Characterization of poly(vinyl alcohol)/sodium bromide polymer electrolytes for electrochemical cell applications

Sodium‐ion conducting polymer electrolytes based on poly(vinyl alcohol) complexed with sodium bromide were prepared with a solution‐casting technique. The structure of these films was determined with X‐ray diffraction, and the complexation of the salt with the polymer was confirmed with Fourier transform infrared spectroscopy studies. Electrical conductivity was measured with an alternating‐current impedance analyzer in the frequency range of 100 Hz to 1 MHz and in the temperature range of 303–373 K. It was observed that the magnitude of conductivity increased with the increase in the salt concentration as well as the temperature. The nature of the charge transport in these polymer electrolyte films was determined with both Wagner's polarization technique and the Watanabe technique. The dominant conducting species were found to be ions, particularly anions. Optical absorption studies were performed in the wavelength range of 200–600 nm, and the absorption edge, direct band gap, and indirect band gap values were evaluated. Electrochemical cells were fabricated, and their discharge characteristics were studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Construction of two-dimensional supramolecular structure containing water tetramer and octamer

The complex [Cd₂(phen)₄(p-phth)(H₂O)₂](p-phth) · 10H₂O (1) has been synthesized by the reaction Cd(NO₃)₂ with phen and p-phth (where phen = 1,10-phenanthroline, p-phth = p-phthalic acid) in a solution of ethanol and distilled water. The crystal structure was characterized by X-ray single-crystal diffraction and infrared spectrum. In 1, a novel 2D supramolecular structure was formed, containing water octamer and tetramer.     

Electrical properties of ZnSe-CdS alloy films

Thin films of ZnSe _x CdS_1–x (t 0.6 m) over the entire range of x, were deposited on glass substrates at two temperatures, T _s (350 and 470 K) by vacuum evaporation. X-ray diffraction studies showed that all the films were polycrystalline in nature. Films prepared at 470 K were nearly stoichiometric. Grain size increased with substrate temperature, T _s. The electrical conductivity and Hall measurements were carried out by d.c. van der Pauw technique. Hall effect studies/hot probe test showed that all the films were of n-type conductivity. Hall mobility increased with T _s. In addition, mobilities increased with temperature in films of all compositions, indicating the dominance of grain-boundary scattering. Grain-boundary potentials were in range 0.03–0.06 eV.     

Hamshahri: A standard Persian text collection

The Persian language is one of the dominant languages in the Middle East, so there are significant amount of Persian documents available on the Web. Due to the different nature of the Persian language compared to the other languages such as English, the design of information retrieval systems in Persian requires special considerations. However, there are relatively few studies on retrieval of Persian documents in the literature and one of the main reasons is the lack of a standard test collection. In this paper, we introduce a standard Persian text collection, named Hamshahri, which is built from a large number of newspaper articles according to TREC specifications. Furthermore, statistical information about documents, queries and their relevance judgments are presented in this paper. We believe that this collection is the largest Persian text collection, so far.     

MHD combined free and forced convection flow through two parallel porous walls

Summary The flow of a viscous conducting fluid between two parallel plates of infinite length (one of which is at rest and the other moving parallel to itself with a linear axial temperature variation) under the influence of a uniform transverse magnetic field is considered. It is assumed that the fluid is injected into the channel through the lower wall and sucked from the channel through the upper wall with the same velocityv ₀. The velocity and temperature distributions, the coefficient of skin friction and the rate of heat transfer coefficient are evaluated. The effects of magnetic parameterM, the suction Reynolds numberR, the Grashoff numberG and Binkmann numberB on the above mentioned physical quantities are investigated.With 21 Figures     

Absorption and emission properties of Ho doped lead-zinc-borate glasses

This paper reports on the affect of lead content on the absorption and emission spectra of the Ho³⁺ ion doped lead-zinc-borate glasses in the composition (mol%) of (20 − x)PbO-20ZnO-(59 + x)B₂O₃-1.0Ho₂O₃ where x = 0, 5,10,15 of PbO content with λ_exc = 405 nm. The experimental absorption band energies have satisfactorily been correlated with the theoretical results with an r.m.s deviation of zero with the following correction factors obtained by a least square fit analysis: ΔE¹ = 348.495936 cm^− 1, ΔE² = 1.436043 cm^− 1, ΔE³ =  46.481575 cm^− 1, Δξ_4f = − 28.512979 cm^− 1, Δα = 55.508936 cm^− 1, Δβ = − 1394.339908 cm^− 1 and Δγ = 1208.424336 cm^− 1. By applying the Judd-Ofelt intensity parameter Ω₂ has been found to be linearly decreasing with the PbO content from 5 to 10 mol% and then increasing. And also radiative (A, A_T, β, τ_r) characteristic factors of the luminescent transitions (⁵I₈ ← ⁵F_3,4,5 and ⁵S₂) of the glasses have been evaluated. Stimulated emission cross-sections (σ_p^E) of the measured emission transitions of holmium glasses have also been computed.     

Synthesis of nanocrystalline MMoO4 (M = Ni,Zn) phosphors via a citrate complex route assisted by microwave irradiation and their photoluminescence

Nanocrystalline MMoO₄ (M = Ni, Zn) phosphors, which have wolframite-type structure, were successfully synthesized at low temperatures via a modified citrate complex route assisted by microwave irradiation. The citrate complex precursors were heat-treated from 300 to 600 °C for 3 h. Crystallization of the MMoO₄ (M = Ni, Zn) nanocrystallites were detected at 500 °C, and entirely completed at a temperature of 600 °C. The nanoparticles presented primarily dispersed and homogeneous morphology with particle size of 20–40 nm. The nanocrystalline MMoO₄ (M = Ni, Zn) phosphors prepared at 600 °C exhibited broad luminescence in green and blue wavelength region, respectively.     

Characterization of reacted ohmic contacts to GaAs

In the calculation of the true value of specific resistivity of reacted ohmic contacts, a modification in the conductivity of the semiconductor that may occur below the contact must be considered. Contacts to GaAs are discussed. A substantial decrease in the sheet resistance of p-type GaAs is measured for Pt-reacted contacts in which a single thin layer of Mg is interposed. It is pointed out that this lowering, which is attributed to the doping action of Mg, if not taken into account, can lead to serious errors in the estimation of specific contact resistivity.