Studies on Catalytic Side-Chain Oxidation of Nitroaromatics to Aldehydes with Oxygen

The side-chain oxidation of 2-nitrotoluene in liquid phase in the presence of catalytic amount of manganese sulfate and stoichiometric amount of potassium hydroxide with oxygen was studied. In the most favorable conditions, over 80% of conversion of 2-nitrotoluene and 50% of selectivity to 2-nitrobenzaldehyde was achieved. Effects of the reaction parameters on the conversion of the reactant and the selectivity of the product were examined. These results, together with EPR spectroscopic study, show that a benzyl anion was formed in the early stage of the reaction, which was then converted to the final product via a free radical mechanism.     

用户无功功率低压集中补偿方式探讨

主要研究了用户无功功率低压集中补偿的问题,简单介绍了目前国内普遍采用的低压集中补偿方式的基本原理及技术特点,着重分析了在设计、安装、调试、维护等方面需注意的问题及处理措施。     

建筑用纺织品的性能与应用

本文系统介绍了各种建筑用纺织品在国内外的应用现状，阐述了各种建筑用纺织品的性能，指出了建筑用纺织品的发展方向和应用前景。     

电液比例阀在水轮机液压伺服系统中的应用

电液比例阀是阀内比例电磁铁根据输入的电压信号产生相应动作,使工作阀阀芯产生位移,阀口尺寸发生改变并以此完成与输入电压成比例的压力、流量输出的元件。由于电液比例阀具有形式种类多样,容易组成使用电气及计算机控制的各种电液系统,控制精度高,安装使用灵活以及抗污染能力     

FCC提升管反应器新型预提升结构开发

从气固流动规律、结构形式、预提升气分配等角度对工业提升管预提升段进行了试验研究,开发出油剂接触较为均匀,可有效减少反应器结焦的新型预提升结构,工业应用效果良好,反应结焦减少,装置剂油比增大,操作弹性提高,经济效益显著.     

Rich photoluminescence emission of SnO2–SiO2 composite aerogels prepared with a co-fed precursor sol–gel process

Tin oxide–silica composite aerogels were successfully prepared with a co-fed precursor sol–gel process. The crystallinity of the tin oxide nanoparticles, embedded in the mesoporous SiO₂ network, was improved with increasing the post-reaction thermal treatment temperature. The composite aerogels exhibited a rich photoluminescence (PL) emission contributed by both SnO₂ and SiO₂. The PL peak of 346 nm was from the near band edge emission of the tin oxide nanoparticles, and the ones located at 310 and 476 nm were attributable to the oxygen deficiencies of the silica network. Three more emission peaks, 387, 432, and 522 nm, were observed, with the 387 nm peak contributed by the oxygen vacancies V_O⁺⁺, the 432 nm peak by the Sn interstitials, and the 522 nm peak by the oxygen vacancies V_O⁺, respectively, of the tin oxide nanoparticles. The intensities of these three defect level emissions were found decreased, as compared to that of the near band edge emission, with increasing the post-reaction thermal treatment temperature as the tin oxide crystallinity improved.     

青坨子凸起馆陶组地震相研究

青坨子凸起馆陶组是东辛油田潜在的油气勘探区带，但目前对本区的地层分布和沉积相特征尚未进行系统研究，区内钻井不多且钻井取心、录井资料较少，因此开展区域的沉积相研究必须依靠现有的三维地震资料。通过对青坨子凸起周缘馆陶组地震相的研究，总结了该区的沉积模式，这对于下一步的油气勘探有一定的指导意义。另外，本区河流地震相的研究工作也可以作为其他地区地震相研究的借鉴。     

两性淀粉的制备及表征

以正磷酸盐为阴离子化剂,对高取代度的阳离子淀粉进行改性,制备阴阳离子比为0.5的两性淀粉,其最佳工艺为:磷酸盐与阳离子淀粉质量比为1.94～2.02.反应温度145～155℃,反应时间3～3.5 h。用红外光谱、X射线衍射、扫描电镜对其结构进行了表征,结果表明此种两性淀粉仅使淀粉结构中的非晶态区发生改变,并未改变整体结晶结构,因此其生物降解性会同天然高分子淀粉一样可完全降解。     

机械式有杆泵抽油井示功图的识别

介绍了一种用计算机精确、快速识别机械式示功图的方法。将绘制的示功图通过扫描仪输入计算机,通过对示功图进行二值、细化、矢量化等处理,将示功图的二值点阵信息转换为矢量信息,为后续示功图特征提取创造有利条件,有利于提高抽油井故障的诊断正确率。     

自锁式景观砌块加筋挡土结构的设计与应用

介绍砌块仿花岗岩挡土结构的特点和砌块形状,针对砌块挡土结构在我国刚开始应用,没有设计、施工规范的现状,依托可以借鉴的加筋挡土结构和浆砌块石挡土结构设计规范,提出了自锁式砌块加筋挡土结构设计中的地面荷载强度及土压力计算方法、砌块层间稳定验算方法、加筋长度和间距验算方法、挡土结构整体稳定验算方法和施工过程中需要注意的主要问题,为自锁式砌块加筋挡土结构设计人员提供了设计验算内容、验算方法和安全系数取值范围,为现场施工和监理人员提供参考,并为该类型的挡土结构推广应用提供技术支持。