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1.
Abdelbaki Benamor Brahim Si Ali Mohamed Kheireddine Aroua 《Korean Journal of Chemical Engineering》2008,25(3):451-460
The absorption rates of CO2 into aqueous solutions of Diethanolamine (DEA) with varying concentrations from 0.2 to 4M and temperature range from 293
to 323 K were measured by using a laboratory stirred reactor. The CO2 partial pressure was varied in a range that the reaction would occur in pseudo first order regime. Experimental data were
analyzed and the kinetic parameters associated with the reaction were determined. The activation energy for the deprotonation
of the intermediate zwitterion was estimated at about 11.4 kcal/mol. The contribution of carbamate formation to the overall
absorbed CO2 was experimentally evaluated and found to be of the order of 100%. 相似文献
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4.
《Fuel》2006,85(5-6):867-870
Crude and distilled palm oil methyl esters conveniently known as palm diesel have been successfully evaluated as diesel substitute. Crude palm oil methyl esters are produced from transesterification of crude palm oil with minor components such as carotenes and vitamin E still intact and they are reddish in colour. The distilled palm oil methyl esters are obtained after the recovery of minor components (e.g. Carotenes and vitamin E) From the crude palm oil methyl esters. These valuable minor components are preferably to be recovered as they can be sold as value-added products before they are burnt together with the methyl esters as fuel. Although both possesses fuel characteristics which are comparable to those of petroleum diesel, crude palm oil methyl esters are found to exhibit better oxidative stability (rancimat induction period >25 h) than distilled palm oil methyl esters (about 3.5 h). It is attributed to the presence of vitamin E (about 600 ppm), a natural antioxidant in the former. While the distilled palm oil methyl esters contain practically no vitamin E (<50 ppm) and as a result, they exhibit poor oxidative stability. Thus, the crude palm oil methyl esters meet the european standard for biodiesel (EN 14214) which has set a minimum rancimat induction period of 6 h. In the present study, research was conducted to enhance the oxidative stability of distilled palm oil methyl esters in order to meet the aforementioned standard. Natural and synthetic antioxidants were used in the present study to investigate their effect on the oxidative stability of distilled palm oil methyl esters. It was found that both types of antioxidant showed beneficial effects in inhibiting the oxidation of distilled palm oil methyl esters. Comparatively, the synthetic antioxidants were found to be more effective than the natural antioxidants as lower dosage (17 times less) was needed to achieve the minimum rancimat induction period of 6 h. 相似文献
5.
《Solid-state electronics》2006,50(7-8):1382-1388
We have performed the first principles full-potential linearized augmented plane wave calculations (FP-LAPW) with density functional theory in local density approximations (LDA), in aim to determine and to predict the pressure dependence of structural and optical properties of zinc-blende BeS, BeSe and BeTe compounds. The elastic constant, refractive index and its variation with hydrostatic pressure are well described. 相似文献
6.
《Cement and Concrete Composites》2007,29(1):13-21
There are ∼6700 million tons of perlite reserves in the world and two thirds of this amount takes place in Turkey. Although perlite possesses pozzolanic properties, it has not been so far used in producing blended cements. This study focuses on the use of natural perlites in blended cement production. For this purpose, after examining the suitability of the perlites as pozzolans and their ease of grindability, 16 types of blended cements having 320 m2/kg or 370 m2/kg Blaine fineness were produced by using 20% or 30% perlite additions. Production of the blended cements were accomplished either by intergrinding or separate grinding. The performance of the cements was evaluated by conducting the following tests: particle size distribution by laser diffraction, normal consistency, setting time, soundness and compressive strength. The results showed that perlites possess sufficient pozzolanic characteristics to be used in production of blended cement. 相似文献
7.
YF Ngeow 《Canadian Metallurgical Quarterly》1996,25(2):300-304
Infection with Chlamydia trachomatis results in the formation of a variety of antibodies with group, species, subspecies and serovarspecificity. Sera from patients with genital tract infections often show broad reactivity in serological tests. This may be due to the presence of cross-reacting antibodies, repeated infections by different serotypes or concurrent genital and respiratory infections by different chlamydial species. Other factors contributing to difficulties in interpretation include how antibody titres in acute mucosal infections, the occurrence of latent infections and reactivations, and the persistence of IgG which does not allow the differentiation of past from current infections. For these reasons, serology alone is inadequate for the diagnosis of uncomplicated lower genital tract infections. In upper genital tract infections, however, because of difficulties with sampling from the infected site, a positive serology may be the only indications of chlamydial involvement. This paper discusses the principles of chlamydial antibody assays, difficulties with their interpretation and their role in the diagnosis of upper and lower genital tract infections. 相似文献
8.
Privacy issues are frequently discussed amongst researchers, practitioners and patients in healthcare. However, psychiatric patients’ privacy issues get less attention in information system development (ISD), whereby they are one of the most important stakeholders. This paper applies Carew and Stapleton’s ISD privacy framework to psychiatric monitoring systems to understand the issues that are related to monitoring psychiatric patients’ behaviour. By understanding the privacy issues amongst patients, the research will be able to provide guidance to system developers to produce a privacy-sensitive system that can contribute to the system engineering for international stability. We will elaborate each factor in the framework (physical, social, psychological and informational) and then explain the relationship to the privacy of psychiatric patient. 相似文献
9.
《Expert systems with applications》2014,41(18):8225-8233
The current web IR system retrieves relevant information only based on the keywords which is inadequate for that vast amount of data. It provides limited capabilities to capture the concepts of the user needs and the relation between the keywords. These limitations lead to the idea of the user conceptual search which includes concepts and meanings. This study deals with the Semantic Based Information Retrieval System for a semantic web search and presented with an improved algorithm to retrieve the information in a more efficient way.This architecture takes as input a list of plain keywords provided by the user and the query is converted into semantic query. This conversion is carried out with the help of the domain concepts of the pre-existing domain ontologies and a third party thesaurus and discover semantic relationship between them in runtime. The relevant information for the semantic query is retrieved and ranked according to the relevancy with the help of an improved algorithm. The performance analysis shows that the proposed system can improve the accuracy and effectiveness for retrieving relevant web documents compared to the existing systems. 相似文献
10.
Estimation and forecasting with logarithmic autoregressive conditional duration models: A comparative study with an application 总被引:1,自引:0,他引:1
《Expert systems with applications》2014,41(7):3323-3332
This paper presents a semi-parametric method of parameter estimation for the class of logarithmic ACD (Log-ACD) models using the theory of estimating functions (EF). A number of theoretical results related to the corresponding EF estimators are derived. A simulation study is conducted to compare the performance of the proposed EF estimates with corresponding ML (maximum likelihood) and QML (quasi maximum likelihood) estimates. It is argued that the EF estimates are relatively easier to evaluate and have sampling properties comparable with those of ML and QML methods. Furthermore, the suggested EF estimates can be obtained without any knowledge of the distribution of errors is known. We apply all these suggested methodology for a real financial duration dataset. Our results show that Log-ACD (1, 1) fits the data well giving relatively smaller variation in forecast errors than in Linear ACD (1, 1) regardless of the method of estimation. In addition, the Diebold–Mariano (DM) and superior predictive ability (SPA) tests have been applied to confirm the performance of the suggested methodology. It is shown that the new method is slightly better than traditional methods in practice in terms of computation; however, there is no significant difference in forecasting ability for all models and methods. 相似文献