The combustion of kerosene: Experimental results and kinetic modelling using 1- to 3-component surrogate model fuels

The oxidation of kerosene Jet-A1 and that of n-decane have been studied experimentally in a jet-stirred reactor at atmospheric pressure and constant residence time, over the high temperature range 900–1300 K, and for variable equivalence ratio (0.5≤ϕ≤2). Concentration profiles of the reactants, stable intermediates, and final products have been obtained by probe sampling followed by on-line and off-line GC analyses. The oxidation of neat n-decane and of kerosene in these conditions was modeled using a detailed kinetic reaction mechanism (209 species and 1673 reactions, most of them reversible). The present model was successfully used to simulate the structure of a fuel-rich premixed n-decane–oxygen–nitrogen flame. In the modelling, kerosene was represented by four surrogate model fuels: 100% n-decane, n-decane-n-propylbenzene (74%/26% mol), n-decane-n-propylcyclohexane (74%/26% mol), and n-decane-n-propylbenzene-n-propylcyclohexane (74%/15%/11% mol). The 3-component model fuel was the most appropriate for simulating the JSR experiments. It was also successfully used to simulate the structure of a fuel-rich premixed kerosene–oxygen–nitrogen flame.     

Turbulent transport of passive scalar behind line sources in an unstably stratified open channel flow

This study employs a direct numerical simulation (DNS) technique to study the flow, turbulence structure, and passive scalar plume transport behind line sources in an unstably stratified open channel flow. The scalar transport behaviors for five emission heights (z_s = 0, 0.25H, 0.5H, 0.75H, and H, where H is the channel height) at a Reynolds number of 3000, a Prandtl number and a Schmidt number of 0.72, and a Richardson number of −0.2 are investigated. The vertically meandering mean plume heights and dispersion coefficients calculated by the current DNS model agree well with laboratory results and field measurements in literature. It is found that the plume meandering is due to the movement of the positive and negative vertical turbulent scalar fluxes above and below the mean plume heights, respectively. These findings help explaining the plume meandering mechanism in the unstably stratified atmospheric boundary layer.     

Numerical study on the influence mechanism of inlet distortion on the stall margin in a transonic axial rotor

A numerical study is conducted to investigate the influence of inlet flow condition on tip leakage flow (TLF) and stall margin in a transonic axial rotor.A commercial software package FLUENT,is used in the simulation.The rotor investigated in this paper is ND_TAC rotor,which is the rotor of one-stage transonic compressor in the University of Notre Dame.Three varied inlet flow conditions are simulated.The inlet boundary condition with hub distortion provides higher axial velocity for the incoming flow near tip region than that for the clean inflow,while the incoming main flow possesses lower axial velocity near the tip region at tip distortion inlet boundary condition.Among the total pressure ratio curves for the three inlet flow conditions,it is found that the hub dis-torted inlet boundary condition improves the stall margin,while the tip distorted inlet boundary condition dete-riorates compressor stability.The axial location of interface between tip leakage flow (TLF) and incoming main flow (MF) in the tip gap and the axial momentum ratio of TLF to MF are further examined.It is demonstrated that the axial momentum balance is the mechanism for interface movement.The hub distorted inflow could de-crease the axial momentum ratio,suppress the movement of the interface between TLF and MF towards blade leading edge plane and thus enhance compressor stability.     

Experimental investigations on liquid flow and heat transfer in rectangular microchannel with longitudinal vortex generators

The behaviors of improved Heat transfer and the associated higher pressure drop for liquid flow in rectangular micochannels with longitudinal vortex generators (LVGs) were determined experimentally for the Reynolds numbers of 170–1200 with hydraulic diameter of 187.5 μm and aspect ratio of 0.067 for LVGs with different number of pairs and angles of attack. It was found that the range of critical Reynolds numbers (600–730) were at a much smaller value by adding LVGs than the one without (Re ～ 2300); heat transfer performance was improved (9–21% higher for those with laminar flow and 39–90% for those with turbulent flow), while encountering larger pressure drop (34–83% for laminar flow and 61–169% for turbulent flow). Empirical correlations for these two parameters were then obtained by curve-fittings for a variety of rectangular microchannels under study.     

On the double-layer structure of the boundary layer adjacent to a sidewall of a differentially heated cavity

This study is concerned with the transition of the boundary layer adjacent to a sidewall of a differentially heated cavity to a double-layer structure and with the important flow and heat transfer features of the double-layer structure. The transition to the double-layer structure is examined by comparing numerical and experimental results. The mechanism responsible for the formation of the double-layer structure, i.e. the stratification of the fluid in the core, is discussed. Detailed discussion of the energy balance adjacent to the sidewall reveals that the heat transfer in the double-layer structure is rather complex. There is an opposing horizontal thermal diffusion within the double-layer structure.     

The interfacial strength and fracture characteristics of ethanol and polymer modified carbon nanotube fibers in their epoxy composites

Carbon nanotube (CNT) fibers spun from CNT arrays were used as the reinforcement for epoxy composites, and the interfacial shear strength (IFSS) and fracture behavior were investigated by a single fiber fragmentation test. The IFSS between the CNT fiber and matrix strongly depended on the types of liquid introduced within the fiber. The IFSS of ethanol infiltrated CNT fiber/epoxy varied from 8.32 to 26.64 MPa among different spinning conditions. When long-molecule chain or cross-linked polymers were introduced, besides the increased fiber strength, the adhesion between the polymer modified fiber and the epoxy matrix was also significantly improved. Above all, the IFSS can be up to 120.32 MPa for a polyimide modified CNT fiber, one order of magnitude higher than that of ethanol infiltrated CNT fiber composites, and higher than those of typical carbon fiber/epoxy composites (e.g. 60–90 MPa). Moreover, the composite IFSS is proportional to the tensile strength and modulus of the CNT fiber, and decreases with increasing fiber diameter. The results demonstrate that the interfacial strength of the CNT fiber/epoxy can be significantly tuned by controlling the fiber structure and introducing polymer to optimize the tube–tube interactions within the fiber.     

Dynamics and control of solar thermochemical reactors

A general dynamic model for solar-driven thermochemical processes is formulated based on unsteady mass and energy conservation equations coupled to the reaction kinetics. It is applied to two pertinent high-temperature thermochemical reactors for fuel production that make use of concentrated solar energy as the source of process heat, namely: an indirectly irradiated batch-operated packed bed reactor for the carbothermic reduction of zinc oxide, and a directly irradiated continuously operated particle flow reactor for the steam-gasification of petcoke. Model parameter identification and validation is accomplished by comparing numerically simulated and experimentally measured temperatures and outlet product concentrations. A linear feedback controller was implemented using the LQG/LTR design method. Simulations of the controlled reactor system with real solar irradiation data indicates improved quality and steadiness of product composition throughout transient solar input phases and superior solar-to-chemical energy conversion efficiency.     

Stress relaxation in carbon nanotube-based fibers for load-bearing applications

Carbon nanotube (CNT) based continuous fiber, a CNT assembly that could retain the superb properties of individual CNTs on a macroscopic scale, has emerged as a promising candidate for reinforcement in multifunctional composites. While existing research has extensively examined their short-term mechanical properties based upon quasi-static measurements, the long-term durability of CNT fibers has been largely neglected. Here we report time-dependent behavior of CNT fibers, with a particular focus on tensile stress relaxation. Both the pure CNT fiber and the CNT/epoxy composite fiber exhibited significant stress decay during the relaxation process, and this time-dependent behavior became more significant at a higher initial strain level, a lower strain rate and a greater gauge length. The present approach signifies a fundamental difference in the load-bearing characteristics between CNT fibers and traditional advanced fibers, which has major implications for the long-term durability of CNT fibers in load-bearing multifunctional applications.     

Enhanced photocatalytic H2 evolution and phenol degradation over sulfur doped meso/macroporous g-C3N4 spheres with continuous channels

S-doped meso/macroporous g-C₃N₄ spheres (SMCN) were successfully synthesized via an in situ novel method utilizing millimeter-scale porous silica spheres as template and thiourea as precursor and S source. Such SMCN possessed millimeter-scale spherical morphology with continuous channels at 20–80 nm in the interior of the spheres, and exhibited increased H₂ generation rate (15 times) and phenol degradation rate (5 times) under visible light irradiation compared with that over pristine g-C₃N₄, mainly due to the enlarged surface area, enhanced mass transfer and improved efficiency of charges separation all stemming from the synergetic effects of the S doping and pore creating. Notably, density functional theory (DFT) calculations were employed to further understand the mechanism of the photocatalytic enhancement with regard to the optical absorption property at atomic level. Combined with the finite difference time domain (FDTD) simulations aiming at evaluating the effect of the nanoscale pore architecture on the optical absorption ability, it was revealed that not only the S doping but also the meso/macroporous structure resulted in the enhancement of the optical absorption, which was considered to be an essential role for the enhanced photocatalytic performances over SMCN.     

Enhancement of thermal performance by converging-diverging channel in a micro tube combustor fueled by premixed hydrogen/air

As the core component of the micro thermophotovoltaic (MTPV) system, the micro combustor with a high and uniform wall temperature distribution is beneficial to improve the energy conversion efficiency. In this paper, a micro tube combustor with converging-diverging channel is proposed and the thermal performance is numerically investigated, compared with that of the micro combustor with cylindrical channel. The effects of inlet velocity of H₂/air mixture, dimensionless position and diameter of throat, and solid material on the thermal performance are widely analyzed. Results show that the outer wall temperature and emitter efficiency of the micro combustor with converging-diverging channel are higher than that of the micro combustor with cylindrical channel, and the converging-diverging channel has more uniform temperature distribution. The converging-diverging micro combustor with dimensionless throat position l = 0.375 and dimensionless throat diameter β = 0.4 is more suitable for the application of MTPV system. When H₂/air inlet velocity is 11 m/s and H₂/air equivalence ratio is 1.0, the mean wall temperature is increased by 82.39 K and the emitter efficiency is increased by 6.59%, while the normalized temperature standard deviation is reduced by 65.85%. Additionally, the use of SiC as wall material can improve the thermal performance of the micro combustor. It is worth noting that this work will offer us significant guidelines for the optimized work of micro tube combustor.