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排序方式: 共有798条查询结果,搜索用时 15 毫秒
1.
Noriyuki Wada Jyoji Hanai Mikiya Furukawa Kazuo Kojima 《Journal of the American Ceramic Society》2019,102(8):4621-4631
To make a Mn2+-doped red glass phosphor that can be excited with ultraviolet (UV) light of light-emitting diodes (LEDs), 60P2O5-35ZnO-5Al2O3-8MnO-xCu2O glasses (x = 0-1.00) were prepared by a melt-quenching method at 1200-1400°C for 30-180 minutes in atmospheric air, and the redox of Mn and Cu as well as fluorescence properties were investigated. The Mn2+ ion was not reduced and oxidized in the melting, quenching, and annealing processes. The valence of Cu in the glasses changed in the order of 0, 1+, and 2+ with the increase in the amount of Cu2O and in the melting temperature and time. In this study, a 60P2O5-35ZnO-5Al2O3-8MnO-0.10Cu2O glass melted at 1250°C for 90 minutes, having the highest Cu+ concentration, showed the strongest Mn2+ red fluorescence under the UV light at 275 nm. This strong Mn2+ red fluorescence has been caused by the energy transfer from excited Cu+ ions to Mn2+ ions. 相似文献
2.
The structural, elastic, and thermodynamic properties of ZnGeP2 with chalcopyrite structure are investigated using the pseudo-potentials plane wave method based on the density functional theory with the generalized gradient approximation. The lattice parameters (a, c and u) are directly calculated and agree well with previous experimental and theoretical results. The obtained negative formation enthalpy shows that ZnGeP2 crystal has strong structural stability. We have also calculated the bulk modulus B and the elastic parameters (C11, C12, C13, C33, C44, and C66) which have not been measured yet. The accuracy and reliability of the calculated elastic constants of ZnGeP2 crystal are discussed. In addition, the pressure and temperature dependencies of the lattice parameters, bulk modulus, Debye temperature, Grüneisen parameter, entropy, volume thermal expansion coefficient, and specific heat capacity are obtained in the ranges of 0–20 GPa and 0–1200 K using the quasi-harmonic Debye model. To our knowledge this is the first quantitative theoretical prediction of the thermodynamic properties for ZnGeP2 compound and still awaits experimental confirmations. 相似文献
3.
Dr. Li Di Prof. Per Artursson Dr. Alex Avdeef Prof. Leslie Z. Benet Prof. J. Brian Houston Dr. Manfred Kansy Edward H. Kerns Prof. Hans Lennernäs Dr. Dennis A. Smith Prof. Kiyohiko Sugano 《ChemMedChem》2020,15(20):1862-1874
Passive permeability is a key property in drug disposition and delivery. It is critical for gastrointestinal absorption, brain penetration, renal reabsorption, defining clearance mechanisms and drug-drug interactions. Passive diffusion rate is translatable across tissues and animal species, while the extent of absorption is dependent on drug properties, as well as in vivo physiology/pathophysiology. Design principles have been developed to guide medicinal chemistry to enhance absorption, which combine the balance of aqueous solubility, permeability and the sometimes unfavorable compound characteristic demanded by the target. Permeability assays have been implemented that enable rapid development of structure-permeability relationships for absorption improvement. Future advances in assay development to reduce nonspecific binding and improve mass balance will enable more accurately measurement of passive permeability. Design principles that integrate potency, selectivity, passive permeability and other ADMET properties facilitate rapid advancement of successful drug candidates to patients. 相似文献
4.
T. YAMAMOTO M. IWATA M. SAKANE Y. TSUKADA H. NISHIMURA 《Fatigue & Fracture of Engineering Materials & Structures》2007,30(5):376-386
This paper describes the creep‐fatigue life of Sn–8Zn–3Bi under push–pull loading. Creep‐fatigue tests were carried out using Sn–8Zn–3Bi specimens in fast–fast, fast–slow, slow–fast, slow–slow and hold–time strain waveforms. Creep‐fatigue lives in the slow–slow and hold‐time waveforms showed a small reduction from the fast–fast lives but those in the slow–fast and fast–slow waveforms showed a significant reduction from the fast–fast lives. Conventional creep‐fatigue life prediction methods were applied to the experimental data and the applicability of the methods was discussed. Creep‐fatigue characteristics of Sn–8Zn–3Bi were compared with those of Sn–3.5Ag and Sn–37Pb. 相似文献
5.
T. Tanaka H. Nakayama K. Kimura 《Fatigue & Fracture of Engineering Materials & Structures》1985,8(1):13-22
The impact fatigue crack growth characteristics of a low carbon steel and an aluminium alloy were studied. An impact fatigue testing machine of the Hopkinson bar type was used in these experiments to conduct a series of crack growth tests under simple impact stresses. The following characteristics of impact fatigue crack growth behaviour were revealed: (1) crack growth rate is higher in impact fatigue than in non-impact fatigue; (2) crack opening ratio in impact fatigue takes a higher value than in non-impact fatigue; (3) crack tip plastic zone size is smaller in impact fatigue than in non-impact fatigue. 相似文献
6.
《Electric Power Systems Research》2005,73(2):121-128
In this paper the performance of a three-phase induction motor operating from single-phase supply with a new electronically controlled capacitor using an electronic switch in series with a fixed capacitor to achieve a minimum unbalance of the motor phase voltages at all loading conditions is proposed. No mechanical or centrifugal switch is used here. Basic system operation, theoretical analysis, simulated and experimental results in comparison with conventional operation using one and two fixed capacitors are presented in this paper. The optimum effective capacitor value can be on-line adjusted at any operating speed by periodically changing the duty cycle of the controlled switch to achieve minimum unbalance in phase voltages to improve the motor performance at different speeds. 相似文献
7.
8.
An HIP compact of MA-processed powder having a nominal composition of Ti-48at.% Al was produced. The compact consisted of a large amount of TiAl(λ) and a small amount of Ti3Al (2), in a completely ultra-fine equiaxed grain structure. This two-phase compact showed typical superplastic deformation behaviour. A maximum elongation of 550% was obtained. A strain exponent, n = 2, and grain size exponent, p = 2, were determined from the results of a strain-rate-change test and a creep test at constant initial stress using samples having various grain sizes, respectively. The activation energy for creep, Qc at constant stress was calculated to be 350 kJ/mole. It is concluded that the superplastic deformation mechanism of the material under study is grain boundary sliding controlled by lattice diffusion in the TiAl phase. 相似文献
9.
K Yamada 《Water science and technology》2007,56(1):11-20
Many parts of Japan have experienced rapid urbanization and industrialization over the past 50 years. This trend resulted in severe water pollution in many urban areas. To address the pollution problems, several measures such as construction of sewerage systems and enactment of laws and regulations have been undertaken. Because of these measures, the water quality has been improved to some extent. However, many water quality concerns still remain and are attributed in part to diffuse pollution. In this paper, historical progress, present situation and future aspects of diffuse pollution problems in Japan are reviewed. It is noted that solving diffuse pollution problems will require a combination of several measures including application of conventional treatment technologies and natural purification systems, implementation of appropriate policy measures, and promotion of citizen participation. 相似文献
10.