工艺参数对射频磁控溅射PTFE靶形成的等离子体组成的影响

采用四极质谱仪测量了试验参数对高压脉冲增强射频磁控溅射PTFE靶等离子体气氛的影响规律。结果表明：增加脉冲偏压、脉冲频率、脉宽、射频功率和气压能提高Az离子对PTFE靶的溅射能力，增加空间中氟碳自由基的数量，其中各参数对峰位位于25．0aum处的氟碳自由基强度影响最大：脉冲电压从10kV提高到20kV能将该峰强度提高2倍；脉宽从40s提高到100μs强度提高80倍；频率从50Hz提高到200Hz强度提高4倍；溅射气压由0．1Pa提高到0.3Pa强度提高6倍；射频功率由200W提高到400W强度提高6倍。励磁电流能有效的约束氟碳自由基的空间分布。     

线阵电荷耦合器技术在自动测长系统中的应用

介绍用线阵电荷耦合器件(CCD)技术设计的型材在线实时测量系统。采用粗测和精测相结合的方法，解决了较大长度范围内精确测量问题。详细介绍动态在线非接触式测控系统的基本工作原理及软硬件组成。实测结果表明其测量精度高、效果好，能满足快速流水线的现场检测。     

Quantification of trace amounts of impurities in high purity cobalt by high resolution inductively coupled plasma mass spectrometry

An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pt, Au, and Pb) in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCl. The matrix effects because of the presence of excess HCl and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the deter- mination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 μg?g?1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results.     

HIGH TEMPERATURE OXIDATION AND STRUCTURE OF SCALE AND WHISKERS FOR Fe-Ni-Cr SEALING ALLOYS

The oxidation rate,the growth,morphology and structure of oxide scale and whiskers forFe-Ni-Cr sealing alloys in H_2-H_2O atmosphere at high temperatures have been studied.The growth rate of scale is controlled by diffusion.The scale is composed of Cr_2O_3 andspinel(Fe,Mn)O·Cr_2O_3 and the oxide whisker,are spinel(Fe,Mn)O·Cr_2O_3.     

印刷线路板电镀废水综合治理

简述线路板电镀废水中氰、铜氨、油墨废水治理方法和混合废水综合治理工艺流程及原理。     

提高钻杆接头冲击功的工艺方法

针对石油钻井关键产品高强度钻杆接头的使用要求,在保证强度指标要求非常高的前提下,研究摸索增加高温正火后再调质的工艺方法,以改善接头材料原始微观带状组织和纤维结构,细化晶粒,提高钻杆接头的冲击功,使该产品力学性能达到API标准的要求。     

La在KCl-NaCl和LaCl_3-KCl-NaCl熔体中的溶解行为SCIEI

本文利用透明槽技术、电化学循环V-A法及量子化学EHMO三种方法,研究了La在KCl-NaCl(1:1mol)及LaCl_3-KCl-NaCl熔体中的溶解行为。初步认为:溶解在KCl-NaCl熔体中的La是以中性金属状态存在。在LaCl_3-KCl-NaCl熔体中,溶解的La与La^(3+)作用生成低价La^(2+)离子,La^(2+)又与周围的La^(3+)作用形成原子簇离子La_m^(n+)赋存于熔体之中。     

Performances of electrically heated microgroove vaporizers

An electrically heated microgroove vaporizer was proposed. The vaporizer mainly comprised an outer tube, an inner tube and an electrical heater cartridge. Microgrooves were fabricated on the external surface of the inner tube by micro-cutting method, which formed the flow passage for fluid between the external surface of the inner tube and the internal surface of the outer tube. Experiments related to the temperature rise response of water and the thermal conversion efficiency of vaporizer were done to estimate the influences of microgroove＇s direction, feed flow rate and input voltage on the performances of the vaporizer. The results indicate that the microgroove＇s direction dominates the vaporizer performance at a lower input voltage. The longitudinal microgroove vaporizer exhibits the best performances for the temperature rise response of water and thermal conversion efficiency of vaporizer. For a moderate input voltage, the microgroove＇s direction and the feed flow rate of water together govern the vaporizer performances. The input voltage becomes the key influencing factor when the vaporizer works at a high input voltage, resulting in the similar performances of longitudinal, oblique and latitudinal microgroove vaporizers.     

Ti-Al基合金中的Hall-Petch关系及影响因素分析

研究了全层片状组织Ti-Al基合金的室温拉伸性能与品团尺寸的关系。Ti-Al基合金的室温拉伸屈服强度和断裂强度与晶团尺寸成Hall-Petch关系。当合金中添加替代元素Cr和Nb时，其Hall-Petch斜率不变；而添加间隙元素C和B时，其Hall-Petch斜率增加。Ti-Al基合金的室温延伸率与晶团尺寸不满足Hall-Petch关系。     

Fe(Ⅲ)改性膨润土光催化降解水溶液中的4-氯苯酚

以Fe（Ⅲ）离子交换改性膨润土,制得一种多相Fenton催化剂;以4-氯苯酚为模型污染物,研究不同反应条件的影响。结果表明,复合催化剂主要含SiO2及α-Fe2O3两种晶型,Fe是以高催化活性的α-Fe2O3形式存在。复合催化剂在H2O2及紫外光的协同作用下,经60 min反应后对4-氯苯酚的降解率约100%,TOC去除率约70%,且其循环使用性能较好。在实际操作过程中,控制溶液体系的pH值为6以及H2O2与4-氯苯酚浓度比约15较为适宜;在4-氯苯酚的降解过程中,C—Cl键持续断裂,Cl-被释放出来,降解过程生成了一些不含氯的中间产物。