全文获取类型
收费全文 | 4675篇 |
免费 | 166篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 72篇 |
综合类 | 15篇 |
化学工业 | 1006篇 |
金属工艺 | 95篇 |
机械仪表 | 69篇 |
建筑科学 | 229篇 |
矿业工程 | 25篇 |
能源动力 | 113篇 |
轻工业 | 375篇 |
水利工程 | 27篇 |
石油天然气 | 2篇 |
无线电 | 470篇 |
一般工业技术 | 801篇 |
冶金工业 | 907篇 |
原子能技术 | 65篇 |
自动化技术 | 573篇 |
出版年
2023年 | 37篇 |
2022年 | 23篇 |
2021年 | 71篇 |
2020年 | 61篇 |
2019年 | 71篇 |
2018年 | 82篇 |
2017年 | 58篇 |
2016年 | 94篇 |
2015年 | 88篇 |
2014年 | 126篇 |
2013年 | 204篇 |
2012年 | 171篇 |
2011年 | 279篇 |
2010年 | 168篇 |
2009年 | 177篇 |
2008年 | 202篇 |
2007年 | 154篇 |
2006年 | 154篇 |
2005年 | 108篇 |
2004年 | 112篇 |
2003年 | 112篇 |
2002年 | 131篇 |
2001年 | 97篇 |
2000年 | 88篇 |
1999年 | 106篇 |
1998年 | 305篇 |
1997年 | 216篇 |
1996年 | 134篇 |
1995年 | 113篇 |
1994年 | 104篇 |
1993年 | 96篇 |
1992年 | 64篇 |
1991年 | 80篇 |
1990年 | 57篇 |
1989年 | 52篇 |
1988年 | 51篇 |
1987年 | 43篇 |
1986年 | 26篇 |
1985年 | 47篇 |
1984年 | 45篇 |
1983年 | 36篇 |
1982年 | 25篇 |
1981年 | 29篇 |
1980年 | 30篇 |
1979年 | 22篇 |
1978年 | 21篇 |
1977年 | 32篇 |
1976年 | 61篇 |
1975年 | 24篇 |
1972年 | 20篇 |
排序方式: 共有4844条查询结果,搜索用时 62 毫秒
91.
Jastorff AM Haegler K Maccarrone G Holsboer F Weber F Ziemssen T Turck CW 《Proteomics. Clinical applications》2009,3(11):1273-1287
Multiple sclerosis is characterized by inflammatory demyelination and axonal loss as pathophysiological correlates of relapsing activity and progressive development of clinical disability. The molecular processes involved in this pathogenesis are still unclear as they are quite complex and heterogeneous. In this article we present protein expression analysis of brain and spinal cord tissues from different models of murine experimental autoimmune encephalomyelitis (EAE), the most commonly used animal model for multiple sclerosis. We observed a number of EAE-specific protein expression and PTM differences. Proteome analysis was extended to multiple sclerosis specimens in order to validate the EAE findings. Our findings suggest the regulation of a number of proteins that shed light on the molecular mechanisms of the disease processes taking place in EAE and multiple sclerosis. We found consistent modulation of proteins including serum amyloid P component, sirtuin 2, dihydropyrimidinase-related protein family proteins, stathmin 1, creatine kinase B and chloride intracellular channel protein 1. Functional classification of the proteins by database and the literature mining reveals their association with neuronal development and myelinogenesis, suggesting possible disease processes that mediate neurodegeneration. 相似文献
92.
Nesterov A König K Felgenhauer T Lindenstruth V Trunk U Fernandez S Hausmann M Bischoff FR Breitling F Stadler V 《The Review of scientific instruments》2008,79(3):035106
We examined the high precision deposition of toner and polymer microparticles with a typical size of approximately 10 microm on electrode arrays with electrodes of 100 microm and below using custom-made microelectronic chips. Selective desorption of redundant particles was employed to obtain a given particle pattern from preadsorbed particle layers. Microparticle desorption was regulated by dielectrophoretic attracting forces generated by individual pixel electrodes, tangential detaching forces of an air flow, and adhesion forces on the microchip surface. A theoretical consideration of the acting forces showed that without pixel voltage, the tangential force applied for particle detachment exceeded the particle adhesion force. When the pixel voltage was switched on, however, the sum of attracting forces was larger than the tangential detaching force, which was crucial for desorption efficiency. In our experiments, appropriately large dielectrophoretic forces were achieved by applying high voltages of up to 100 V on the pixel electrodes. In addition, electrode geometries on the chip's surface as well as particle size influenced the desorption quality. We further demonstrated the compatibility of this procedure to complementary metal oxide semiconductor chip technology, which should allow for an easy technical implementation with respect to high-resolution microparticle deposition. 相似文献
93.
Estimating the virial coefficients of small polar molecules 总被引:2,自引:0,他引:2
We adapt existing models for estimating the second and third virial coefficients of small molecules to the halogenated methanes and ethanes. We compare the results with the abundant new, high-qualityPVT data resulting from the search for alternative refrigerants. The present model provides an accurate method for calculating densities, and therefore it should provide reliable thermodynamic properties and fugacity coefficients. We give equations and parameters useful for estimating the properties of pure refrigerants and their mixtures when noPVT data are available.Nomenclature
B
Second virial coeficient
-
B
12
Mixture cross second virial
-
B
h
Second virial of a hard sphere fluid
-
i
(T)
Temperature function, second virial, Eq. (7)
-
C
Third virial coefficient
-
C
112,C
122
Mixture cross third virials
-
C
h
Third virial of a hard sphere fluid
-
N
Avogadro's number
Virial Coefficients
P
c
Critical pressure
-
P
c12
Characteristic critical pressure of a binary mixture
-
T
c
Critical temperature
-
T
c12
Characteristic critical temperature of a binary mixture
-
T
r
Reduced temperature,T/T
c
-
Parameter measuring polar contribution toB, Eq. (3)
-
b
Volume of a hard sphere molecule
-
f
(f)
Polynomials determining temperature dependence of the nonpolar part ofB
-
k
12
Binary interaction parameter for mixtures, Eq. (9a)
-
c
Critical volume
-
e
Molecular polarizability
-
Dipole moment
-
R
Reduced dipole moment, Eq. (4)
-
R12
Mixture reduced dipole moment, second virial
-
R112,
R122
Mixture reduced dipole moment, third virial
-
Pitzer acentric factor
-
12
Mixture acentric factor
-
(r)
Intermolecular potential
-
c
Critical density (1/c) 相似文献
94.
95.
Jian-Qing Lu Rabah Boukherroub Georges Manuel William P. Weber 《Journal of Inorganic and Organometallic Polymers》1995,5(1):61-74
Poly[1-methyl-1-[3-(3-pyridinyl)propyl]-1-sila-cis-pent-3-ene], poly[1-phenyl-1-[3-(3-pyridinyl)propyl)-1-sila-cis-pent-3-ene], and poly[1-phenyl-1-(4-pyridinyl)-1-sila-cis-pent-3-ene] were synthesized by the anionic ring-opening polymerization of 1-methyl-1-[3-(3-pyridinyl)propyl]-1-silacyclopent-3-ene, 1-phenyl-1-[3-(3-pyridinyl)propyl]-1-silacyclopent-3-ene, and 1-phenyl-1-(4-pyridinyl)-1-silacyclopent-3-ene, respectively. These are the first polycarbosilanes which contain heterocyclic pyridine units as side-chain substituents. These polymers were characterized by1H,13C, and29Si NMR as well as by IR and UV spectroscopy. The molecular weight distributions were determined by gel permeation chromatography, glass transition temperatures, by differential seanning calorimetry: (DSC) and thermal behavior, by thermogravimetric analysis. (TGA). 相似文献
96.
Da Silva LB Barbee TW Cauble R Celliers P Ciarlo D Moreno JC Mrowka S Trebes JE Wan AS Weber F 《Applied optics》1995,34(28):6389-6392
The development of multilayer mirror technology capable of operating in the range of 3-30 nm and the construction of thin membranes with excellent uniformity and strength have made it possible to design and implement a Mach-Zehnder interferometer operating at 15.5 nm. We have tested this interferometer by using a soft x-ray laser as a source, and we show its use in probing high-density plasmas. 相似文献
97.
Dovletgeldi Seyitliyev Xixi Qin Manoj K. Jana Svenja M. Janke Xiaowei Zhong Wei You David B. Mitzi Volker Blum Kenan Gundogdu 《Advanced functional materials》2023,33(21):2213021
Electron–phonon interactions play an essential role in charge transport and transfer processes in semiconductors. For most structures, tailoring electron–phonon interactions for specific functionality remains elusive. Here, it is shown that, in hybrid perovskites, coherent phonon modes can be used to manipulate charge transfer. In the 2D double perovskite, (AE2T)2AgBiI8 (AE2T: 5,5“-diylbis(amino-ethyl)-(2,2”-(2)thiophene)), the valence band maximum derived from the [Ag0.5Bi0.5I4]2– framework lies in close proximity to the AE2T-derived HOMO level, thereby forming a type-II heterostructure. During transient absorption spectroscopy, pulsed excitation creates sustained coherent phonon modes, which periodically modulate the associated electronic levels. Thus, the energy offset at the organic–inorganic interface also oscillates periodically, providing a unique opportunity for modulation of interfacial charge transfer. Density-functional theory corroborates the mechanism and identifies specific phonon modes as likely drivers of the coherent charge transfer. These observations are a striking example of how electron–phonon interactions can be used to manipulate fundamentally important charge and energy transfer processes in hybrid perovskites. 相似文献
98.
Weber Lukas Vinon Tobias Kndler Christian Solis-Vasquez Leonardo Bernhardt Arthur Petrov Ilia Koch Andreas 《Distributed and Parallel Databases》2022,40(1):27-45
Distributed and Parallel Databases - Massive data transfers in modern data-intensive systems resulting from low data-locality and data-to-code system design hurt their performance and scalability.... 相似文献
99.
The Influence of Block Ionomer Microstructure on Polyplex Properties: Can Simulations Help to Understand Differences in Transfection Efficiency? 下载免费PDF全文
100.
Early phase distributed system design can be accomplished using solution spaces that provide an interval of permissible values for each functional parameter. The feasibility property guarantees fulfillment of all design requirements for all possible realizations. Flexibility denotes the size measure of the intervals, with higher flexibility benefiting the design process. Two methods are available for solution space identification. The direct method solves a computationally cheap optimization problem. The indirect method employs a sampling approach that requires a relaxation of the feasibility property through re-formulation as a chance constraint. Even for high probabilities of fulfillment, \(P>0.99\), this results in substantial increases in flexibility, which offsets the risk of infeasibility. This work implements the chance constraint formulation into the direct method for linear constraints by showing that its problem statement can be understood as a linear robust optimization problem. Approximations of chance constraints from the literature are transferred into the context of solution spaces. From this, we derive a theoretical value for the safety parameter \(\varOmega\). A further modification is presented for use cases, where some intervals are already predetermined. A problem from vehicle safety is used to compare the modified direct and indirect methods and discuss suitable choices of \(\varOmega\). We find that the modified direct method is able to identify solution spaces with similar flexibility, while maintaining its cost advantage. 相似文献