Controlling Au electrode patterns for simultaneously monitoring electrical actuation and shape recovery in shape memory polymer

This paper presents an effective approach to achieve efficient electrical actuation and monitoring of shape recovery based on patterned Au electrodes on shape memory polymer (SMP). The electrically responsive shape recovery behavior was characterized and monitored by the evolution change in electrical resistance of patterned Au electrode. Both electrical actuation and temperature distribution in the SMP have been improved by optimizing the Au electrode patterns. The electrically actuated shape recovery behavior and temperature evolution during the actuation were monitored and characterized. The resistance changes could be used to detect beginning/finishing points of the shape recovery. Therefore, the Au electrode not only significantly enhances the electrical actuation performance to achieve a fast electrical actuation, but also enables the resistance signal to detect the free recovery process.     

Welding process selection for repairing nodular cast iron engine block by integrated fuzzy data envelopment analysis and TOPSIS approaches

The selection of welding process is one of the most significant decision making problems and it requires a wide range of information in accordance with the type of product. Hence, the automation of knowledge through a knowledge-based system will greatly enhance the decision-making process. A combined fuzzy data envelopment analysis (DEA) and TOPSIS is proposed to investigate the relative welding process selection factors and it can compare and evaluate different welding processes. The proposed approach compares each decision making unit (DMU) with the worst and the ideal virtual DMU and it ranks them via the relative closeness index. The proposed approach is used for ranking eleven welding processes which are commonly used for repairing nodular cast iron engine block in four cases and it is shown that the approach is sensitive to changes in dataset.     

Post microbuckling mechanics of fibre-reinforced shape-memory polymers undergoing flexure deformation

The buckling mechanics of fibre-reinforced shape-memory polymer composites (SMPCs) under finite flexure deformation is investigated. The analytical expressions of the key parameters during the buckling deformation of the materials were determined, and the local post-buckling mechanics of the unidirectional fibre-reinforced SMPC were further discussed. The cross section of SMPC under flexural deformation can be divided into three areas: the non-buckling stretching area, non-buckling compression area and buckling compression area. These areas were described by three variables: the critical buckling position, the neutral plane position and the fibre buckling half-wavelength. A strain energy expression of the SMPC thermodynamic system is developed. According to the principle of minimum energy, the analytical expressions of key parameters in the flexural deformation process is determined, including the critical buckling curvature, critical buckling position, position of the neutral plane, wavelength of the buckling fibre, amplitude of the buckling fibre and macroscopic structural strain of the composite material. The results showed that fibre buckling occurred in the material when the curvature increasing from infinitesimal to the critical value. If the curvature is greater than the critical curvature, the neutral plane of the material will move towards the outboard tensile area, and the critical buckling position will move towards the neutral plane. Consequently, the half-wavelength of the buckling fibre was relatively stabilised, with the amplitude increasing dramatically. Along with the increasing of the shear modulus, the critical curvature and buckling amplitude increase, while the critical half-wavelength of the fibre buckling decrease and the critical strain of the composite material increase. Finally, we conducted experiments to verify the correction of the key parameters describing SMPC materials under flexural deformation. The values determined by the experiments proved that the theoretical prediction is correct. Additionally, the buckling deformation of the carbon fibre generated a large macroscopic structural strain of the composite material and obtained a resulting large flexural curvature of the structure with minimal material strain of the carbon fibre.     

Electroactive shape memory polymer based on optimized multi-walled carbon nanotubes/polyvinyl alcohol nanocomposites

The development of shape memory polymers (SMPs) has gained remarkable attention due to their wide range of applications, from biomedical to electromechanical. In this work, we have developed and optimized an electroactive SMP based on polyvinyl alcohol/multi-walled carbon nanotubes (PVA/MWNTs) composites. When a constant voltage of 60 V was applied to the optimized sample, the polymer shape could be recovered to the original form within 35 s. Different weight fractions of MWNT/PVA composites were prepared by using a simple solution blending and transitional solution casting method, and their microstructures, electrical conductivities, thermal conductivities, and electroactive shape memory properties were investigated. According to our systematic analysis, the enhanced performance can be attributed to the reinforcement of MWNTs that led to the improved electrical and thermal conductivities of the PVA matrix.     

Porous LSCF/dense 3YSZ interface fracture toughness measured by single cantilever beam wedge test

Sandwich specimens were prepared by firing a thin inter-layer of porous La_0.6Sr_0.4Co_0.2Fe_0.8O₃ (LSCF) to bond a thin tetragonal yttria-stabilised zirconia (3YSZ) beam to a thick 3YSZ substrate. Fracture of the joint was evaluated by introducing a wedge between the two YSZ adherands so that the stored energy in the thin YSZ cantilever beam drives a stable crack in the adhesive bond. It was found that the extent of adhesive fracture increased with firing temperature and decreased with LSCF layer thickness. The adhesive failures were mainly at the interface between the LSCF and the thin YSZ beam and FEM modelling revealed that this is due to asymmetric stresses in the LSCF. The intrinsic adhesive fracture toughness of the LSCF/YSZ interface was estimated to be 11 J m⁻² and was not firing temperature dependent within the temperature range investigated.     

Mechanical properties of biomimetic ceramic with Bouligand architecture

Biomimetic Bouligand architecture is constructed in the ceramic to improve its toughness. Firstly, unidirectional carbon fiber-reinforced ZrB₂-SiC ceramic films are achieved through a vacuum-assisted filtration method using graphene oxide. Then, ceramic films are helically assembled at a fixed angle of 30° in the graphite die based on the fiber orientation. Finally, the spark plasma sintering method was utilized to densify helical assembly carbon fiber/ceramic films. By constructing Bouligand structure, high fracture toughness (7.4 MPa·m^0.5) and work of fracture (∼1055 J/m²) are achieved in ZrB₂-based ceramic. The toughening mechanisms mainly are crack deflection, twisting and branching, carbon fiber pulling out, and bridging.     

‘Two way’ shape memory composites based on electroactive polymer and thermoplastic membrane

A practical and facile strategy was proposed to fabricate composites that not only use the properties of individual components (commercial electroactive polymer and thermoplastic resin) to their advantage, but also produce synergy effect of ‘two way’ shape memory properties. In this design, electroactive polymer is treated as soft segment which provides actuation force via converting electrical energy to dynamic energy. Thermoplastic material serves as ‘hard segment’ to help with fixation of temporary shape thanks to its re-structuring and stiffness/modulus changing abilities through the reversible transitional temperature. Compared with traditional one way and two way shape memory materials, this composite material has the capability of changing shape without pre-programming. High shape recover property (99 ± 0.3%.) has been obtained due to the rubber elasticity of electroactive polymer matrix. Many features could be brought up based on this design, such as accurate control over deformation by changing strength of applied electric field as well as tailorable stimulus temperature and mechanical properties.     

An axisymmetric elastic analysis for circular sandwich panels with functionally graded cores

This paper presents an analytical solution in the framework of the elasticity theory, which is useful in describing the elastic bending response of axisymmetric circular sandwich panels with functionally graded material cores and homogeneous face-sheets. The Young’s modulus of the core is assumed to be exponentially dependant on the transverse direction and the Poisson’s ratio as well as uniform and equal to the face-sheets ratio. The elastic solution is obtained using a Plevako representation, which reduces the problem to the search of potential functions satisfying linear fourth-order partial differential equations. We explicitly obtain the analytical solution by writing the potential functions as Fourier Bessel expansions with respect to the radial coordinate. A comparative study of functionally graded versus a homogeneous sandwich core is presented by considering the first term of the expansion as the loading condition. In this way, the solution is written in a closed form and furnishes a benchmark to accurately investigate the agreement with the structural theory results.