Photoelastic Effects in Phosphate Glasses

The stress-optical coefficients of RO-Pz05 glasses (R = Mg, Ca, Sr, Ba, and Zn) were measured, and the photoelasticity mechanisms were analyzed based on the equation expressing the relation among the photoelastic constants, the elastic moduli, and the refractive index of glasses. No simple relation was found between the stress-optical coefficient and the elastic modulus, indicating that the factor (p – q), where p and q are the Neumann strain-optical coefficients, is important. The change of (p – q) with glass composition is governed mainly by changes in the effect of the atoms, rather than the lattice. The atomic effect increases with decreasing radius of the divalent cation, except for Zn²⁺. The ZnO-containing glasses exhibit extraordinarily large atomic effects. The photo-elasticity mechanism is discussed in relation to the nature of the chemical bonds.     

Transmittance and cathodoluminescence of AlN ceramics sintered with Ca3Al2O6 as sintering additive

Aluminum nitride ceramics were prepared by sintering with 0–4.8 mass% of Ca₃Al₂O₆ (C₃A) as a sintering additive. The transmittance in the range of 260–550 nm increased with increasing amount of C₃A. The cathodoluminescence intensity attributed to oxygen-induced defects decreased with increasing amount of C₃A. From the results, the increase of the transmittance in the range of 260–550 nm was considered to be related to the decrease of the oxygen-induced defect density.     

Phase behavior in liquid crystallization for diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components

Phase behavior in liquid crystallization was studied for a series of liquid crystalline (LC) diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components, poly(n-butyl acrylate) (PBA) and poly[11-(4′-cyanophenyl-4″-phenoxy)undecyl acrylate] (PLC), respectively, using a time-resolved small-angle X-ray scattering (SAXS) techniques, DSC and polarized optical microscopy (POM). The block copolymers used had three kinds of copolymer compositions, 44, 20 and 15 wt% of PLC compositions (BLC44, BLC20 and BLC15, respectively). BLC44 showed a smectic liquid crystalline structure. In the process of liquid crystallization for BLC44, the SAXS peak due to the microphase separation structure existing before liquid crystallization was changed continuously to be at a smaller angular side, and at almost the same time, a new peak appeared at a further smaller angular side and developed. The former peak disappeared with the development of liquid crystallization. The behavior of these SAXS peaks suggests that the microphase separation structure was changed discretely at the transition from isotropic to smectic and that two phases coexist in the early stage of the liquid crystallization. The coexistence of two peaks in the early stage of the liquid crystallization corresponded to the POM observation. In the isotropization process, coexistence of two phases was not observed. For BLC20 exhibiting a cylindrical structure in both isotropic and liquid crystalline states, the liquid crystalline structure was not smectic but probably nematic, and the spacing was changed continuously in liquid crystallization. No liquid crystallization was observed in SAXS, POM and DSC for BLC15. The orientation of smectic layers within lamellar domains was investigated using 2D-SAXS images. The smectic layer was aligned perpendicularly to the lamellar interface.     

Skew simulation of a paper transferred by rubber rollers in printers

A skew of a paper transferred by rubber rollers in printers is simulated by FEM software. Effects of an imbalance of preload, an imbalance distribution of coefficient of friction and a front tension on the paper skew are investigated and how to determine the skew direction are shown. A simulation model is composed of a feed roller, a preload roller and a paper. The feed roller is rotated forcibly by a certain degree at every calculation step and a deformation, displacement and strain of the paper and rollers are calculated. A series of calculation results is shown as a motion simulation. The results show that the paper skews to the smaller preload side, to the smaller coefficient of friction side, or to the opposite side of the front tension. Further, effects of a skew prevention guide plate is simulated.     

Use of LINbO3 for Design of Device-type Catalysts with Activity Controllable Functions

A poled ferroelectric LiNbO₃ single crystal with high spontaneous polarization was employed as a catalyst support, and the static and dynamic effects of the polar substrate surfaces on the adsorptive and catalytic properties of thin film catalysts deposited were shown. For the static effect, it was demonstrated that the surface conductivity of copper and metal-free phthalocyanine films increased by the adsorption of NO gas, to a larger extent, when the substrate was the negative polar surface, compared to the positive one. The role of the polar substrates is explained In terms of a band bending model. For the dynamic effect, the Rayleigh surface acoustic wave generated on the LiNbO₃ substrate was shown to enhance the catalytic activity for ethanol oxidation on Cu and Ag thin film catalysts deposited on the propagation path. It is proposed that the catalyst activation is mainly due to an electric Held produced. The use of poled LiNbO₃ is suggested to be effective for the development of a device-type catalyst with activity controllable functions.     

The polymerization of N-vinylcarbazole in the presence of carbon black

In order to obtain more detailed information on the mechanism of the polymerization of N-vinyl-carbazole (N-VC) in the presence of carbon black, a comparison of the rates of conversion under various conditions was made and the following results were obtained. The phenolic hydroxyl groups on the surface of carbon black were found to have an ability to initiate the polymerization, and an increase in dielectric constant of the solvent increased the rate of polymerization. Using the mixture of N-VC and comonomers such as styrene or methyl methacrylate, we found that styrene gives a copolymer with N-VC, while methyl methacrylate gives no copolymer during the early stage of polymerization. The phenomena observed here indicate that the nature of polymerization of N-VC initiated by carbon black is cationic.     

The cyclicJ-integral as a criterion for fatigue crack growth

The definition of the cyclic J-integral is offered and its physical significance for fatigue crack growth is discussed using the Dugdale model on the assumption that the crack closure, cycle dependent creep deformation, and crack extension under cycling can be neglected. It is shown that the cyclic J-integral for small scale yielding is equivalent to theJ-integral for linear elastic crack independent of loading processes, while the value for large scale yielding varies with the loading processes. However, in both cases, the cyclicJ-integral remains constant during the reversal of loading under a constant stress range, if the first monotonic loading stage is excluded. In this situation, the cyclicJ-integral can be applied as a criterion for fatigue crack growth, since it is evaluated as a generalized force on dislocations to be moved or the energy flow rate to be dissipated to heat by the dislocation movements in an element just attached to the fatigued crack tip during one cycle of loading. It is suggested that the available experimental data of different materials for fatigue crack growth can be generalized to a unified formulation on the basis of the energy criterion. It is also deduced that the threshold J corresponding to K _th should be larger than 4 where is the surface energy of the material. Finally the operational definition of the cyclicJ-integral on single loadversus displacement curves is given for center cracked plate with wide uncracked ligaments in tension.

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Résumé On présente la définition de l'intégrale J cyclique et sa signification physique dans le cas d'une croissance de fissure de fatigue est discutée en utilisant le modèle de Dugdale et l'hypothèse que la fermeture de la fissure, la déformation de fluage liée au cycle, et l'extension de la fissure au cours du cycle peuvent être négligées. On montre que l'intégraleJ cyclique est, dans le cas d'écoulement plastique à faible échelle, équivalente à l'intégraleJ utilisée pour les fissures élastiques linéaires indépendamment des processus de mise en charge, tandis que la valeur de déformation plastique macroscopique varie avec le processus de mise en charge. Cependant, dans les 2 cas, l'intégraleJ cyclique demeure constante au cours du renversement de charge appliquée à tension constante si l'on exclut le premier stade de mise en charge monotone. Dans cette situation, l'intégraleJ cyclique peut être appliquée comme critère de la croissance d'une fissure de fatigue puisqu'elle représente une forme généralisée de force, un effort sur les dislocations à mouvoir ou à l'écoulement d'énergie dissipée en chaleur par les mouvements de dislocation dans un élément immédiatement solidaire de l'extrémité de la fissure de fatigue, au cours d'un cycle de mise en charge. On suggère que les données expérimentales disponibles sur différents matériaux pour la croissance d'une fissure de fatigue puissent être généralisées à une formulation unifiée, sur base d'un critère d'énergie. On déduit également que le seuil J correspondant à K _th devrait être plus grand que 4, où est l'énergie de surface du matériau. Finalement, la définition opérationnelle de l'intégraleJ cyclique sous simple charge en fonction des courbes de déplacement est fournie dans le cas d'une plaque comportant une fissure centrale et de larges ligaments non fissurés, soumises à traction.

     

Feasibility of a 1,400 m Span Steel Cable-Stayed Bridge

This paper describes the feasibility of 1,400 m steel cable-stayed bridges from both structural and economic viewpoints. Because the weight of a steel girder strongly affects the total cost of the bridge, the writers present a procedure to obtain a minimum weight for a girder that ensures safety against static and dynamic instabilities. For static instability, elastoplastic, finite-displacement analysis under in-plane load and elastic, finite-displacement analysis under displacement-dependent wind load are conducted; for dynamic instability, multimodal flutter analysis is carried out. It is shown that static critical wind velocity of lateral torsional buckling governs the dimension of the girder. Finally, the writers briefly compare a cable-stayed bridge with suspension bridge alternatives.     

Inverse determination of heat generation sources in two-dimensional homogeneous solids: Application to orthotropic medium

An implementation of the Network Simulation Method for determining the time-dependent heat generation of a source in a 2-D heat conduction problem under first and second type boundary conditions is presented. The thermal properties of the orthotropic solid are temperature-dependent. No prior information of the functional dependence of the time-dependent source was required. Input data for this inverse problem comprise the temperature history (measurements) at a particular location of the boundary. The common iterative least-squares approach, typical for this kind of ill-posed problem, is used in the estimation, while a piecewise continuous function is proposed as an approximate solution for the estimations. An application to estimate the triangular time dependence of the heat source generation, with error-affected measurements, is shown.