Monomer casting nylon-6-b-polyether amine copolymers: Synthesis and properties

MC nylon-6-b-polyether amine copolymers were prepared with macro-initiator based on amino-terminated polyether amine functionalized with isocyanate via in-situ polymerization. It was found that the introduction of polyether amine delayed the polymerization process of caprolactam by increasing apparent activation energy and pre-exponential factor, resulting in the decrease of molecular weight of nylon-6. The motion of molecular chain of the copolymers was easy because of the decreased hydrogen bonds and weakened inter-molecular forces. The physical entanglement of molecular chains of the copolymers was significant and strong which increased the entanglement density. Only the nylon-6 phase crystallized in the copolymers and the crystal grain size, spherulite size and crystallinity of the copolymers decreased. A small amount of γ crystal formed at high polyether amine content. The copolymers presented obvious strain hardening behavior in stress-strain curves and the loss factor dramatically increased while the glass transition temperature and storage module decreased. The fracture surface of the copolymers became rough and presented hairy structure, indicating that the toughening mechanism of the copolymers corresponded to the multi-layer crack extension mechanism.     

Hierarchical multi-reservoir optimization modeling for real-world complexity with application to the Three Gorges system

High dimensionality in real-world multi-reservoir systems greatly hinders the application and popularity of evolutionary algorithms, especially for systems with heterogeneous units. An efficient hierarchical optimization framework is presented for search space reduction, determining the best water distributions, not only between cascade reservoirs, but also among different types of hydropower units. The framework is applied to the Three Gorges Project (TGP) system and the results demonstrate that the difficulties of multi-reservoir optimization caused by high dimensionality can be effectively solved by the proposed hierarchical method. For the day studied, power output could be increased by 6.79 GWh using an optimal decision with the same amount of water actually used; while the same amount of power could be generated with 2.59 × 10⁷ m³ less water compared to the historical policy. The methodology proposed is general in that it can be used for other reservoir systems and other types of heterogeneous unit generators.     

Study on the non-uniform contact during ELID groove grinding

This paper introduces the potential feasibility that ELID (electrolytic in-process dressing) grinding replaces superfinishing in bearing manufacturing, but ELID grinding will bring new challenges. Different regions present distinguish surface profile due to the non-uniform contact in ELID groove grinding. However, few reports explaining the non-uniform contact are available. This article explores the mechanisms of the non-uniform contact during ELID groove grinding. Experiments on the non-uniform contact between bearing raceway and grinding wheel have been carried out under different conditions. The results show that non-uniform contact exists in ELID groove grinding process and it exerts influence on the profile of the raceway surface. Non-uniform contact influences the Rsk and Rku value all the time, but it influences the Ra value occasionally. Improvement strategies of eliminating the non-uniform contact are also discussed based on the experimental study.     

Modelling,simulation and identification of an engine air path electromechanical actuator

This paper deals with the modelling and the identification of an electromechanical Diesel engine actuator. The studied Bosch GPA-S actuator is designed for swirl/tumble flaps to control the air amount entering into the cylinder. This study aims to design a complete simulator that reproduces, with sufficient accuracy, the actuator dynamics taking into account the effects of the friction phenomenon. Hence, an overview of the actuator structure and its operation principle is first given. Then, its mathematical model as well as the nonlinearity, related to its behaviour, is discussed. Next, three identification procedures, which allow estimating both the system parameters and the friction model coefficients, are introduced. Finally, simulation results, using MATLAB, and experimental results, using LabVIEW, are presented demonstrating the effectiveness of the proposed techniques.     

Advanced exergy analysis of an absorption cooling machine: Effects of the difference between the condensation and absorption temperatures

The water–LiBr absorption machine was analyzed with the purpose of identifying the endogenous, exogenous, avoidable and unavoidable fractions of the exergy destruction. The latter was observed to be largely of endogenous nature, with the desorber and absorber being the major contributors. When the difference between the absorption and condensation temperatures was raised, both the first and second law efficiencies degraded. Furthermore, the absorber endogenous avoidable irreversibility was much larger than that at the desorber when the absorption temperature was lower than the condensation temperature, and the situation reversed when the absorption temperature became higher than the condensation temperature. The same trends were observed in terms of the exogenous avoidable exergy destruction. However, the endogenous unavoidable exergy destruction at the absorber was initially smaller than that at the desorber, and the two components equally contributed to the total endogenous unavoidable irreversibility when the absorption temperature became higher than the condensation temperature.     

Homogenization with uncertainty in Poisson ratio for polymers with rubber particles

The main aim of this work is dual computer analysis of probabilistic coefficients for the homogenized tensor of the polymer filled with the rubber particles having randomized Poisson ratios of both constituents. The major issue is to verify an influence of a randomness in rubber Poisson ratio close to the compressibility limit on the uncertainty of the effective tensor probabilistic characteristics. Probabilistic analysis presented here is carried out using mainly the stochastic perturbation technique provided by the common application of the traditional FEM commercial code ABAQUS and the symbolic computations package MAPLE. This FEM-based technique employs polynomial response function of the optimum order recovered from the weighted least squares method and following a set of deterministic solutions obtained for various values of the randomized input parameter. Optimization procedure is released entirely into a symbolic environment, where maximization of the correlation factor together with minimization of the fitting variance and approximation error are applied. Homogenization technique consists in equating of deformation energies for the real composite and the artificial one characterized by the effective elasticity tensor with uncertainty.     

Hygrothermal deformation of orthotropic nanoplates based on the state-space concept

This paper deals with the investigation of the effect of hygrothermal conditions on the bending of nanoplates using Levy type solution model employing the state-space concept. The nanoplates are assumed to be subjected to a hygrothermal environment. The two-unknown function plate theory is used to derive the governing differential equations on the basis of Eringen's nonlocal elasticity theory. The governing equations contain the small scale effect as well as hygrothermal and mechanical effects. These equations are converted into a set of first-order linear ordinary differential equations with constant coefficients. Analytical solution of bending response for nanoplates under combinations of simply supported, clamped and free boundary conditions is obtained. Comparison of the results with those being in the open literature is made. The influences played by small scale parameter, temperature rise, the degree of moisture concentration, boundary conditions, plate aspect ratio and side-to-thickness ratio are studied.     

Pool boiling of saturated FC-72 on nano-porous surface

Pool boiling heat transfer from nano-porous surface immersed in a saturated FC-72 dielectric fluid has been experimentally studied at atmospheric pressure (101 kPa). The data obtained from nano-porous surface (Anodisc 25) of thickness about 70 μm made from aluminum oxide (Al₂O₃) obtained from Whatman, were compared to that of a plain surface (aluminum) of thickness about 105 μm. From the experimental data obtained it was evident that there is a reduction of about 30% in the incipient superheat for the applied power for nano-porous surface over plain surface. SEM photographs of the nano-porous coating were taken for determining the size of the pores.     

Delayed failure of ceramic matrix composites in tension at elevated temperatures

Ultimate tensile strength of five different continuous fiber-reinforced ceramic matrix composites (CMCs), including SiC_f/BSAS (two dimensional (2D), 2 types), SiC_f/MAS (2D), SiC_f/SiC (2D), and C_f/SiC (2D, 2 types), was determined as a function of test rate at 1100–1200 °C in air. All five CMCs exhibited a significant dependency of ultimate tensile strength on test rate such that the ultimate tensile strength decreased with decreasing test rate. The dependency of ultimate tensile strength on test rate, the applicability of preload technique, and the predictability of life from one loading configuration (constant stress-rate loading) to another (constant stress loading) all suggested that the overall, phenomenological delayed failure of the CMCs would be governed by a power-law type of slow crack growth.     

Al–Si cast alloys under isothermal and thermomechanical fatigue conditions

This work presents a survey of the isothermal and anisothermal fatigue behavior of aluminum casting alloys obtained from different processes. Experimental results have shown that porosity, especially large and irregular pores, provides the main factor in decreasing fatigue properties of the tested alloys. In materials with similar porosity levels, other microstructural factors became relevant such as, matrix morphology and the amount of alloying elements. Fractographic analyses showed that fatigue cracks preferentially start to propagate in microcracks or interdendritic shrinkage usually located next to the surface. In most cases, propagation takes place in the eutectic phase, although in the thixoformed material, a transition from transgranular to intergranular mode was observed in the crack propagation mode.