Hybrid photocatalytic membranes embedding decatungstate for heterogeneous photooxygenation

The incorporation of decatungstate in polymeric membranes provides new heterogeneous photocatalysts for the oxidation of organic substrates under oxygen atmosphere at 25 °C. Photocatalytic membranes have been prepared yielding polymeric films with a high thermal, chemical and mechanical stability (PVDF, PDMS, Hyflon). Surface spectroscopy techniques including transmittance and reflectance UV-Vis and FT-IR have been used to assess the photocatalyst integrity within the polymeric support. Catalyst screening has been performed under both homogeneous and heterogeneous photooxygenation conditions. The photocatalyst activity has been evaluated in terms of the substrate conversion, turnover numbers, and recycling experiments. A membrane induced selectivity behavior has been evidenced by comparison with homogeneous oxidations.     

The removal of arsenic from （ground）-water by adsorbent loaded in polymeric microspheres

Arsenic is a natural tasteless and odourless element,existing in the earth’s crust at average levels of between two and five thousands micrograms per liter (parts per million) . Arsenic is highly toxic to humans, who are exposed to it primarily from air,food and water. The occurrence of arsenic in groundwater is due to geological composition of soil. High concentrations of arsenic in water are the result of dissolution or desorption of ferric oxides and the oxidation of mineral arsenopyrites. Arsenic in drinking water has an important impact on the human health,especially in the less developed countries. Different methods exist to remove arsenic from aquatic media,and one of them is by adsorption. In this work,the adsorption of both As(III) and As(V) by means of novel microspheres has been investigated. In particular,TiO2 has been embedded into polymeric microspheres PES (PolyEtherSulphone) and PEEK-WC (PolyEtherEther-Ketone) . The main advantages of this encapsulation adsorption material are: no loss of adsorbents into the water stream,easy to be used and scaled-up.     

Investigating the effect of SPRM on mechanical strength and thermal conductivity of highly porous alumina ceramics

For recycling waste refractory materials in metallurgical industry, porous alumina ceramics were prepared via pore forming agent method from α-Al₂O₃ powder and slide plate renewable material. Effects of slide plate renewable material (SPRM) on densification, mechanical strength, thermal conductivity, phase composition and microstructure of the porous alumina ceramics were investigated. The results showed that SPRM effectively affected physical and thermal properties of the porous ceramics. With the increase of SPRM, apparent porosity of the ceramic materials firstly increased and then decreased, which brought an opposite change for the bulk density and thermal conductivity values, whereas the bending strength didn’t decrease obviously. The optimum sample A2 with 50 wt% SPRM introducing sintered at 1500 °C obtained the best properties. The water absorption, apparent porosity, bulk density, bending strength and thermal conductivity of the sample were 31.7%, 62.8%, 1.71 g/cm³, 47.1 ± 3.7 MPa and 1.73 W/m K, respectively. XRD analysis indicated that a small quantity of silicon carbide and graphite in SPRM have been oxidized to SiO₂ during the firing process, resulting in rising the porous microstructures. SEM micrographs illustrated that rod-like mullite grains combined with plate-like corundum grains to endow the samples with high bending strength. This study was intended to confirm the preparation of porous alumina ceramics with high porosity, good mechanical properties and low thermal conductivity by using SPRM as pore forming additive.     

On the determination of mechanical properties of composite laminates using genetic algorithms

This paper describes a method which combines finite element analysis and genetic algorithms (GAs) for identifying the elastic constants of composite laminates by using vibration test data. A procedure updates the elastic constants in a numerical model so that the output from the numerical code fits the results from vibration testing. In this approach, the elastic constants can be readily identified in a single test without damaging the structure. The GA, developed on a personal computer using the language MATLAB, applies the general-purpose numerical code MSC-NASTRAN to carry out the modal analysis.     

Boron removal by membrane contactors: the water that purifies water

The potential of membrane contactors for treating boron containing waters were investigated. In particular, experimental tests at lab scale on flat membrane modules with 40 cm² of membrane area were carried out, to identify the effect of different parameters, such as temperature, flow rate, boron concentration, etc. on the efficiency of the process. Water was chosen as the extractant in order to avoid the pollution of the feed stream and two symmetric microporous hydrophilic flat membranes with different pore size and porosity were used. From these tests, it results that the boron removal increases with the extractant temperature and with the operating flow rates. However, it is independent on the initial boron concentration in the feed water. Moreover, higher removals are obtained with the membrane with larger pore size and higher porosity. Based on the experimental results, an integrated reverse osmosis-membrane contactor system, where the membrane contactor works on the reverse osmosis permeate, was proposed and designed for a 100 m³/h fresh water production (with a boron content ≤0.4 ppm). In particular, membranes with higher porosity and lower thickness than those used in the experimental tests were considered for the calculations, in order to work at 25°C (so, there is no need of heating the extractant stream) with reasonable membrane areas. The comparison of the proposed plant to that actually used, has shown that the proposed one appears to be more effective in terms of size, energy and chemical consumption, flexibility and modularity.     

Methane steam reforming in a Pd-Ag membrane reformer: An experimental study on reaction pressure influence at middle temperature

In this experimental work, methane steam reforming (MSR) reaction is performed in a dense Pd-Ag membrane reactor and the influence of pressure on methane conversion, CO_x-free hydrogen recovery and CO_x-free hydrogen production is investigated. The reaction is conducted at 450 °C by supplying nitrogen as a sweep gas in co-current flow configuration with respect to the reactants. Three experimental campaigns are realized in the MR packed with Ni-ZrO catalyst, which showed better performances than Ni-Al₂O₃ used in a previous paper dealing with the same MR system. The first one is directed to keep constant the total pressure in both retentate and permeate sides of the membrane reactor. In the second case study, the total retentate pressure is kept constant at 9.0 bar, while the total permeate pressure is varied between 5.0 and 9.0 bar. As the best result of this work, at 450 °C and 4.0 bar of total pressure difference between retentate and permeate sides, around 65% methane conversion and 1.2 l/h of CO_x-free hydrogen are reached, further recovering 80% CO_x-free hydrogen over the total hydrogen produced during the reaction. Moreover, a study on the influence of hydrogen-rich gas mixtures on the hydrogen permeation through the Pd-Ag membrane is also performed and discussed.     

A discrete constitutive model for transverse and shear damage of symmetric laminates with arbitrary stacking sequence

A damage constitutive model in conjunction with a 2-D finite element discretization is presented for predicting onset and evolution of matrix cracking and subsequent stiffness reduction of symmetric composite laminates with arbitrary stacking sequence subjected to membrane loads. The formulation uses laminae crack densities as the only state variables, with crack growth driven by both mechanical stress and residual stress due to thermal expansion. The formulation is based on fracture mechanics in terms of basic materials properties, lamina moduli, and critical strain energy release rates G_IC and G_IIC, only. No additional adjustable parameters are needed to predict the damage evolution. Spurious strain localization and mesh size dependence are intrinsically absent in this formulation. Thus, there is no need to define a characteristic length. Comparison of model results to experimental data is presented for various laminate stacking sequences. Prediction of crack initiation, evolution, and stiffness degradation compare very well to experimental data.     

A heuristic for the periodic rural postman problem

The periodic rural postman problem (PRPP) is variant of the classical rural postman problem whose applications arise in garbage collection and street sweeping. In the PRPP each required arc/edge of a graph must be visited a given number of times over an m-day planning period in such a way that service days are equally spaced. The PRPP amounts to select a service day combination for each required arc/edge and to determine a postman tour for each day of the planning period. The objective is to minimize the total distance travelled. In this paper a simple but effective heuristic for the undirected PRPP is presented. Extensive computational results indicate that the algorithm is capable of providing high quality solutions. To our knowledge this is the first methodological paper devoted to a periodic arc routing problem.     

Ultrasonic and laser measurements in structural contact problems

This paper deals with two experimental techniques recently set up by the authors which enable the study of contact problems between elastic bodies. The more widely used experimental techniques for determining the response of elastic bodies in unilateral contact include moiré fringes, holography and photoelasticity. The experimental techniques proposed here utilize either the ultrasonic pulse transit time method or the laser beam intensity method. Both techniques are applied to measure the relative displacements and the contact area of beam and plate models in unilateral contact with an elastic half-space model. The experimental results, compared with those obtained by numerical analysis, show the efficiency and validity of the measurement techniques proposed.

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Resume Cet article traite de deux techniques expérimentales récemment mises au point par les auteurs, qui permettent d’étudier les problèmes de contact entre corps élastiques. Les techniques expérimentales les plus largement utilisées pour déterminer la réponse des corps élastiques dans le contact unilatéral sont la méthode du moiré, l’holographie et la photoélasticité. On propose ici deux méthodes expérimentales: l’une par la mesure du temps de réflexion ultrasonique, l’autre par la mesure de l’intensité d’un rayon laser. On applique les deux techniques à la mesure des déplacements relatifs et de la surface de contact entre des modèles de poutre et de plaque en contact unilatéral avec un modèle de semi-espace élastique. Les résultats experimentaux, quand on les compare avec ceux obtenus par analyse numérique, montrent l’efficacité et la validité des techniques de mesure proposées.

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