Thin films of iron oxide by low pressure MOCVD using a novel precursor: tris(t-butyl-3-oxo-butanoato)iron(III)

Deposition of thin films of iron oxide on glass has been carried out using a novel precursor, tris(t-butyl-3-oxo-butanoato)iron(III), in a low-pressure metalorganic chemical vapor deposition (MOCVD) system. The new precursor was characterized for its thermal properties by thermogravimetry and differential thermal analysis. The films were characterized by X-ray diffraction (XRD), transmission electron microscopy, scanning electron microscopy, and by optical measurements. XRD studies reveal that films grown at substrate temperatures below ∼550 °C and at low oxygen flow rates comprise only the phase Fe₃O₄ (magnetite). At higher temperatures and at higher oxygen flow rates, an increasing proportion of α-Fe₂O₃ is formed along with Fe₃O₄. Films of magnetite grown under different reactive ambients—oxygen and nitrous oxide—have very different morphologies, as revealed by scanning electron microscopic studies.     

Interpolymer association between phenolic copolymers and polyelectrolytes: effects of copolymer structure and hydrophobic interactions on the stability of polycomplexes

Summary Phenolic copolymers have been prepared with two different feed compositions from some typical phenolic monomers, such as, p-Chlorophenol, p-Cresol and p-Aminophenol. They have been characterized by known methods. Some interpolymer complexes of the phenolic copolymers have been prepared with polyelectrolytes, such as poly(methacrylic acid) (PMA) and poly(ethylene imine)(PEI). The degree of linkage, stability constant, enthalpy and entropy changes of the systems were determined at several temperatures. Interpretations have been sought in terms of the various interacting forces involved in the complex formation.     

Free convection in a non-Darcian wavy porous enclosure

A numerical study of non-Darcian natural convection in a wavy vertical enclosure filled with a porous medium is performed. The flow is modelled using Forchheimer extended Darcy model. The governing equations are solved by finite element method. Numerical results demonstrate the importance of non-Darcian effect. Cumulative heat flux and Nusselt number together with flow and temperature distributions in the form of streamlines and isotherms are presented for a wide range of governing parameters like Grashof number, Rayleigh number, wave amplitude, wave phase and roughness parameter.     

Electron beam induced synthesis of CdSe nanomaterials: Tuning of shapes from rods to cubes

Cadmium selenide (CdSe) nanomaterials of different shapes have been synthesized in the water pool of the water-in-oil microemulsions through 7 MeV electron beam irradiation. The rod shaped CdSe nanomaterials of lengths and breadths up to 1 μm and 200 nm, respectively with aspect ratios from 3 to 5 were grown in the case of microemulsions containing lower water content, water to surfactant concentrations ratio, w₀ = 10. In contrast, the cubic shaped CdSe nanomaterials of dimensions about 100 nm were formed in the microemulsions with higher water contents, w₀ values from 20 to 40. Such a transformation of shape from rod to cube was attributed to the change in the hydrophobicity and hydrophilicity of the micro-environment in the microemulsions. The as-grown CdSe nanomaterials were stable at ambient conditions and thus expected to be very useful in the device applications.     

Acid base catalyzed transesterification kinetics of waste cooking oil

The present study reports the results of kinetics study of acid base catalyzed two step transesterification process of waste cooking oil, carried out at pre-determined optimum temperature of 65 °C and 50 °C for esterification and transesterification process respectively under the optimum condition of methanol to oil ratio of 3:7 (v/v), catalyst concentration 1%(w/w) for H₂SO₄ and NaOH and 400 rpm of stirring. The optimum temperature was determined based on the yield of ME at different temperature. Simply, the optimum concentration of H₂SO₄ and NaOH was determined with respect to ME Yield. The results indicated that both esterification and transesterification reaction are of first order rate reaction with reaction rate constant of 0.0031 min^− 1 and 0.0078 min^− 1 respectively showing that the former is a slower process than the later. The maximum yield of 21.50% of ME during esterification and 90.6% from transesterification of pretreated WCO has been obtained. This is the first study of its kind which deals with simplified kinetics of two step acid-base catalyzed transesterification process carried under the above optimum conditions and took about 6 h for complete conversion of TG to ME with least amount of activation energy. Also various parameters related to experiments are optimized with respect to ME yield.     

Nanoparticles of Transition Metals as Accelerants in the Thermal Decomposition of Ammonium Perchlorate,Part 62

Four transition metal nanoparticles (TMNs) of 3d series (Cu, Co, Ni, and Fe) were prepared by hydrazine reduction of metal chloride in ethylene glycol at 60°C and characterized by X-ray diffraction (XRD). The XRD pattern showed average particle sizes for Cu, Ni, Co, and Fe of 16.7, 40.5, 27.4, and 35.0 nm, respectively. The activity of these TMN accelerants on the thermal decomposition of ammonium perchlorate (AP) was investigated using thermogravimetry (TG), differential scanning calorimetry (DSC), and ignition delay studies. Isothermal TG data were used to evaluate the kinetic parameters by model fitting as well as an isoconversional methods. The activation energy for thermal decomposition of AP was found to be 66.8, 68.7, 78.5, and 85.4 kJmol^?1, respectively, for Co, Cu, Ni, and Fe, when they were mixed with AP. Hence, the order of activity was found to be Co > Cu > Ni > Fe. The accelerant effect of nanoparticles of TMNs was found to be better than their respective nano-oxides.     

Physicochemical,rheological, and organoleptic characteristics of wheat‐fenugreek supplemented blends

The effect of blending of fenugreek (raw, soaked, and germinated) flour (Trigonella faenum graecum) from 5 to 20% in wheat flour on the rheological and sensory evaluation of bread, biscuit, noodle, and macroni was studied. Farinograph water absorption, dough development time, mixing tolerance index, and dough stability increased significantly with increased amount of fenugreek flour. Incorporation of fenugreek flour in wheat flour increased the protein and fat contents of blends but decreased the gluten contents. Among the supplemented blends, blends containing germinated fenugreek flour had higher protein contents (13.83–16.30%) up to 20%. Overall acceptability scores of bread, biscuit, noodles, and macroni were found highly acceptable up to 15, 10, and 20% levels, respectively.     

A Co-Existence Power Domain Non-Orthogonal Multiple Access Using Walsh-Hadamard and Pseudo-Noise Waveforms

Wireless Personal Communications - Non-orthogonal multiple access (NOMA) is one of the promising techniques anticipated in the upcoming wireless systems. This paper introduces a NOMA technique...     

Enhancing Detection of R2L Attacks by Multistage Clustering Based Outlier Detection

Wireless Personal Communications - The modern society is greatly benefited by the advancement of Internet. The contemporary humanity is significantly profited by the Internet. The ease of access to...     

Cauliflower-like poly(3,4-ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor

A cauliflower-like ternary nanocomposite of poly(3,4-ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide (PEDOT/NCC/MnO₂) was synthesized using one-step electropolymerization technique. The effect of manganese (Mn) concentration on the supercapacitive performance was investigated. The structural and morphology studies were conducted using field emission scanning electron microscope, Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray diffraction. The morphology of ternary nanocomposite at an optimized concentration of Mn resembles the cauliflower-like structure. The two-electrode electrochemical analysis of a ternary nanocomposite PEDOT/NCC/MnO₂ exhibited a higher specific capacitance of 144.69 F/g at 25 mV/s in 1.0 M potassium chloride compared to PEDOT/NCC(63.57 F/g). PEDOT/NCC/MnO₂ ternary nanocomposite was able to deliver a specific power of 494.9 W/kg and 10.3 Wh/kg of specific energy at 1 A g⁻¹ and retained 83% of initial capacitance after 2,000 cycles. These promising results from the incorporation of Mn displayed great prospective in developing PEDOT/NCC/MnO₂ as an electrode material for supercapacitor.