Laser-induced heterometallic phase deposition from solutions of supramolecular complexes

Heterometallic (Au–Cu) phase precipitation on the surface of soda-lime glass as a result of laser-induced chemical liquid phase deposition (LCLD) is demonstrated for the first time. The precipitation of heterometallic structures was carried out under Ar⁺ laser irradiation from the solutions of supramolecular complexes. Energy dispersive X-ray (EDX) analysis showed that the deposits consist of both Au and Cu. Morphology of the deposited structures was found to be dependent on the used solvents: delocalized sparse surface structures in the case of the dichloromethane solution, close packed nanoparticles for the dimethyl formamide and homogeneous phase with nano-pores for the acetone solution. In accordance to the SEM photos and scan EDX analysis the homogeneous heterometallic phase with fixed Au/Cu ratio was achieved for the acetone solution of supramolecular complex. The observed formation of the heterometallic phase was explained by the laser-initiated intramolecular reduction process of the supramolecular metal core.     

Optimized Catalytic Bleaching Sequences for Eucalyptus Kraft Pulp

Contemporary multi-stage bleaching processes partially remove residual lignin and hexenuronic acid from cellulosic pulps. The reactions in the steps could be faster and consume smaller amounts of chemicals. Catalytic bleaching (H_cat), utilizing hypochlorite (H), triethylenediamine (DABCO) and its derivative N-carboxymethyl triethylenediamine (CM-DABCO), is a new discovery that has the potential to improve the chemical and energetic efficiency of bleaching processes in chemical pulp mills, e.g. through reducing the reaction time of the bleaching processes. The objective of this study was to clarify if new kraft pulp bleaching sequences with initial stage of chlorine dioxide (ClO₂; D) and an intermediate stage of H_cat could provide fully bleached pulps. The bleaching sequences of the studied eucalyptus pulps include D₀E_(OP)H_cat(Q)P and H_catZ/DP, which attained a final brightness of 88 and 89% ISO, respectively. H_catZ/DP showed to be the best sequence for the catalytic bleaching of eucalyptus kraft pulps. This study may open new doors to future bleaching of cellulose pulps with fewer towers and decreased use of chemicals.     

Soiling of plasticized poly(vinyl chloride)

The effects of three plasticizers and two plasticizer concentrations on the topography and soiling of poly (vinyl chloride) (PVC) were studied. Palmitic acid and triolein were chosen to represent solid and liquid soils. The feasibility of using infrared spectroscopy to quantify the amount of soil on PVC was examined. The structure of the solid model soil on plasticized PVC was studied with optical microscopy and atomic force microscopy. Palmitic acid formed two different structures on the PVC surface. Both the type and concentration of the plasticizer influenced the structure of the oily soil on plasticized PVC. The wetting of plasticized PVC with the liquid oily soil was compared to wetting with water through the measurement of the contact angles. Plasticized PVC was hydrophobic and oleophilic. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Friction Paths for Cubic Boron Nitride: An Ab Initio Study

Friction coefficients for cubic boron nitride were determined with the use of hybrid density functional B3LYP calculations. Two cluster models and an infinite periodic model were applied. Various contacts between duplicated surfaces and different sliding paths of the surfaces with respect to each other were taken into consideration, and friction coefficients were derived. The calculations suggest that three different sliding paths contribute to the friction, the friction coefficient for the periodic model being 0.21 at its lowest. This value is in agreement with previous experimental studies, where a friction coefficient of 0.1–0.2 has been measured for cubic boron nitride.     

Microclimate and ventilation in Estonian and Finnish dairy buildings

A series of ventilation, thermal and indoor air quality measurements were performed in 14 different dairy buildings in Estonia and Finland. The number of animals in the buildings varied from 30 to 600. Measurements were made all year round with ambient temperatures ranging between −40 °C and +30 °C. The results showed that microclimatic conditions in the dairy buildings were affected by the design of the building, outside temperature, wind, ventilation and manure handling method. The average inside air concentration of carbon dioxide was 950 ppm, ammonia 5 ppm, methane 48 ppm, relative humidity 70% and inside air velocity was 0.2 m/s. Although occasionally exceeded, the ventilation and average indoor air quality in the dairy buildings were mainly within the recommended limits.     

Designing Fast Fourier Transform Accelerators for Orthogonal Frequency-Division Multiplexing Systems

Designing accelerators for the real-time computation of Fast Fourier Transform (FFT) algorithms for state-of-the-art Orthogonal Frequency-Division Multiplexing (OFDM) demodulators has always been challenging. We have scaled-up a template-based Coarse-Grain Reconfigurable Array device for faster FFT processing that generates special purpose accelerators based on the user input. Using a basic and a scaled-up version, we have generated a radix-4 and mixed-radix (2, 4) FFT accelerator to process different length and types of algorithms. Our implementation results show that these accelerators satisfy not only the execution time requirements of FFT processing for Single Input Single Output (SISO) wireless standards that are IEEE-802.11 a/g and 3GPP-LTE but also for Multiple Input Multiple Output (MIMO) IEEE-802.11n standard.     

Real‐Time Label‐Free Monitoring of Nanoparticle Cell Uptake

The surface plasmon resonance technique in combination with whole cell sensing is used for the first time for real‐time label‐free monitoring of nanoparticle cell uptake. The uptake kinetics of several types of nanoparticles relevant to drug delivery applications into HeLa cells is determined. The cell uptake of the nanoparticles is confirmed by confocal microscopy. The cell uptake of silica nanoparticles and polyethylenimine–plasmid DNA polyplexes is studied as a function of temperature, and the uptake energies are determined by Arrhenius plots. The phase transition temperature of the HeLa cell membrane is detected when monitoring cell uptake of silica nanoparticles at different temperatures. The HeLa cell uptake of the mesoporous silica nanoparticles is energy‐independent at temperatures slightly higher than the phase transition temperature of the HeLa cell membrane, while the uptake of polyethylenimine–DNA polyplexes is energy‐dependent and linear as a function of temperature with an activation energy of Ea = 62 ± 7 kJ mol^?1 = 15 ± 2 kcal mol^?1. The HeLa cell uptake of red blood cell derived extracellular vesicles is also studied as a function of the extracellular vesicle concentration. The results show a concentration dependent behavior reaching a saturation level of the extracellular vesicle uptake by HeLa cells.     

Diffractive optics for virtual reality displays

Abstract— Near‐to‐eye (NTE) displays are generally systems where the imaging optics of a microdisplay is brought close to the eye, like a magnifying glass. In portable NTE terminals, the challenges are in achieving low power consumption as well as low weight and small size. Part of the problem is related to the microdisplay, but the optics also plays a major role. A study on how diffractive optical elements (DOEs) on planar waveguides can be used to miniaturize the optics of NTE displays is presented and the performance of the system is analyzed.     

Specific identification of certain probiotic Lactobacillus rhamnosus strains with PCR primers based on phage-related sequences

PCR primers derived from Lactobacillus rhamnosus phage Lc-Nu genome were used to screen the presence of phage-related sequences in Lb. rhamnosus strains. Several primer pairs derived from structural and replication gene regions of phage Lc-Nu amplified PCR products of expected sizes from bacterial strains revealing phage-related sequences in 10 of 11 Lb. rhamnosus strains. Strain-specific PCR primers for three probiotic Lb. rhamnosus strains were derived from these phage-related sequences for identification and detection purposes. Specificity of these primers was tested against 11 Lb. rhamnosus strains and over 40 other bacterial strains.     

Development of a high-throughput format for solid-phase extraction of enantiomers using an immunosorbent in 384-well plates

An antibody-based solid-phase extraction method for filtered 384-well plates was developed for a medical drug candidate having two enantiomeric forms in order to demonstrate the potential of the use of recombinant antibody fragments as specific and efficient immunosorbents. An immobilization method using a six-histidine tag of the antibody fragment and mild oxidation was applied in order to immobilize antibody fragments in an oriented and kinetically stable way that ensured high capacity of the antibody support. Phosphate buffer or plasma spiked with enantiomers were used as samples. Selective solid-phase extraction was followed by liquid chromatography-mass spectrometry analysis. Average recoveries for buffer and plasma samples ranged from 79 to 122% and 80 to 108%, respectively. Good linearity was observed in the concentration range of 30-3000 ng/mL of the enantiomer.