The fabrication of exfoliated graphite sheet-based air cathodes and gel electrolyte for metal-air batteries

In this paper, we demonstrate that activated carbon (AC) and manganese dioxide (MnO₂) coated exfoliated graphite sheets are a promising cathode for metal-air batteries. A simple and effective method is developed to exfoliate the graphite sheets and to load a catalyst onto their surfaces. Several low-cost, environmentally friendly air cathodes are fabricated, and their performances are tested by constructing Al-air b`atteries whose electrolyte 6 M NaOH, including ZnO inhibitor, is gelled by adding a cost-effective water retainer. The experimental results show that this new Al-air battery has a good discharge performance. In particular one of the new cathodes containing 50 wt% AC and 50 wt% MnO₂ produces a capacity of 311 mAh/g at a constant current discharge of 1.56 mA. Finally, future research directions are discussed for the further usage of the fabricated cathodes.     

The impact of data aggregation on the performance of wireless sensor networks

With the increasing need for different energy saving mechanisms in Wireless Sensor Networks (WSNs), data aggregation techniques for reducing the number of data transmissions by eliminating redundant information have been studied as a significant research problem. These studies have shown that data aggregation in WSNs may produce various trade‐offs among some network related performance metrics such as energy, latency, accuracy, fault‐tolerance and security. In this paper, we investigate the impact of data aggregation on these networking metrics by surveying the existing data aggregation protocols in WSNs. Our aim is twofold: First, providing a comprehensive summary and comparison of the existing data aggregation techniques with respect to different networking metrics. Second, pointing out both the possible future research issues and the need for collaboration between data management and networking research communities working on data aggregation in WSNs. Copyright © 2006 John Wiley & Sons, Ltd.     

Gold‐supported activated NiZn coatings: hydrogen evolution and corrosion studies

Gold‐supported Raney‐type NiZn coatings were prepared on a thin Ni film‐modified copper substrate (Cu/Ni/NiZn‐Au). The hydrogen evolution activity, time stability and corrosion behaviour of the electrode was investigated in 1 M KOH solution by electrochemical, microscopic and spectroscopic technique. It was found that Au‐modified activated coatings exhibits good hydrogen evolution activity, electrochemical and physical stability as well as corrosion resistance. The enhanced hydrogen evolution activity of the Au‐modified electrode was related to the larger available surface area and/or a possible synergistic effect between the metals. Copyright © 2017 John Wiley & Sons, Ltd.     

Extraction and reliable determination of acrylamide from thermally processed foods using ionic liquid-based ultrasound-assisted selective microextraction combined with spectrophotometry

Acrylamide (AAm) is a carcinogenic chemical that can form in thermally processed foods by the Maillard reaction of glucose with asparagine. AAm can easily be formed especially in frequently consumed chips and cereal-based foods depending on processing conditions. Considering these properties of AAm, a new, simple and green method is proposed for the extraction of AAm from thermally processed food samples. In this study, an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate, [Bmim][BF₄]) as extractant was used in the presence of a cationic phenazine group dye, 3,7-diamino-5-phenylphenazinium chloride (PSH⁺, phenosafranine) at pH 7.5 for the extraction of AAm as an ion-pair complex from selected samples. Under optimum conditions, the analytical features obtained for the proposed method were as follows; linear working range, the limits of detection (LOD, 3S_b/m) and quantification (LOQ, 10S_b/m), preconcentration factor, sensitivity enhancement factor, sample volume and recovery% were 2.2–350 µg kg^?1, 0.7 µg kg^?1, 2.3 µg kg^?1, 120, 95, 60 mL and 94.1–102.7%, respectively. The validity of the method was tested by analysis of two certified reference materials (CRMs) and intra-day and inter-day precision studies. Finally, the method was successfully applied to the determination of AAm levels in thermally processed foods using the standard addition method.     

The stability of hydrogen evolution activity and corrosion behavior of NiCu coatings with long-term electrolysis in alkaline solution

In this study, NiCu composite coating was electrochemically deposited on a copper electrode (Cu/NiCu) and tested for hydrogen evolution reaction (HER) in 1 M KOH solution for long-term electrolysis with the help of cathodic current–potential curves and electrochemical impedance spectroscopy (EIS) techniques. The bulk and surface composition of the coating was determined using atomic absorption spectroscopy (AAS) and energy dispersive X-ray (EDX) analysis. The surface morphology was investigated by scanning electron microscopy (SEM). The effect of electrolysis on the corrosion behavior of the Cu/NiCu electrode was also reported. It was found that the NiCu coating had a compact and porous structure with good time stability. The HER activity of the coating was stable over 120 h electrolysis and the HER mechanism was not modified during the operation. The corrosion tests showed that the corrosion resistance of the Cu/NiCu electrode changed when a cathodic current was applied to the electrolysis system.     

Detecting stock-price manipulation in an emerging market: The case of Turkey

This paper aims to develop methods that are capable of detecting manipulation in the Istanbul Stock Exchange. We take the difference between manipulated stock’s and index’s average daily return, average daily change in trading volume and average daily volatility and used these statistics as explanatory variables. The data in post-manipulation and pre-manipulation periods are used as non-manipulated instances while the data in the manipulation period are used as manipulated instances. Test performance of classification accuracy, sensitivity and specificity statistics for Artificial Neural Networks (ANN) and Support Vector Machine (SVM) are compared with the results of discriminant analysis and logistics regression (logit). We found that the data mining techniques (ANN and SVM) are better suited to detect stock-price manipulation than multivariate statistical techniques (discriminant analysis, logistics regression) as the performances of the data mining techniques in terms of total classification accuracy and sensitivity statistics are better than those of multivariate techniques. We also found that unit change in difference between average daily return of manipulated stock and the index has the largest effect while unit change in difference between average daily change in trading volume of manipulated stock and index has the least effect on multivariate classifiers’ decision functions.     

PressBase : a presentation synchronization database for distributed multimedia systems

Multimedia presentations are the basic objects of multimedia databases. Since a multimedia presentation is not an instant display of a query result, the control knowledge (or synchronization requirements) has to be incorporated into the database and necessary precautions have to be taken for a lengthy presentation. Active databases provide a mechanism for incorporation of control knowledge by using event-condition-action (ECA) rules. In this paper, we describe how multimedia synchronization can be handled within a database using ECA rules. We present a prototype presentation synchronization database, named as PressBase, for distributed multimedia systems. We have adopted one of the synchronization models, SynchRuler, and then incorporated into a relational database system.     

PLUS: a probe-loss utilization streaming mechanism for distributed multimedia presentation systems

We present a new flow and congestion control scheme, PLUS (Probe-Loss Utilization Streaming protocol), for distributed multimedia presentation systems. This scheme utilizes probing of the network situation and an effective adjustment mechanism to data loss to support multimedia presentations. The proposed scheme is also designed to scale with increasing number of PLUS-based streaming traffic and to live in harmony with TCP-based traffic. The novelty of the PLUS protocol is that it utilizes the knowledge of its future bottleneck bandwidth in probing the current network situation. This can be achieved by a priori knowledge of the multimedia data before a presentation is requested by a client. Compression schemes like MPEG introduce dependencies on media units. I frames are needed to successfully decode P and B frames, and P frames are needed to decode B frames. A loss of an I or P frame automatically eliminates dependent media units. Our probing scheme increases the successful transmission of critical I and P packets without the overhead of error-correction-schemes. Probing is done using B-frame packets. The advantage is that we use data packets as probe packets. With the PLUS protocol we address the need to avoid congestion rather than react to it. Experiments demonstrate the effectiveness of the approach in utilizing network resources and decreasing loss ratios.     

Designing of a powder compressing device with vibration and investigation of compressibility of MgO powders with this device

One of metal matrix composite (MMC) production methods is infiltration of liquid metal into preformed reinforcement. In this method, MMCs are produced by infiltration of liquid metal into preformed reinforcement using one of pressure, vacuum or pressureless (free) infiltration methods. For infiltration purposes, reinforcement materials in different figuration are preformed in desired shape and reinforcement volume ratio. In this study a vibration apparatus has been designed to compress the particulate reinforcement in a tube so that pressure or vacuum infiltration can be carried out. The compressibility of MgO powders with different sizes with this apparatus has also been investigated. It has been found that with this apparatus, it is possible to compress desired number of specimens uniformly at the same time and at the same ratio. It has also been determined that MgO powders can be compressed in different ratio due to particle sizes with this device. Compressing time of 3 min is enough to reach maximum compression ratio in MgO powders.