Pre-Activation of CO2 at Cobalt Phthalocyanine-Mg(OH)2 Interface for Enhanced Turnover Rate

Cobalt phthalocyanine (CoPc) anchored on heterogeneous scaffold has drawn great attention as promising electrocatalyst for carbon dioxide reduction reaction (CO₂RR), but the molecule/substrate interaction is still pending for clarification and optimization to maximize the reaction kinetics. Herein, a CO₂RR catalyst is fabricated by affixing CoPc onto the Mg(OH)₂ substrate primed with conductive carbon, demonstrating an ultra-low overpotential of 0.31 ± 0.03 V at 100 mA cm⁻² and high faradaic efficiency of >95% at a wide current density range for CO production, as well as a heavy-duty operation at 100 mA cm⁻² for more than 50 h in a membrane electrode assembly. Mechanistic investigations employing in situ Raman and attenuated total reflection surface-enhanced infrared absorption spectroscopy unravel that Mg(OH)₂ plays a pivotal role to enhance the CO₂RR kinetics by facilitating the first-step electron transfer to form anionic *CO₂⁻ intermediates. DFT calculations further elucidate that introducing Lewis acid sites help to polarize CO₂ molecules absorbed at the metal centers of CoPc and consequently lower the activation barrier. This work signifies the tailoring of catalyst-support interface at molecular level for enhancing the turnover rate of CO₂RR.     

高职院校毕业实习质量管理研究

毕业实习是高职教育的重要教学环节,在分析高职院校毕业实习质量现状及存在问题原因的基础上,从实习规划、实习目标、过程管理,沟通协作、毕业实习评价体系、实习信息反馈等方面,对如何提高毕业实习质量进行了探讨,并提出了相应的对策。     

VFP标签在酒店管理中的应用

计算机技术的迅速发展与普及,在每个领域都给带来了诸多的便捷,如何应用所学的计算机知识,更好地为工作、生活服务,进一步提高管理水平和工作效率,是每一位用户都应该思考的问题。本文在探讨应用VFP6.0的标签、表单等功能编制、打印酒店住宿管理中客户消费清单的过程中,体现理实一体、学以致用的教学理念。     

Concurrent size and shape coarsening of γ′ in AlAg

The coarsening of γ′ precipitates in aluminum-silver has been investigated. Thesplate-shaped precipitates have coherent broad faces, and a hexagonal close packed crystal structure and develop on ∝111∝ planes of the aluminum matrix. During growth, a dispersion of nonequilibrium shaped γ′ precipitates develops. To understand the subsequent size and shape coarsening of these γ′ precipitates, several microstructural parameters have been experimentally determined as a function of aging time through quantitative electron microscopy. The measured thickening rate and nterledge spacing confirm that precipitate thickening takes place by a ledge mechanism and that the overall coarsening process of these precipitates is related to the average interledge spacing which remains relatively constant throughout the coarsening stage. The change in precipitate diameter does not appear to obey any temporal law and most likely accomodates the precipitate thickening and local supersaturation.     

轴向出流的单腔压电泵结构设计与性能研究

为提高压电泵的输出性能,设计了一种新型轴向出流的单腔有阀压电泵。泵体结构主要由3部分构成,即固定压电振子的上盖、带有腔体结构和被动截止阀的中间体及起压紧和密封作用的下盖。轴向出流的单腔压电泵的结构是将进口阀安装在圆柱形腔体的中心位置,保证进口管的轴线与压电振子垂直,出口阀安装在泵腔外,通过导流槽与泵腔连接,形成轴向进出流方式。将轴向出流的单腔压电泵和早期设计的侧向出流压电泵进行输出性能测试,试验发现,在低频工作阶段,侧向出流的单腔压电泵输出效果要略高于轴向出流,在高频工作阶段,后者要高于前者,而在整个40~400 Hz测试范围内,后者输出的液体压力都要高于前者。     

拉伸取向控制对AZ31镁合金孪生和织构演化的影响

以室温单轴拉伸实验与晶体塑性有限元相结合的方法,通过拉伸取向控制,研究了AZ31镁合金拉伸变形过程中孪生行为、织构演化规律、塑性各向异性之间的关系。基于率相关晶体塑性本构理论,建立了滑移和孪生机制耦合的具有不同取向的晶体塑性本构模型,引入孪晶体积分数研究孪生对AZ31镁合金塑性变形过程中织构演变和力学性能的影响。结果表明,2种不同取向的样品在塑性变形过程中呈现出明显不同的织构演变规律,表现出明显的各向异性。轴向拉伸时孪生被抑制,孪晶激活体积分数低,径向拉伸时孪晶极易产生,孪晶激活体积分数高。轴向试样在整个塑性变形过程中{0001}极图偏移较小,径向试样因大量拉伸孪晶的开启,使得{0001}棱柱面织构的极密度逐渐向RD的正反方向发生明显偏移。     

复合抗氧化剂对亚麻油稳定性的影响

利用烘箱加速氧化试验,选取酸价和过氧化值两个指标作为评判标准,采用正交试验研究不同复合配比天然抗氧化剂与合成抗氧化剂组合对亚麻油稳定性及货架期的影响。结果表明,复合抗氧化剂的最佳配比为:0.04%迷迭香油+0.018%叔丁基对甲氧酚+0.018%没食子酸丙酯。通过对比碱炼前后亚麻油酸价的变化,发现当向4g亚麻油中添加0.6~0.7g的NaOH反应4h后,酸价降低约80%,对延长亚麻油货架期的效果较为显著。     

运用Excel提升大学计算机教学质量探究

提高教学质量、教学效果是教育工作者不懈追求的目标,而质量与效果的提高依赖于先进的教学模式、教学方法、教学手段。该文理论联系,对运用Excel提升大学计算机基础教学质量进行了探讨。     

试论云计算中的关键技术

在计算机技术的基础上,通过对网格计算进行优化和改良从而构建出一种新的计算模型即为云计算.随着计算机技术和网络技术的不断发展,云计算的使用范围也在不断地扩大,这同时也给IT产业提供了相当有利的技术保障.本文对云计算进行了阐述,同时针对其关键技术进行了概述.     

常州市美丽乡村示范项目建设的实践与成效

美丽乡村建设是深入推进社会主义新农村建设的一项重大举措,是推进生态文明建设的一项重要载体。常州市将以美丽乡村示范项目建设为契机,集中优势力量,发挥示范作用,以点带面地推进全域美丽乡村建设。通过对常州市美丽乡村示范项目建设的主要实践和成效进行分析和研究,以期提升美丽乡村建设水平。