Optical,Morphological, and Structural Properties of Tablets Obtained from Porous Silicon

Silicon - Porous silicon (PS) is a material with a great interest due to its optical (photoluminescent) and chemical (reactive surface) properties, for this reason, it is important to find new ways...     

Study of the photon down‐conversion effect produced by thin silicon‐rich oxide films on silicon solar cells

In the present work, we studied the photon down‐conversion effect produced by thin films of silicon oxide with embedded silicon nanocrystals also called silicon‐rich oxide (SRO). These films have been used to absorb high energy light and the re‐emission of two or more low energy photons (~1.1 eV) with the goal of improving the external quantum efficiency and consequently the conversion efficiency of silicon solar cells. According to our results, the incorporation of a thin SRO film on the solar cell surface increases the short circuit current and the FF of the silicon solar cells; the enhancement of spectral response is due to the high photoluminescence intensity of the SRO in the visible region when irradiated with UV light. An improvement of 38% in the solar cell efficiency has been observed in our particular solar cell fabrication process by the use of an SRO film with high photoluminescence intensity, which replaces the conventional silicon dioxide film. Copyright © 2016 John Wiley & Sons, Ltd.     

Water: A key resource in energy production

Water and energy are the key resources required for both economic and population growth, and yet both are increasingly scarce. The distribution of water takes large amounts of energy, while the production of energy requires large amounts of water in processes such as thermal plant cooling systems or raw materials extraction. This study analyzes the water needs for energy production in Spain according to the energy source sector (electricity, transportation or domestic) and process type (extraction and refining of raw materials or thermal plant use). Current and future water needs are quantified according to energy demand and technology mix evolution. Hypothetical scenarios that simulate the risks of promoting specific energy policies are also analyzed. Results show that the combination of energy resources used in Spain is projected to be more than 25% more water consumptive in 2030 than in 2005 under ceteris paribus conditions. Renewable energies are mixed in terms of their consequences on the water supply; wind power can reduce water withdrawal, while the biofuels production is a water-intensive process.     

Effect of decortication and protease treatment on the kinetics of liquefaction,saccharification, and ethanol production from sorghum

BACKGROUND: This study analyzes the effect of decortication and protease treatment on the kinetics of liquefaction, saccharification and ethanol production from sorghum kernels. In general, bioethanol yields from sorghum are lower than those from maize. This has been attributed to reduced access of starch‐degrading enzymes due to the crosslinked protein net in the sorghum kernels. RESULTS: Liquefaction is described as a zero order kinetics process, with reaction rates enhanced by protease treatment. The use of protease almost doubled the liquefaction rate in both whole and decorticated sorghum, compared with untreated kernels. During saccharification of decorticated sorghum, protease treatment significantly affected the glucose/starch yield and the glucose concentration profile over time. When compared with maize, protease treatment of decorticated sorghum resulted in superior ethanol production rates. Specific ethanol yields during fermentation were statistically comparable with those for maize. CONCLUSION: Protease treatment of decorticated sorghum kernels can impart substantial economic benefits in terms of improvement of bioethanol yield (13% over whole sorghum) and in reduced fermentation time (approximately 50% with respect to maize). Copyright © 2010 Society of Chemical Industry     

Cyclic voltammetric behaviour of polyfuran perchlorate doped films

Electroactivity with continuous cycling and the electrochemical behaviour of polyfuran perchlorate films (PFu/ClO₄) were investigated to determine the reversibility of doping/dedoping processes and the electrochemical mechanism of these processes as a function of the electropolymerization potential. A surface capacitive oxidation mechanism and a diffusion controlled mechanism in the dedoping process were detected when the potential scan rate was varied in D films (_p = 2.3 V). Moreover, D films (_p = 2.1 V ) showed a mixture of mechanism in the reduction processes. The polymeric material was found to deteriorate with continuous charge–discharge over successive days.     

Component-Based Derivation of a Parallel Stiff ODE Solver Implemented in a Cluster of Computers

A component-based methodological approach to derive distributed implementations of parallel ODE solvers is proposed. The proposal is based on the incorporation of explicit constructs for performance polymorphism into a methodology to derive group parallel programs of numerical methods from SPMD modules. These constructs enable the structuring of the derivation process into clearly defined steps, each one associated with a different type of optimization. The approach makes possible to obtain a flexible tuning of a parallel ODE solver for several execution contexts and applications. Following this methodological approach, a relevant parallel numerical scheme for solving stiff ODES has been optimized and implemented on a PC cluster. This numerical scheme is obtained from a Radau IIA Implicit Runge–Kutta method and exhibits a high degree of potential parallelism. Several numerical experiments have been performed by using several test problems with different structural characteristics. These experiments show satisfactory speedup results.     

Common-Mode Response Overlapping vs. Shaping in Rail-to-Rail Op-Amp Input Stages

In this paper, a circuit technique—common-mode (CM) response overlapping—for maintaining the small-signal behavior of rail-to-rail amplifiers nearly constant over the whole input CM range, is introduced. This technique modifies the CM response of the rail-to-rail input stage adequately by means of two constant input floating voltage sources, which are adjusted by using a static tuning section. Its performance is compared with a second technique—CM response shaping—, which is also based on two variable input floating voltage sources, but relies on a dynamic feedback tuning loop. Experimental results obtained from two 3-V 0.8-m CMOS single-stage rail-to-rail amplifiers, which operate with CM response overlapping and shaping, respectively, are provided.     

Superstructure determination of the perovskite βLa0.33NbO3

New interesting results in the crystal structure of the perovskite La_0.33NbO₃ were revealed using selected area electron diffraction, powder X-ray diffraction techniques and Rietveld refinement method. Although the superstructure of La_0.33NbO₃ could not be seen by conventional X-ray powder diffraction technique, the electron diffraction patterns revealed weak spots resulting in a superstructure array for the atoms of La_0.33NbO₃. The crystal symmetry is compatible with an orthorhombic cell, space group Cmmm. From Rietveld refinement, the resulting lattice parameters are: a = 7.82(1) Å, b = 7.83(9) Å, c = 7.90(9) Å and goodness of fit R = 0.1107, Rwp = 0.15. The superstructure is built from distorted octahedra NbO₆ along the [001] axis. Results suggest that this distortion may be produced by occupation of La atoms in (2a) and (4l) sites.     

First impressions: A multicultural content analysis of professional psychology program Web sites.

With the ascension of the Internet as an information resource, Web sites are likely to be the first exposure applicants have to specific programs. The authors evaluated professional psychology program Web sites for ethnic and sexual orientation minority content, discovering that diversity content of Web sites was considerably less than in previously examined paper application materials. Clinical psychology programs were more likely to state a commitment to diversity training while counseling psychology programs were more likely to state a diversity minor/track. School psychology programs had the lowest diversity content on their Web pages. This article explores how graduate psychology program Web sites communicate multicultural information and offers recommendations on using the World Wide Web as a cost-effective tool to attract a diverse student body. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Adhesive forces significantly affect elastic modulus determination of soft polymeric materials in nanoindentation

The present study investigated the effects of adhesion on the elastic modulus determined from nanoindentation curves for soft polydimethylsiloxane (PDMS) elastomers with five different crosslink concentrations. Indentation load-displacement curves were obtained for samples of all concentrations at four different peak loads. All load-displacement curves were nearly linear, resulting in load independent contact stiffnesses (p < 0.003) for the range of loads tested. As a result, elastic modulus calculated from nanoindentation curves with the Hertz contact model exhibited significant differences (p < 0.004) both at different peak loads for a single PDMS concentration and between different PDMS concentrations at a single peak load (p < 0.001). The differences for different peak loads were attributed to the presence of substantial adhesive forces at the tip-sample interface. By taking these adhesive interactions into account with the Johnson, Kendall, Roberts (JKR) contact model, the differences in elastic modulus at different peak loads could be reconciled. Significant differences (p < 0.001) in moduli between different PDMS concentrations were still present. The results highlight the importance of considering adhesive forces in nanoindentation analyses of low modulus polymeric materials.