A dotted nanowire arrayed by 5 nm sized palladium and nickel composite nanopaticles showing significant electrocatalytic activity towards ethanol oxidation reaction (EOR)

To the best of our knowledge, this is the first time to report the preparation of a dotted nanowire arrayed by 5 nm sized palladium and nickel composite nanoparticles (denoted as Pd_xNi_y NPs) via a hydrothermal method using NU and PdO·H₂O as the starting materials. The samples prepared at the mass ratio of NU to PdO·H₂O 1:1, 1:2 and 2:1 were, respectively, nominated as catalyst c₁, c₂ and c₃. The chemical compositions of all synthesized catalysts were mainly studied by using X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), revealing that metallic Ni was one main component of all prepared catalysts. Surprisingly, the main diffraction peaks appearing in the XRD patterns of all prepared catalysts were assigned to the metallic Ni rather than the metallic Pd. Very interestingly, as indicated by the TEM images, a large number of dotted nanowires arrayed by numerous equidistant 5 nm sized nanoparticles were distinctly exhibited in catalyst c₁. More importantly, when being used as electrocatalysts for EOR, all prepared catalysts exhibited an evident electrocatalytic activity towards EOR. In the cyclic voltammetry (CV) test, the peak current density of the forward peak of EOR on catalyst c₁ measured at 50 mV s^?1 was as high as 56.1 mA cm^?2, being almost 9 times higher than that of EOR on catalyst c₃ (6.3 mA cm^?2). Particularly, the polarized current density of EOR on catalyst c₁ at 3600 s, as indicated by the chronoamperometry (CA) experiment, was still maintained to be around 1.47 mA cm^?2, a value higher than the latest reported data of 1.3 mA cm^?2 (measured on the pure Pd/C electrode). Presenting a novel method to prepare dotted nanowires arranged by 5 nm sized nanoparticles and showing the significant eletrocatalytic activities of the newly prepared dotted nanowires towards EOR were the major contributions of this preliminary work.     

钢管套筒灌浆连接轴向受拉性能模拟试验研究

为研究钢管套筒灌浆连接轴向受拉破坏过程及破坏机理，试验中设计了16组48个钢管套筒灌浆连接试件，试件采用钢板代替圆钢管，并进行静载试验。分析了灌浆料裂缝扩展过程、荷载-相对位移曲线，并对抗剪键高距比、灌浆料厚度、侧向力等因素对破坏过程及承载力的影响进行分析。结果表明：对于不设置抗剪键的套筒灌浆连接试件，斜裂缝随机产生，裂缝分布不均匀；对于设置抗剪键的套筒灌浆连接试件，裂缝首先出现在底部抗剪键位置处，与水平方向夹角约为30°，随后在中部和上部抗剪键位置处分别出现斜裂缝。由于每个抗剪键上荷载分担并不均匀，与抗剪键接触的灌浆料逐渐达到极限压应力，达到极限状态时，承载力全部由抗剪键间的机械咬合力承担，在连接承载力中，可忽略摩擦力和胶结力作用。随着抗剪键高距比h/s增大，各试件初始剪切刚度相差不大，承载力增大，但增幅逐渐减小，建议抗剪键高距比0.06g/s>0.3，同时需要满足灌浆料灌注的施工要求。     

新型TBS分选机的研究

传统TBS在使用中又存在着处理粒度范围窄、入料浓度要求较高、可控参数少、对于难选煤的处理效果差等问题,通过增加倾斜管,采用脉动水流与干扰沉降相结合,底部增加旋流分选的措施,达到增强其适应性,改善处理效果的目的。     

DP980+Z烘烤硬化值与退火温度的关系

摘要：为了研究退火温度对镀锌DP980+Z烘烤硬化值的影响，退火温度控制在760～820℃之间，系统分析退火温度对烘烤硬化值的影响。通过准静态拉伸试验机测量烘烤硬化值及抗拉强度，采用lepara试剂对组织中的马氏体进行着色，利用金相显微镜及图像处理软件测量马氏体的体积分数；采用扫描电镜观察DP980+Z的双相组织特点，并且将组织图片通过CAD转化成有限元图进行网格划分，建立代表性体积单元（RVE），通过有限元分析铁素体、马氏体强度对烘烤硬化值的影响。在同样的变形量情况下，DP980+Z的原始屈服强度越高，烘烤硬化值越高。     

结晶器液面自动控制系统在唐钢板坯连铸机的应用

介绍了涡流法和同位素法2种结晶器钢水液面自动控制检测方式,及其在唐钢板坯连铸机的应用.     

废塑料改性沥青的性能研究

通过沥青基本性能测试、荧光显微镜观察研究了废塑料（PE）对改性沥青高温性能的影响及其机理,并通过对改性沥青混合料的马歇尔稳定度测试及对沥青混合料断口观察研究了混合料的强度及高温性能。结果表明：废PE达到一定剂量时,在沥青中形成网状结构,增强了改性沥青的高温性能；加入废PE后,沥青与矿料的结合强度提高,提高了沥青混合料的高温稳定性。     

天车称重系统解析

以河北钢铁集团唐山钢铁有限责任公司一钢轧厂240t天车称重系统为例,介绍天车称重系统的硬件结构、工作原理、传输方式、仪表功能、称重传感器原理、钢丝绳补偿、信号传输、称重仪表等,结合在生产中的实际运行状况,总结出在生产维护中的常见问题,并提出具体的解决方法。     

浅谈基于云计算技术的医疗信息化

该文通过分析影响医疗信息化建设与快速发展的主要因素以及对于云计算技术的概念、特点及其发展现状进行了解,简要介绍了云计算技术为医疗卫生信息化建设提供的服务,分析了云计算技术为医疗信息化建设所带来的益处,探讨了云计算技术在医疗信息化应用中所面临的挑战。     

Improved electric insulation ability and ferromagnetic property in Nb2O5 doped BiFeO3-based multiferroic ceramics

Journal of Electroceramics - 0.675BiFeO3-0.3BaTiO3-0.025LaFeO3-x mol% Nb2O5 (x?=?0–1.25) multiferroic lead- free ceramics, fabricated by conventional solid-state reaction, were...