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111.
《Synthetic Metals》2006,156(16-17):1078-1082
Polypyrrole (PPy) was prepared by chemical oxidation polymerization, analyzed by FT-IR, elemental analysis and HRTEM, and studied for gas sensitivity. It suggested that PPy had sensitivity to NH3, H2S and NOx, and showed irreversibility to NOx gas. The organic–inorganic hybrid materials PPy/ZnO with different PPy weight percents were prepared by mechanical mixing, and the sensitivity study of the materials to toxic gases NH3, H2S, NOx was carried out at different operating temperatures 30, 60, and 90 °C. It was found that PPy/ZnO materials (PPy(1%)/ZnO, PPy(3%)/ZnO, PPy(5%)/ZnO, PPy(10%)/ZnO, PPy(20%)/ZnO) had better selectivity and reversibility to NOx than pure PPy, and much lower working temperature than the reported working temperature of ZnO (about 350–450 °C). Their sensitivity increased with the increasing concentration of NOx at particular working temperature, and among them PPy(10%)/ZnO had the maximum sensitivity to NOx in the same condition. They showed no response to 1000, 1500, 2000 ppm NH3 or H2S. The response mechanism of PPy/ZnO materials to NOx was discussed. 相似文献
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Response time (RT) of Networked Automation Systems (NAS) is affected by timing imperfections induced due to the network, computing and hardware components. Guaranteeing RT in the presence of such timing imperfections is essential for building dependable NAS, and to avoid costly upgrades after deployment in industries.This investigation proposes a methodology and work-flow that combines modelling, simulation, verification, experiments, and software tools to verify the RT of the NAS during the design, rather than after deployment. The RT evaluation work-flow has three phases: model building, modelling and verification. During the model building phase component reaction times are specified and their timing performance is measured by combining experiments with simulation. During the modelling phase, component based mathematical models that capture the network architecture and inter-connection are proposed. Composition of the component models gives the NAS model required for studying the RT performance on system level. Finally, in the verification step, the NAS formal models are abstracted as UPPAAL timed automata with their timing interfaces. To model timing interfaces, the action patterns, and their timing wrapper are proposed. The formal model of high level of abstraction is used to verify the total response time of the NAS where the reactions to be verified are specified using a subset of timed computation tree logic (TCTL) in UPPAAL model checker. The proposed approach is illustrated on an industrial steam boiler deployment. 相似文献
115.
Petri网自提出以来得到了学术界和工业界的广泛关注. Petri网系统的可达性是最基本性质之一.系统的其他相关性质都可以通过可达性进行分析.利用等价的有限可达树来研究无界Petri网可达性,依然是一个开放性问题.该研究可以追溯到40年前,但由于问题本身的复杂性和难度太大,直到最近20年,经过国内外诸多学者的不懈努力,才逐渐取得了一些阶段性的成果和部分突破.本文回顾了近40年来国内外学者为彻底解决该问题作出的贡献.重点对4种开创性的研究成果展开讨论,分别为有限可达树、扩展可达树、改进可达树及新型改进可达树.探讨了今后无界Petri网可达性问题的研究方向. 相似文献
116.
高维多目标优化问题普遍存在且难以解决, 到目前为止, 尚缺乏有效解决该问题的进化优化方法. 本文提出一种基于目标分解的高维多目标并行进化优化方法, 首先, 将高维多目标优化问题分解为若干子优化问题, 每一子优化问题除了包含原优化问题的少数目标函数之外, 还具有由其他目标函数聚合成的一个目标函数, 以降低问题求解的难度; 其次, 采用多种群并行进化算法, 求解分解后的每一子优化问题, 并在求解过程中, 充分利用其他子种群的信息, 以提高Pareto非被占优解的选择压力; 最后, 基于各子种群的非被占优解形成外部保存集, 从而得到高维多目标优化问题的Pareto 最优解集. 性能分析表明, 本文提出的方法具有较小的计算复杂度. 将所提方法应用于多个基准优化问题, 并与NSGA-II、PPD-MOEA、ε-MOEA、HypE和MSOPS等方法比较, 实验结果表明, 所提方法能够产生收敛性、分布性, 以及延展性优越的Pareto最优解集. 相似文献
117.
Control of autonomous systems subject to stochastic uncertainty is a challenging task. In guided airdrop applications, random wind disturbances play a crucial role in determining landing accuracy and terrain avoidance. This paper describes a stochastic parafoil guidance system which couples uncertainty propagation with optimal control to protect against wind and parameter uncertainty in the presence of impact area obstacles. The algorithm uses real-time Monte Carlo simulation performed on a graphics processing unit (GPU) to evaluate robustness of candidate trajectories in terms of delivery accuracy, obstacle avoidance, and other considerations. Building upon prior theoretical developments, this paper explores performance of the stochastic guidance law compared to standard deterministic guidance schemes, particularly with respect to obstacle avoidance. Flight test results are presented comparing the proposed stochastic guidance algorithm with a standard deterministic one. Through a comprehensive set of simulation results, key implementation aspects of the stochastic algorithm are explored including tradeoffs between the number of candidate trajectories considered, algorithm runtime, and overall guidance performance. Overall, simulation and flight test results demonstrate that the stochastic guidance scheme provides a more robust approach to obstacle avoidance while largely maintaining delivery accuracy. 相似文献
118.
In this work, we discuss a recently proposed approach for supervised dimensionality reduction, the Supervised Distance Preserving Projection (SDPP) and, we investigate its applicability to monitoring material's properties from spectroscopic observations. Motivated by continuity preservation, the SDPP is a linear projection method where the proximity relations between points in the low-dimensional subspace mimic the proximity relations between points in the response space. Such a projection facilitates the design of efficient regression models and it may also uncover useful information for visualisation. An experimental evaluation is conducted to show the performance of the SDPP and compare it with a number of state-of-the-art approaches for unsupervised and supervised dimensionality reduction. The regression step after projection is performed using computationally light models with low maintenance cost like Multiple Linear Regression and Locally Linear Regression with k-NN neighbourhoods. For the evaluation, a benchmark and a full-scale calibration problem are discussed. The case studies pertain the estimation of a number of chemico-physical properties in diesel fuels and in light cycle oils, starting from near-infrared spectra. Based on the experimental results, we found that the SDPP leads to parsimonious projections that can be used to design light and yet accurate estimation models. 相似文献
119.
工程实践中常见的带间隙的三明治系统的准确故障预报具有重要的现实意义,为此,本文构建了一种新的动态鲁棒观测器对其进行故障预报.首先,通过将非光滑项转化为干扰项的方法,将间隙非光滑三明治系统转化为可用动态鲁棒观测器设计方法设计的系统.其次,采用零点配置和最小化基准区间观测器的范数(H_∞,F/H_,F)指标的方法确定动态鲁棒观测器的增益矩阵.最后,通过仿真,分别比较了基于非光滑鲁棒观测器和基于传统观测器的故障预报效果,比较结果表明:鲁棒观测器能够及时地准确预报传统观测器无法预报的故障,且有效减少了故障的漏报和错报现象. 相似文献
120.
A new iterative algorithm for solving H∞ control problem of continuous‐time Markovian jumping linear systems based on online implementation 下载免费PDF全文
A new online iterative algorithm for solving the H∞ control problem of continuous‐time Markovian jumping linear systems is developed. For comparison, an available offline iterative algorithm for converging to the solution of the H∞ control problem is firstly proposed. Based on the offline iterative algorithm and a new online decoupling technique named subsystems transformation method, a set of linear subsystems, which implementation in parallel, are obtained. By means of the adaptive dynamic programming technique, the two‐player zero‐sum game with the coupled game algebraic Riccati equation is solved online thereafter. The convergence of the novel policy iteration algorithm is also established. At last, simulation results have illustrated the effectiveness and applicability of these two methods. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献