文获取类型
收费全文 | 674篇 |
免费 | 39篇 |
专业分类
电工技术 | 8篇 |
化学工业 | 143篇 |
金属工艺 | 1篇 |
机械仪表 | 14篇 |
建筑科学 | 60篇 |
矿业工程 | 1篇 |
能源动力 | 18篇 |
轻工业 | 101篇 |
水利工程 | 25篇 |
石油天然气 | 2篇 |
无线电 | 52篇 |
一般工业技术 | 96篇 |
冶金工业 | 17篇 |
原子能技术 | 3篇 |
自动化技术 | 172篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 18篇 |
2020年 | 18篇 |
2019年 | 18篇 |
2018年 | 19篇 |
2017年 | 29篇 |
2016年 | 28篇 |
2015年 | 16篇 |
2014年 | 39篇 |
2013年 | 77篇 |
2012年 | 44篇 |
2011年 | 48篇 |
2010年 | 38篇 |
2009年 | 27篇 |
2008年 | 40篇 |
2007年 | 29篇 |
2006年 | 24篇 |
2005年 | 22篇 |
2004年 | 17篇 |
2003年 | 10篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 10篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 2篇 |
排序方式: 共有713条查询结果,搜索用时 99 毫秒
71.
Due to process stability and excellent effluent quality, the use of membrane processes is rapidly expanding. However, a drawback is the production of concentrates and their proper disposal. In this study, reverse osmosis concentrate was treated by Fenton and O3/UV oxidation processes. The concentrate contains halogenated compounds, recalcitrant COD and low biodegradability. The removal of halogenated compounds and the enhancement of biodegradability were examined. Comparing the investigated processes, Fenton oxidation resulted in a better mineralization of organic matter; however, O3/UV oxidation achieved a better enhancement of the biodegradability. Furthermore, similar degradation of halogenated compounds were observed for both oxidation processes. 相似文献
72.
Most simulations of colloidal suspensions treat the solvent implicitly or as a continuum. However as particle size decreases to the nanometer scale, this approximation fails and one needs to treat the solvent explicitly. Due to the large number of smaller solvent particles, such simulations are computationally challenging. Additionally, as the ratio of nanoparticle size to solvent size increases, commonly-used molecular dynamics algorithms for neighbor finding and parallel communication become inefficient. Here we present modified algorithms that enable fast single processor performance and reasonable parallel scalability for mixtures with a wide range of particle size ratios. The methods developed are applicable for any system with widely varying force distance cutoffs, independent of particle sizes and independent of the interaction potential. As a demonstration of the new algorithm's effectiveness, we present results for the pair correlation function and diffusion constant for mixtures where colloidal particles interact via integrated potentials. In these systems, with nanoparticles 20 times larger than the surrounding solvent particles, our parallel molecular dynamics code runs more than 100 times faster using the new algorithms. 相似文献
73.
The force transfer between concrete and reinforcement depends on the bond characteristics between the two materials. Bond influences crack widths and the deflections of RC members and also determines anchorage and splice lengths. Self-compacting concrete (SCC) is characterized by a smaller amount of coarse aggregates when compared to conventional vibrated concrete. To investigate whether this change in mix design has a significant influence on the bond behaviour, a series of beam tests (according to RILEM recommendation RC6) was performed. A total of 36 specimens were cast using 3 different concrete types: one conventional vibrated concrete (CVC) and two powder-type SCC’s. The bond stress—slip behaviour of reinforcing bars with diameters ranging from 12 to 40 mm has been recorded. From these tests, it can be concluded that the bond strength of SCC is even higher than it is for CVC for small bar diameters, but the difference becomes smaller for larger bar diameters. 相似文献
74.
Pieter Bauwens Ann Monté Wim Christiaens Jan Doutreloigne Jan Vanfleteren 《Displays》2009,30(2):71-76
One of the major problems with PM displays is that, depending on the used display material, only a limited number of lines can be multiplexed. We developed a new driving technology and display setup that takes care of that problem. We divided the display into several independent parts or modules. Each module acts as an individual display and has its own display driver. With the use of the new ultra-thin chip package (UTCP), these driver chips can be embedded into the (flexible) display itself. This paper explains the setup of the fully modular display and describes the basic structure of the display drivers and its components. 相似文献
75.
Pieter Hooijmans 《电子产品世界》2005,(18):58-62
未来消费电子产品的RF应用将向更高的载波频率方向发展.这种趋势已经初现端倪,新提议的IEEE-802.11a数字网络标准在5GHz频率工作,超宽带(UWB)的带宽要求则介于3GHz和10GHz之间.汽车防撞雷达的工作频率是25GHz,而多种IEEE 802.16WirelessMAN(无线城域网)标准、本地多点分布式服务(LMDS)网络和卫星返回通道所需的带宽位于25GHz到 35GHz之间(参见图1). 相似文献
76.
Eugne T. W. M. Schipper Alexander H. C. Roelofs Pieter Piet Anton L. German 《Polymer International》1994,33(1):79-86
In order to study the promoting effect of polycations on the cobalt(II)phthalocyanine-tetrasodiumsulphonate (CoPc(NaSO3)4)-catalysed autoxidation of thiols, it is imperative to know the molecular weight dependence of the polymer. Monodisperse oligomers can often supply a lot of information. To elecidate the mechanism of the promoting effect of 2,4-ionene, a poly(quaternary ammonium)salt, on the CoPc(NaSO3)4-catalysed autoxidation of 2-mercaptoethanol, a series of monodisperse 2,4-ionene oligomers were prepared. Trimeric 2,4-ionenes, containing two quaternary ammonium groups separated by four methylene groups, showed a high co-catalytic activity, and active Co-aggregates were detected with visible light spectroscopy. The spectroscopic behaviour was in close agreement with that of high molecular 2,4-ionene/CoPc(NaSO3)4 complexes. In order to achieve this aggregation several oligomeric ionenes have to act concertedly. If the distance between the ionic sites is short the trimer acts as a simple salt in stablizing the aggregates. With respect to the catalytic activity the optimum polycation/catalyst ratio, expressed as the N+/Co ratio, decreased with increasing chain lenght and reached a constant level of 50 at a 2,4-ionene nonamer. For the trimers and pentamers this ratio is affected by the type of end-group. All synthesized 2,4-ionene oligomers exhibited excellent co-catalytic properties at the optimum N+/Co ratio, with maximum turnover frequencies of 4600 mol thiol/(mol Co s), i.e. 50 times higher than those obtained for the polymer-free system. In the case of monodisperse 2,4-ionene pentamer with bromo end-groups, double Michaelis–Menten kinetics were observed, as also was exhibited by high molecular weight ionene. 相似文献
77.
Alexandru I. Petrisor Sandra Szyjka Tomohiro Kawaguchi Pieter T. Visscher Robert Sean Norman Alan W. Decho 《International journal of molecular sciences》2014,15(1):850-877
Microspatial arrangements of sulfate-reducing microorganisms (SRM) in surface microbial mats (~1.5 mm) forming open marine stromatolites were investigated. Previous research revealed three different mat types associated with these stromatolites, each with a unique petrographic signature. Here we focused on comparing “non-lithifying” (Type-1) and “lithifying” (Type-2) mats. Our results revealed three major trends: (1) Molecular typing using the dsrA probe revealed a shift in the SRM community composition between Type-1 and Type-2 mats. Fluorescence in-situ hybridization (FISH) coupled to confocal scanning-laser microscopy (CSLM)-based image analyses, and 35SO4
2−-silver foil patterns showed that SRM were present in surfaces of both mat types, but in significantly (p < 0.05) higher abundances in Type-2 mats. Over 85% of SRM cells in the top 0.5 mm of Type-2 mats were contained in a dense 130 μm thick horizontal layer comprised of clusters of varying sizes; (2) Microspatial mapping revealed that locations of SRM and CaCO3 precipitation were significantly correlated (p < 0.05); (3) Extracts from Type-2 mats contained acylhomoserine-lactones (C4-, C6-, oxo-C6 C7-, C8-, C10-, C12-, C14-AHLs) involved in cell-cell communication. Similar AHLs were produced by SRM mat-isolates. These trends suggest that development of a microspatially-organized SRM community is closely-associated with the hallmark transition of stromatolite surface mats from a non-lithifying to a lithifying state. 相似文献
78.
79.
Joost Van Aelst Danny Verboekend An Philippaerts Nicolas Nuttens Mert Kurttepeli Elena Gobechiya Mohamed Haouas Sreeprasanth P. Sree Joeri F. M. Denayer Johan A. Martens Christine E. A. Kirschhock Francis Taulelle Sara Bals Gino V. Baron Pierre A. Jacobs Bert F. Sels 《Advanced functional materials》2015,25(46):7130-7144
Hierarchical zeolites are a class of superior catalysts which couples the intrinsic zeolitic properties to enhanced accessibility and intracrystalline mass transport to and from the active sites. The design of hierarchical USY (Ultra‐Stable Y) catalysts is achieved using a sustainable postsynthetic room temperature treatment with mildly alkaline NH4OH (0.02 m ) solutions. Starting from a commercial dealuminated USY zeolite (Si/Al = 47), a hierarchical material is obtained by selective and tuneable creation of interconnected and accessible small mesopores (2–6 nm). In addition, the treatment immediately yields the NH4+ form without the need for additional ion exchange. After NH4OH modification, the crystal morphology is retained, whereas the microporosity and relative crystallinity are decreased. The gradual formation of dense amorphous phases throughout the crystal without significant framework atom leaching rationalizes the very high material yields (>90%). The superior catalytic performance of the developed hierarchical zeolites is demonstrated in the acid‐catalyzed isomerization of α‐pinene and the metal‐catalyzed conjugation of safflower oil. Significant improvements in activity and selectivity are attained, as well as a lowered susceptibility to deactivation. The catalytic performance is intimately related to the introduced mesopores, hence enhanced mass transport capacity, and the retained intrinsic zeolitic properties. 相似文献
80.
Hierarchical Zeolite: Catalyst Design by NH4OH Treatment of USY Zeolite (Adv. Funct. Mater. 46/2015) 下载免费PDF全文
Joost Van Aelst Danny Verboekend An Philippaerts Nicolas Nuttens Mert Kurttepeli Elena Gobechiya Mohamed Haouas Sreeprasanth P. Sree Joeri F. M. Denayer Johan A. Martens Christine E. A. Kirschhock Francis Taulelle Sara Bals Gino V. Baron Pierre A. Jacobs Bert F. Sels 《Advanced functional materials》2015,25(46):7244-7244