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排序方式: 共有612条查询结果,搜索用时 15 毫秒
91.
Shayan Seyedin Simge Uzun Ariana Levitt Babak Anasori Genevieve Dion Yury Gogotsi Joselito M. Razal 《Advanced functional materials》2020,30(12)
The integration of nanomaterials with high conductivity into stretchable polymer fibers can achieve novel functionalities such as sensing physical deformations. With a metallic conductivity that exceeds other solution‐processed nanomaterials, 2D titanium carbide MXene is an attractive material to produce conducting and stretchable fibers. Here, a scalable wet‐spinning technique is used to produce Ti3C2Tx MXene/polyurethane (PU) composite fibers that show both conductivity and high stretchability. The conductivity at a very low percolation threshold of ≈1 wt% is demonstrated, which is lower than the previously reported values for MXene‐based polymer composites. When used as a strain sensor, the MXene/PU composite fibers show a high gauge factor of ≈12900 (≈238 at 50% strain) and a large sensing strain of ≈152%. The cyclic strain sensing performance is further improved by producing fibers with MXene/PU sheath and pure PU core using a coaxial wet‐spinning process. Using a commercial‐scale knitting machine, MXene/PU fibers are knitted into a one‐piece elbow sleeve, which can track various movements of the wearer's elbow. This study establishes fundamental insights into the behavior of MXene in elastomeric composites and presents strategies to achieve MXene‐based fibers and textiles with strain sensing properties suitable for applications in health, sports, and entertainment. 相似文献
92.
Xian-Kui Wei Gustav Bihlmayer Xiaodong Zhou Wanxiang Feng Yury V. Kolen'ko Dehua Xiong Lifeng Liu Stefan Blügel Rafal E. Dunin-Borkowski 《Advanced materials (Deerfield Beach, Fla.)》2020,32(46):2003479
Ferroelectric metals—with coexisting ferroelectricity and structural asymmetry—challenge traditional perceptions because free electrons screen electrostatic forces between ions, the driving force of breaking the spatial inversion symmetry. Despite ferroelectric metals having been unveiled one after another, topologically switchable polar objects with metallicity have never been identified so far. Here, the discovery of real-space topological ferroelectricity in metallic and non-centrosymmetric Ni2P is reported. Protected by the rotation–inversion symmetry operation, it is found that the balanced polarity of alternately stacked polyhedra couples intimately with elemental valence states, which are verified using quantitative electron energy-loss spectroscopy. First-principles calculations reveal that an applied in-plane compressive strain creates a tunable bilinear double-well potential and reverses the polyhedral polarity on a unit-cell scale. The dual roles of nickel cations, including polar displacement inside polyhedral cages and a 3D bonding network, facilitate the coexistence of topological polarity with metallicity. In addition, the switchable in-plane polyhedral polarity gives rise to a spin–orbit-coupling-induced spin texture with large momentum-dependent spin splitting. These findings point out a new direction for exploring valence–polarity–spin correlative interactions via topological ferroelectricity in metallic systems with structural asymmetry. 相似文献
93.
Simge Uzun Marion Schelling Kanit Hantanasirisakul Tyler S. Mathis Ron Askeland Genevieve Dion Yury Gogotsi 《Small (Weinheim an der Bergstrasse, Germany)》2021,17(1):2006376
Direct printing of functional inks onto flexible substrates allows for scalable fabrication of wearable electronics. However, existing ink formulations for inkjet printing require toxic solvents and additives, which make device fabrication more complex, limit substrate compatibility, and hinder device performance. Even water-based carbon or metal nanoparticle inks require supplemental surfactants, binders, and cosolvents to produce jettable colloidal suspensions. Here, a general approach is demonstrated for formulating conductive inkjet printable, additive-free aqueous Ti3C2Tx MXene inks for direct printing on various substrates. The rheological properties of the MXene inks are tuned by controlling the Ti3C2Tx flake size and concentration. Ti3C2Tx-based electrical conduits and microsupercapacitors (MSCs) are printed on textile and paper substrates by optimizing the nozzle geometry for high-resolution inkjet printing. The chemical stability and electrical properties of the printed devices are also studied after storing the devices for six months under ambient conditions. Current collector-free, textile-based MSCs show areal capacitance values up to 294 mF cm−2 (2 mV s−1) in poly(vinyl alcohol)/sulfuric acid gel electrolyte, surpassing reported printed MXene-based MSCs and inkjet-printed MSCs using other 2D nanomaterials. This work is an important step toward increasing the functional capacity of conductive inks and simplifying the fabrication of wearable textile-based electronics. 相似文献
94.
Meikang Han Yuqiao Liu Roman Rakhmanov Christopher Israel Md Abu Saleh Tajin Gary Friedman Vladimir Volman Ahmad Hoorfar Kapil R. Dandekar Yury Gogotsi 《Advanced materials (Deerfield Beach, Fla.)》2021,33(1)
Highly integrated, flexible, and ultrathin wireless communication components are in significant demand due to the explosive growth of portable and wearable electronic devices in the fifth‐generation (5G) network era, but only conventional metals meet the requirements for emerging radio‐frequency (RF) devices so far. Here, it is reported on Ti3C2Tx MXene microstrip transmission lines with low‐energy attenuation and patch antennas with high‐power radiation at frequencies from 5.6 to 16.4 GHz. The radiation efficiency of a 5.5 µm thick MXene patch antenna manufactured by spray‐coating from aqueous solution reaches 99% at 16.4 GHz, which is about the same as that of a standard 35 µm thick copper patch antenna at about 15% of its thickness and 7% of the copper weight. MXene outperforms all other materials evaluated for patch antennas to date. Moreover, it is demonstrated that an MXene patch antenna array with integrated feeding circuits on a conformal surface has comparable performance with that of a copper antenna array at 28 GHz, which is a target frequency in practical 5G applications. The versatility of MXene antennas in wide frequency ranges coupled with the flexibility, scalability, and ease of solution processing makes MXene promising for integrated RF components in various flexible electronic devices. 相似文献
95.
Chuangang Hu Yi Lin John W. Connell Hui‐Ming Cheng Yury Gogotsi Maria‐Magdalena Titirici Liming Dai 《Advanced materials (Deerfield Beach, Fla.)》2019,31(13)
Owing to their high earth‐abundance, eco‐friendliness, high electrical conductivity, large surface area, structure tunability at the atomic/morphological levels, and excellent stability in harsh conditions, carbon‐based metal‐free materials have become promising advanced electrode materials for high‐performance pseudocapacitors and metal–air batteries. Furthermore, carbon‐based nanomaterials with well‐defined structures can function as green catalysts because of their efficiency in advanced oxidation processes to remove organics in air or from water, which reduces the cost for air/water purification and avoids cross‐contamination by eliminating the release of heavy metals/metal ions. Here, the research and development of carbon‐based catalysts in supercapacitors and batteries for clean energy storage as well as in air/water treatments for environmental remediation are reviewed. The related mechanistic understanding and design principles of carbon‐based metal‐free catalysts are illustrated, along with the challenges and perspectives in this emerging field. 相似文献
96.
Vladimir Chepelev Yury Parfenov William Radasky Boris Titov Leonid Zdoukhov Kejie Li Yuhao Chen Xu Kong Yan-zhao Xie 《Journal of Electronic Testing》2018,34(5):547-557
In this paper, we have considered a methodical approach to forecast the consequences of the influence of pulsed electromagnetic fields on electronic devices based on three defined conditions of the disruption of device functioning. The approach is based on the use of key parameters of pulse disturbances in critical circuits of electronic devices. Depending on the problem being solved and features of the object being tested, the key parameters can be: the amplitude of a voltage pulse in a critical circuit of an object; the Joule integral; the energy; the frequency of repetition of influencing pulses; the probability of a bit error; the number of errors in a transferred data packet; the data rate, etc. 相似文献
97.
Inkjet Printing of Self‐Assembled 2D Titanium Carbide and Protein Electrodes for Stimuli‐Responsive Electromagnetic Shielding 下载免费PDF全文
Mert Vural Abdon Pena‐Francesch Joan Bars‐Pomes Huihun Jung Hemanth Gudapati Christine B. Hatter Benjamin D. Allen Babak Anasori Ibrahim T. Ozbolat Yury Gogotsi Melik C. Demirel 《Advanced functional materials》2018,28(32)
2D titanium carbides (MXene) possess significant characteristics including high conductivity and electromagnetic interference shielding efficiency (EMI SE) that are important for applications in printed and flexible electronics. However, MXene‐based ink formulations are yet to be demonstrated for proper inkjet printing of MXene patterns. Here, tandem repeat synthetic proteins based on squid ring teeth (SRT) are employed as templates of molecular self‐assembly to engineer MXene inks that can be printed as stimuli‐responsive electrodes on various substrates including cellulose paper, glass, and flexible polyethylene terephthalate (PET). MXene electrodes printed on PET substrates are able to display electrical conductivity values as high as 1080 ± 175 S cm?1, which significantly exceeds electrical conductivity values of state‐of‐the‐art inkjet‐printed electrodes composed of other 2D materials including graphene (250 S cm?1) and reduced graphene oxide (340 S cm?1). Furthermore, this high electrical conductivity is sustained under excessive bending deformation. These flexible electrodes also exhibit effective EMI SE values reaching 50 dB at films with thicknesses of 1.35 µm, which mainly originate from their high electrical conductivity and layered structure. 相似文献
98.
Joseph Halim Sankalp Kota Maria R. Lukatskaya Michael Naguib Meng‐Qiang Zhao Eun Ju Moon Jeremy Pitock Jagjit Nanda Steven J. May Yury Gogotsi Michel W. Barsoum 《Advanced functional materials》2016,26(18):3118-3127
Large scale synthesis and delamination of 2D Mo2CT x (where T is a surface termination group) has been achieved by selectively etching gallium from the recently discovered nanolaminated, ternary transition metal carbide Mo2Ga2C. Different synthesis and delamination routes result in different flake morphologies. The resistivity of free‐standing Mo2CT x films increases by an order of magnitude as the temperature is reduced from 300 to 10 K, suggesting semiconductor‐like behavior of this MXene, in contrast to Ti3C2T x which exhibits metallic behavior. At 10 K, the magnetoresistance is positive. Additionally, changes in electronic transport are observed upon annealing of the films. When 2 μm thick films are tested as electrodes in supercapacitors, capacitances as high as 700 F cm?3 in a 1 m sulfuric acid electrolyte and high capacity retention for at least 10,000 cycles at 10 A g?1 are obtained. Free‐standing Mo2CT x films, with ≈8 wt% carbon nanotubes, perform well when tested as an electrode material for Li‐ions, especially at high rates. At 20 and 131 C cycling rates, stable reversible capacities of 250 and 76 mAh g?1, respectively, are achieved for over 1000 cycles. 相似文献
99.
Layered Orthorhombic Nb2O5@Nb4C3Tx and TiO2@Ti3C2Tx Hierarchical Composites for High Performance Li‐ion Batteries 下载免费PDF全文
Chuanfang Zhang Seon Joon Kim Michael Ghidiu Meng‐Qiang Zhao Michel W. Barsoum Valeria Nicolosi Yury Gogotsi 《Advanced functional materials》2016,26(23):4143-4151
Engineering electrode nanostructures is critical in developing high‐capacity, fast rate‐response, and safe Li‐ion batteries. This study demonstrates the synthesis of orthorhombic Nb2O5@Nb4C3Tx (or @Nb2CTx) hierarchical composites via a one‐step oxidation —in flowing CO2 at 850 °C —of 2D Nb4C3Tx (or Nb2CTx) MXene. The composites possess a layered architecture with orthorhombic Nb2O5 nanoparticles decorated uniformly on the surface of the MXene flakes and interconnected by disordered carbon. The composites have a capacity of 208 mAh g?1 at a rate of 50 mA g?1 (0.25 C) in 1–3 V versus Li+/Li, and retain 94% of the specific capacity with 100% Coulombic efficiency after 400 cycles. The good electrochemical performances could be attributed to three synergistic effects: (1) the high conductivity of the interior, unoxidized Nb4C3Tx layers, (2) the fast rate response and high capacity of the external Nb2O5 nanoparticles, and (3) the electron “bridge” effects of the disordered carbon. This oxidation method was successfully extended to Ti3C2Tx and Nb2CTx MXenes to prepare corresponding composites with similar hierarchical structures. Since this is an early report on producing this structure, there is much room to push the boundaries further and achieve better electrochemical performance. 相似文献
100.