Hydrogen reduced graphene oxide/metal grid hybrid film: towards high performance transparent conductive electrode for flexible electrochromic devices

The metal grid and reduced graphene oxide (RGO) are both promising transparent conductive materials for replacing the indium tin oxide (ITO) in flexible optoelectronics. However, the large empty area that exists in the grid together with the relatively high sheet resistance of RGO hinder both the materials for practical applications. In this work, we report for the first time a novel strategy for efficient combination of the metal grid and RGO by using a newly developed room-temperature reduction technique. The obtained RGO/metal grid hybrid films not only overcome the shortcomings of individual components but exhibit enhanced optical and electrical performances (R_s = 18 Ω sq⁻¹ and T = 80%) and excellent flexural endurance. With this hybrid film as the window electrode, a highly flexible electrochromic device with excellent stability and ultra-fast response shorter than 60 ms has been successfully fabricated. Considering its high efficiency, high quality, low cost and large area, the strategy would be particularly useful for economically fabricating various metal grid/RGO films which are quite promising high performance transparent and conductive materials for next generation optoelectronic devices.     

Performance improvement of conventional and inverted polymer solar cells with hydrophobic fluoropolymer as nonvolatile processing additive

The morphology of the photoactive layer critically affects the performance of the bulk heterojunction polymer solar cells (PSCs). To control the morphology, we introduced a hydrophobic fluoropolymer polyvinylidene fluoride (PVDF) as nonvolatile additive into the P3HT:PCBM active layer. The effect of PVDF on the surface and the bulk morphology were investigated by atomic force microscope and transmission electron microscopy, respectively. Through the repulsive interactions between the hydrophilic PCBM and the hydrophobic PVDF, much more uniform phase separation with good P3HT crystallinity is formed within the active layer, resulting enhanced light harvesting and improved photovoltaic performance in conventional devices. The PCE of the conventional device can improve from 2.40% to 3.07% with PVDF additive. The PVDF distribution within the active layer was investigated by secondary ion mass spectroscopy, confirming a bottom distribution of PVDF. Therefore, inverted device structure was designed, and the PCE can improve from 2.81% to 3.45% with PVDF additive. Our findings suggest that PVDF is a promising nonvolatile processing additive for high performance polymer solar cells.     

Amine-containing olefin copolymer with CO2-switchable oil absorption and desorption

Global decrease in crude oil resources and frequent crude oil leaks cause the energy crisis and ecological pollution. The absorption and release of leaked crude oil through absorption materials are a necessary process for environmental protection and recycling. In this article, a CO₂-responsive olefin copolymer was obtained by copolymerization of styrene and an amine-containing olefin monomer. The structure of resultant copolymer was characterized by FTIR; thermal properties and CO₂-responsive morphology changes were determined by DSC/TGA and SEM, respectively. Copolymers had certain absorption capacity for toluene with absorption rate up to 180.0%. The absorbed toluene could be released upon CO₂ stimulation with desorption rate up to 84.6%. The CO₂-responsive copolymer could be regenerated through a simple heating process and showed stable absorption–desorption performance even after being recycled for 4 times. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47439.     

直线电机抽油机与游梁式抽油机性能对比

攻克了直线电机大推力的关键技术,研制成功了具有国际领先水平的直线电机抽油机。这种抽油机最大特点是改变了过去各种抽油机将电能转变为旋转运动,再通过机械方式转变为直线往复运动的方式,通过变频和控制直接将电能转变为直线往复运动。与游梁式抽油机相比,直线电机抽油机不但提高了机械效率,而且能够实现抽汲参数的无级调整,进而能够根据抽油的需要调整悬点运动规律,具备智能化控制和远程监控的有利条件。     

建筑构件积木式CAD软件研究

西方以混凝土坝内廓道施工样图设计阶段为例，论述水工建筑件积木式ＣＡＤ软件的必要性和积木模块ＣＡＤ软件的具体实现方法。     

奥陶系烃源层中粘球形藻干酪根活化能参数初步研究

我国下古生界烃源层特别是碳酸盐岩地层分布十分广泛,但碳酸盐岩分布区的地球化学评价一直是个薄弱环节,重要原因之一是由于碳酸盐岩的高过成熟性,其地化参数很难取准。本文选用奥陶系烃源层中具有普遍分布意义的低成熟的粘球形藻(G.prisca)干酪根进行热解实验,取得了一系列化学反应动力学参数(活化能E、指前因子A随降解率X的变化关系),这些参数对正确评价下古生界碳酸盐岩地层的油气潜力和生排烃史具有明显的借鉴作用。      

电力变压器蒸发冷却装置FC液位监控系统

介绍电力变压器蒸发冷却装置的液位控制系统,该系统以嵌入式以太网芯片为核心构成网络终端,实现了冷却介质FC液位的远程监测调节。     

基于邻域搜索的OPTA指纹细化改进算法

在指纹细化的研究中,基于OPTA的细化算法及其改进算法普遍存在指纹图像不够光滑,毛刺较多,细化质量不高等现象。为解决上述问题,在OPTA改进算法基础上提出一个新的设计方案。首先重新设计了删除模板和构造模板,然后将该模板设计成一种独特的一维数组查表索引模式,通过计算比较点的邻域值,在表中查找并进行比对判决,即根据邻域的情况来判断一个点是否可以删除。仿真结果表明,用新方法处理后的指纹图像细化完全,骨架接近纹线中心线,光滑无毛刺,且查询速度快,是一种较为成功的细化改进方案。     

爆破P波作用下直埋压力管道安全振速研究

基于爆破产生的P波入射作用下均匀内压薄壁管道的受力特点,采用拟静力分析和叠加原理建立压力管道爆破地震波作用下的应力解析计算模型;基于压力管道材料屈服特性及Tresca屈服理论,建立爆破P波作用下压力管道的振动安全判据计算模型,并结合爆炸影响的直埋压力薄壁管道工程案例进行解析验算。研究结果表明:爆破荷载施加前管道仅受均匀内压,具有初始轴向和切向应力,爆破发生后,管道同时受到内压和爆破地震波P波动荷载作用;管?土界面入射波临界角较小,管道峰值应力随入射角度增大减小,垂直入射时主要发生拉伸破坏,全反射时主要为切向破坏;压力管道安全控制振速随入射角的增大而增大,随运行内压的增大而减小,实际工程中根据管道内压实际情况,选择较小的值作为安全控制值。      

Fluorescent lamp promoted formaldehyde removal over CeO2 catalysts at ambient temperature

Exploring an alternative strategy with high efficiency and low cost to abate formaldehyde (HCHO) in indoor environment, is of increasing significance for people's health. CeO₂ catalysts prepared by hydrothermal, precipitation and calcination methods were investigated for HCHO removal at ambient temperature. It is found that indoor fluorescent light visibly boosts the catalytic performance of CeO₂ catalysts for HCHO decomposition at ambient temperature. Among the CeO₂ catalysts, CeO₂ prepared from hydrothermal method (CeO₂–H) exhibits a superior catalytic performance and an excellent durability by eight recycle times. Based on the characterization and analysis, the excellent catalytic performance of CeO₂–H is mainly contributed by its abundance of surface oxygen vacancies, and photogenerated electrons and hole activated by fluorescent light. This work shows a potential practicability in HCHO pollution elimination by taking full advantage of the existing lighting in indoor environments.