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1.
《Carbon》2015
The metal grid and reduced graphene oxide (RGO) are both promising transparent conductive materials for replacing the indium tin oxide (ITO) in flexible optoelectronics. However, the large empty area that exists in the grid together with the relatively high sheet resistance of RGO hinder both the materials for practical applications. In this work, we report for the first time a novel strategy for efficient combination of the metal grid and RGO by using a newly developed room-temperature reduction technique. The obtained RGO/metal grid hybrid films not only overcome the shortcomings of individual components but exhibit enhanced optical and electrical performances (Rs = 18 Ω sq−1 and T = 80%) and excellent flexural endurance. With this hybrid film as the window electrode, a highly flexible electrochromic device with excellent stability and ultra-fast response shorter than 60 ms has been successfully fabricated. Considering its high efficiency, high quality, low cost and large area, the strategy would be particularly useful for economically fabricating various metal grid/RGO films which are quite promising high performance transparent and conductive materials for next generation optoelectronic devices. 相似文献
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The morphology of the photoactive layer critically affects the performance of the bulk heterojunction polymer solar cells (PSCs). To control the morphology, we introduced a hydrophobic fluoropolymer polyvinylidene fluoride (PVDF) as nonvolatile additive into the P3HT:PCBM active layer. The effect of PVDF on the surface and the bulk morphology were investigated by atomic force microscope and transmission electron microscopy, respectively. Through the repulsive interactions between the hydrophilic PCBM and the hydrophobic PVDF, much more uniform phase separation with good P3HT crystallinity is formed within the active layer, resulting enhanced light harvesting and improved photovoltaic performance in conventional devices. The PCE of the conventional device can improve from 2.40% to 3.07% with PVDF additive. The PVDF distribution within the active layer was investigated by secondary ion mass spectroscopy, confirming a bottom distribution of PVDF. Therefore, inverted device structure was designed, and the PCE can improve from 2.81% to 3.45% with PVDF additive. Our findings suggest that PVDF is a promising nonvolatile processing additive for high performance polymer solar cells. 相似文献
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Global decrease in crude oil resources and frequent crude oil leaks cause the energy crisis and ecological pollution. The absorption and release of leaked crude oil through absorption materials are a necessary process for environmental protection and recycling. In this article, a CO2-responsive olefin copolymer was obtained by copolymerization of styrene and an amine-containing olefin monomer. The structure of resultant copolymer was characterized by FTIR; thermal properties and CO2-responsive morphology changes were determined by DSC/TGA and SEM, respectively. Copolymers had certain absorption capacity for toluene with absorption rate up to 180.0%. The absorbed toluene could be released upon CO2 stimulation with desorption rate up to 84.6%. The CO2-responsive copolymer could be regenerated through a simple heating process and showed stable absorption–desorption performance even after being recycled for 4 times. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47439. 相似文献
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建筑构件积木式CAD软件研究 总被引:4,自引:0,他引:4
西方以混凝土坝内廓道施工样图设计阶段为例,论述水工建筑件积木式CAD软件的必要性和积木模块CAD软件的具体实现方法。 相似文献
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介绍电力变压器蒸发冷却装置的液位控制系统,该系统以嵌入式以太网芯片为核心构成网络终端,实现了冷却介质FC液位的远程监测调节。 相似文献
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基于爆破产生的P波入射作用下均匀内压薄壁管道的受力特点,采用拟静力分析和叠加原理建立压力管道爆破地震波作用下的应力解析计算模型;基于压力管道材料屈服特性及Tresca屈服理论,建立爆破P波作用下压力管道的振动安全判据计算模型,并结合爆炸影响的直埋压力薄壁管道工程案例进行解析验算。研究结果表明:爆破荷载施加前管道仅受均匀内压,具有初始轴向和切向应力,爆破发生后,管道同时受到内压和爆破地震波P波动荷载作用;管?土界面入射波临界角较小,管道峰值应力随入射角度增大减小,垂直入射时主要发生拉伸破坏,全反射时主要为切向破坏;压力管道安全控制振速随入射角的增大而增大,随运行内压的增大而减小,实际工程中根据管道内压实际情况,选择较小的值作为安全控制值。 相似文献
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《中国稀土学报(英文版)》2022,40(6):906-915
Exploring an alternative strategy with high efficiency and low cost to abate formaldehyde (HCHO) in indoor environment, is of increasing significance for people's health. CeO2 catalysts prepared by hydrothermal, precipitation and calcination methods were investigated for HCHO removal at ambient temperature. It is found that indoor fluorescent light visibly boosts the catalytic performance of CeO2 catalysts for HCHO decomposition at ambient temperature. Among the CeO2 catalysts, CeO2 prepared from hydrothermal method (CeO2–H) exhibits a superior catalytic performance and an excellent durability by eight recycle times. Based on the characterization and analysis, the excellent catalytic performance of CeO2–H is mainly contributed by its abundance of surface oxygen vacancies, and photogenerated electrons and hole activated by fluorescent light. This work shows a potential practicability in HCHO pollution elimination by taking full advantage of the existing lighting in indoor environments. 相似文献