Highly active sites of low spin FeⅡN4species:The identification and the ORR performance

Over recent years,catalytic materials of Fe-N-C species have been recognized being active for oxygen reduction reaction(ORR).However,the identification of active site remains challenging as it generally involves a pyrolysis process and mixed components being obtained.Herein Fe₃C/C and Fe₂N/C samples were synthesized by temperature programmed reduction of Fe precursors in 15%CH₄/H₂and pure NH₃,respectively.By acid leaching of Fe₂N/C sample,only single sites of FeN₄species were presented,providing an ideal model for identification of catalytic functions of the single sites of FeN₄in ORR.A correlation was conducted between the concentration of Fe^ⅡN₄in low spin state by Mossbauer spectra and the kinetic current density at 0.8 V in alkaline media,and such a structure-performance correlation assures the catalytic roles of low spin Fe^ⅡN₄ species as highly active sites for the ORR.     

高瓦斯突出矿井底抽巷一巷多用技术研究与实践

胡底煤业为高瓦斯高突出高矿压的三高矿井。对高瓦斯高突出的治理，该矿采用“地面网络预抽、区域模块降量、底抽穿层保掘、高位顺层保采”的四级模式，施工底抽巷，实现“底抽穿层消突、区域模块降量、异巷探测增效、多巷通风治患、循环排矸减压”等“一巷多用”。该4种方法已在1303（上）、1305（上）工作面应用并推广，取得了良好的效果，大大提高了掘进效率且满足抽放、探放水、通风需要；回填矸石初步设计现已经完善，待下一步掘进将实现填矸作用。     

生物氧化预处理中进气量实时预测数学模型研究

精准预测生物氧化预处理中的进气量对提高黄金提取率和节能降耗具有重要意义。以气体管流连续性方程和运动方程为控制方程，采用Preissmann隐格式法作为差分方法。同时，根据集合卡尔曼滤波(Ensemble Kalman filter，EnKF)算法原理，构造进气量、压强的状态空间模型。结果表明，基于气体管流控制方程建立的进气量模型预测结果与实际进气量观测值具有较好的一致性；与传统静态预测方法相比，EnKF同化方法引入实时观测值和模型参数的更新，有效提高了进气量的预测精度，其平均绝对误差、平均相对误差和均方根误差有明显的降低。可见，基于气体管流控制方程建立的预测模型结合EnKF同化方法是提高生物氧化槽进气量预测精度的有效手段。     

基于空气质量模拟的江苏省大气污染物排放清单比较研究

大气污染物排放清单是空气质量模拟和空气污染治理的重要依据.本研究比较分析了两套覆盖江苏省的2017年大气污染物排放清单，即分别由上海市环境科学研究院、江苏省环境科学研究院编制的"长三角清单"和"江苏省清单"，并结合区域空气质量模型CMAQ评估不同清单对长三角地区2017年1、4、7、10月的空气质量模拟的影响.清单比较结果表明，除二氧化硫（SO₂）以外，江苏省清单估算的各污染物排放量较长三角清单低.通过与观测数据比较，发现两套清单对SO₂、氮氧化物（NO_x）、臭氧（O₃）和细颗粒物（PM_2.5）的模型模拟性能均较好.江苏省清单与长三角清单两者的模拟结果空间分布接近，其中江苏省清单模拟的PM_2.5和O₃在长三角多数地区略低于长三角清单的模拟结果（1月O₃除外）.江苏省清单与长三角清单均能够用于空气质量模式模拟，可为江苏地区的细颗粒物和光化学烟雾污染的控制策略制定提供参考.     

亮色系建筑涂料色浆的研制及应用

阐述了自制亮色系色浆的必要性。介绍了自制亮色系色浆的颜料筛选,配方调整及其在建筑涂料中应用后对面漆性能的影响。     

换能器结构参数对聚合物超声塑化黏弹生热的影响

为研究超声换能器结构参数对聚合物超声塑化过程黏弹性生热的影响，首先确定超声黏弹性生热系统的组成，进行纵振超声换能器结构设计；然后分析超声黏弹性生热过程及超声黏弹性生热原理；最后采用单一变量法分析超声换能器的主要结构参数对其纵振频率及工具头前端质点最大振幅的影响，将其实际输出的纵振激励加载于熔融聚合物，研究其结构参数对聚合物超声黏弹性生热过程及达到聚合物玻璃化转变温度所用时间的影响。结果表明，随纵振激励作用时间的增加，聚合物温度非线性升高；放大比对聚合物温度变化影响最大，前盖板厚度和工具头长度次之，影响最小的是变幅杆长度。     

改性剂用量对紫炭黑填充天然橡胶/顺丁橡胶并用胶性能的影响

研究改性剂（间苯二酚/六次亚甲基四胺共混物）用量对紫炭黑填充天然橡胶/顺丁橡胶并用胶性能的影响。结果表明：随着改性剂用量增大，胶料的硬度和定伸应力提高，拉伸强度、撕裂强度先下降后提高，阿克隆磨耗量先增大后减小；当改性剂/紫炭黑用量比为4%时，胶料的物理性能较好。添加改性剂可提高紫炭黑对胶料的补强作用，并在一定程度上改善胶料的热稳定性。     

Preparation of Silver Nanowires via a Rapid,Scalable and Green Pathway

Rapid synthesis of silver nanowires(Ag NWs) with high quality and a broad processing window is challenging because of the low selectivity of the formation of multiply twinned particles at the nucleation stage for subsequent Ag NWs growth.Herein we report a systematic study of the water-involved heterogeneous nucleation of Ag NWs with high rate(less than 20 min) in a simple and scalable preparation method.Using glycerol as a reducing agent and a solvent with a high boiling point,the reaction is rapidly heated to 210 ℃ in air to synthesize Ag NWs with a very high yield in gram level.It is noted that the addition of a small dose of water plays a key role for obtaining highly pure Ag NWs in high yield,and the optimal water/glycerol ratio is0.25%.After investigating a series of forming factors including reaction temperature and dose of catalysts,the formation kinetics and mechanism of the Ag NWs are proposed.Compared to other preparation methods,our strategy is simple and reproducible.These Ag NWs show a strong Raman enhancement effect for organic molecules on their surface.