Doping-free hybrid white organic light-emitting diodes with fluorescent blue,phosphorescent green and red emission layers

Industrialized white organic light-emitting diodes (OLEDs) currently require host-guest doping, a complicated process necessitating precise control of the guest concentration to get high efficiency and stability. Two doping-free, hybrid white OLEDs with fluorescent blue, and phosphorescent green and red emissive layers (EMLs) are reported in this work. An ultra-thin red phosphorescent EML was situated in a blue-emitting electron transport layer (ETL), while the ultra-thin green phosphorescent EML was placed either in the ETL (Device 1), or the hole transport layer (HTL) (Device 2). Device 2 exhibits higher efficiency and more stable spectrum due to the enhanced utilization of excitons by ultra-thin green EML at the exciton generation zone within the HTL. Values of current efficiency (CE), power efficiency (PE), and CRI obtained for the optimized hybrid white OLEDs fabricated through a doping-free process were of 23.2 cd/A, 20.5 lm/W and 82 at 1000 cd/m², respectively.     

Theoretical investigations on the spin Hamiltonian parameters for Er3+ ion in LiYF4

The spin Hamiltonian parameters g_∥, g_⊥, A_∥ and A_⊥ for Er³⁺ ion in LiYF₄ are investigated by using the perturbation formulas of these parameters for a 4f¹¹ ion in tetragonal symmetry. In these formulas, the contributions to the spin Hamiltonian parameters from the second-order perturbation terms and the admixtures of different states are considered. The relevant crystal field parameters are calculated from the superposition model and the local structural parameters of the Y³⁺ site occupied by impurity Er³⁺. The theoretical optical spectra within ⁴I_15/2 and ⁴I_13/2 states and the spin Hamiltonian parameters obtained in this work are consistent with the observed values.     

X-ray structure analysis and elastic properties of a fabric reinforced carbon/carbon composite

The effect of heat treatment on microstructure of a plain-weave carbon fabric reinforced carbon-carbon composite with phenolformaldehyde-derived carbon matrix was investigated by X-ray diffraction. The diffraction patterns were analysed by the least-square fitting program Carbonxs. After heat treatment from 1000 to 2800 °C the interplanar distance of (002) planes decreased from 3.488 to 3.420 Å and the lattice parameter in basal plane increased from 2.440 to 2.464 Å, respectively. Simultaneously, the coherent block size in the basal plane directions increased from 18 to 54 Å, which was accompanied by an increase of the fraction of organised carbon atoms from 0.50 to 0.85. The 002 diffraction profile of the composite was much narrower than the sum of peaks of the matrix and fabric alone. This can probably be caused by a better crystallographic ordering (or by a partial graphitisation) of the matrix in the composite. On the other hand, the composite Young’s modulus slightly decreased with the treatment temperature increasing from 2200 to 2800 °C in spite of the established strong improvement of fibre crystallinity and, therefore, fibre modulus. The mechanisms diminishing the modulus of composite (e.g. partial matrix graphitisation at the fibre/matrix interface and decreasing fibre/matrix contact area) probably prevailed over the increasing contribution of the fibre modulus.     

激光选区熔化Ti6Al4V合金的工艺参数优化

孔洞、未熔粉、裂纹是在激光选区熔化制备试样过程中常见的缺陷,迄今为止,大量研究均集中在减少缺陷上,关于工艺参数对缺陷影响的研究较少。本文系统研究了工艺参数对激光选区熔化Ti6Al4V合金相对密度、表面粗糙度、力学性能的影响。结果表明,低激光功率、高扫描速度和高层厚将会引起不充分的粉末熔化以及球化效应。最佳工艺参数为激光功率200 W,扫描速度500 mm/s,层厚10 μm,扫描间距105 μm。在该参数下,试样的抗拉强度1077 MPa,屈服强度907 MPa。     

基于多级递阶结构的核电工程管理系统模式与优化

应用系统工程解释结构模型ISM法,结合项目管理方法论,对核电工程项目管理系统进行结构分析,建立其递阶结构模型,并通过模型对管理要素进行优化整合,说明了核电工程AE公司的EP结合,以及进一步实现EPC结合,将能简化核电工程管理系统结构,使管理系统清晰、高效。由此得出在我国核电即将开始的批量化建设时期,培育发展专业化的核电AE工程公司的必要性。研究结果对我国核电工程建造方式选择与管理系统优化具有重要的理论和应用价值。     

Costate estimation for dynamic systems of the second order

The dynamics of a mechanical system in the Lagrange space yields a set of differential equations of the second order and involves much less variables and constraints than that described in the state space. This paper presents a so-called Legendre pseudo-spectral (PS) approach for directly estimating the costates of the Bolza problem of optimal control of a set of dynamic equations of the second order. Under a set of closure conditions, it is proved that the Karush-Kuhn-Tucker (KKT) multipliers satisfy the same conditions as those determined by collocating the costate equations of the second order. Hence, the KKT multipliers can be used to estimate the costates of the Bolza problem via a simple linear mapping. The proposed approach can be used to check the optimality of the direct solution for a trajectory optimization problem involving the dynamic equations of the second order and to remove any conversion of the dynamic system from the second order to the first order. The new approach is demonstrated via two classical benchmark problems. Supported by the National Natural Science Foundation of China (Grant Nos. 10372039, 10672073), and the Innovation Fund for Graduate Students of NUAA (Grant No. 4003-019016)     

Caking property and active components of coal based on group component separation

The content and the caking index of the heavy,the dense medium and the loose medium components of coal,obtained by extraction and stripping with CS_2/N-methyl-2-pyrrolidinone mixed solvent(1:1 by volume),were studied and correlated with the caking property of raw coals.Images of the three group components after heat treatment were analyzed.The results show that both caking index(G) and maximum thickness of plastic layer(Y) of coals have a good linear relationship with the content of the medium component;the dense medium and the loose medium components are the two key factors to determine the caking property of raw coals-they are the source materials of fluidity and swelling of coal,respectively;the heavy component without the swelling and fluidity was cohered by the other components;two new indexes,which can extend current understanding of the caking properties,were introduced.     

双酚A型聚碳酸酯快速拉伸过程的分子动力学模拟

本文采用用分子动力学方法研究了双酚A型聚碳酸酯的快速拉伸过程.采用COMPASS力场和NPT系综研究了应力应/变关系、能量/应变关系等.应力-应变曲线的研究结果显示,前"屈服点"和后"屈服点"分别为0.14和0.17,应变≤0.05为"弹性区域".0.14<ε_(xx)<1.05的区域为"塑性区域",ε_(xx)>1.05属于"硬化"区.能量-应力关系的研究结果显示,在应力-应变呈线性关系的"弹性区域",体系的总势能及各势能分量随应变增大发生不规则的波动.为了从能量的角度解释PBC-PC在外部拉伸条件下的应变情况,本文还研究了体系总能量与各能量分项,与应变的关系,对链结构与能量分项的关系进行了讨论.     

聚能装药对双层板的动态响应分析

聚能爆炸的过程是非常复杂,很难进行精确的解析分析,通过实验手段研究则耗资过于巨大,所以数值分析是有效的近似手段.对于聚能射流对靶板的作用的研究比较少.ALE单元算法是一种比较新的有关流固耦合的算法,因此利用非线性有限元ANSYS/LS-DYNA软件中ALE算法,分别计算两种装药形式(圆锥形装药和球缺形装药)对双层板破坏的动力响应,分析了各计算结果,对比了破口,位移以及应力等变量.得到结论:圆锥形装药在纵向上的破坏要强于球缺形装药,然而球缺形装药能产生更大的破口.     

Toward Flexible Embodied Energy: Scale-Inspired Overlapping Lithium-Ion Batteries with High-Energy-Density and Variable Stiffness

High performance flexible batteries are essential ingredients for flexible devices. However, general isolated flexible batteries face critical challenges in developing multifunctional embodied energy systems, owing to the lack of integrative design. Herein, inspired by scales in creatures, overlapping flexible lithium-ion batteries (FLIBs) consisting of energy storage scales and connections using LiNi_0.5Co_0.2Mn_0.3O₂ (NCM523) and graphite electrodes are presented. The scale-dermis structure ensures a high energy density of 374.4 Wh L⁻¹ as well as a high capacity retention of 93.2% after 200 charge/discharge cycles and 40 000 bending times. A variable stiffness property is revealed that can be controlled by battery configurations and deformation modes. Furthermore, the overlapping FLIBs can be housed directly into the architecture of several flexible devices, such as robots and grippers, allowing to create multifunctionalities that go far beyond energy storage and include load-bearing and variable flexibility. This study broadens the versatility of FLIBs toward energy storage structure engineering of flexible devices.