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《International Journal of Hydrogen Energy》2019,44(54):28984-28995
We simulate agglomeration in different fuel cell catalyst ink solutions using Discrete Element Method. Carbon support is modelled as particles in various inks with ionomer and various solvents. The particles interact with particle-pair forces resulting in agglomerate build-up. The classical colloidal theory with van der Waals and electric double layer forces underestimates the ink stability, which motivates the development of a new model of polymer force between particles. The force is activated when there is a bridging of polymer between the carbon black particles, and the strength is dependent on the ionomer interaction with the solvent by the dielectric constant. A critical dielectric constant was defined for which ionomer form a web-like polymer network that increases the ink stability. This modification can explain the trend of the ink stability, and the model can simulate the effect of different solvents on the agglomerate size distribution with good agreement with experimental results. 相似文献
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通过断口分析、化学成分分析、金相检验和硬度测试对皮卡车的钢板弹簧断裂的原因进行了分析。结果表明:钢板弹簧表面存在凹坑造成了应力集中,而且板材的非金属夹杂物超标,降低了疲劳强度,在交变应力载荷的作用下,最终造成钢板弹簧发生了早期疲劳断裂。 相似文献
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平衡轴系统配合间隙的设计要考虑形状公差及位置公差、材料线膨胀系数等因素的综合影响,考虑不全面会导致实际工作的配合间隙不合理,过大或者过小都可能导致抱轴问题的发生。优化配合间隙能够有效地解决抱轴问题,但需要重新评价对整机润滑系统、NVH性能的影响并加以验证。试验结果表明:间隙的优化有效解决了平衡轴抱轴问题,同时对系统油压、NVH性能带来影响在可接受的范围内。 相似文献
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低速大负荷早燃现象是制约增压直喷汽油发动机低速性能提升的主要因素之一,早燃易导致发动机火花塞烧蚀、活塞熔顶等质量问题,所以在发动机设计开发过程中必须对早燃问题加以优化改善。阐述了早燃产生的机理,更换不同机油、改变压缩比以及空燃比进行试验,结果表明:更换机油以及改变空燃比能够降低早燃频次,改变压缩比对早燃无影响。 相似文献
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《International Journal of Hydrogen Energy》2021,46(66):33300-33313
The ionomer state in the catalyst ink of a proton exchange membrane fuel cell (PEMFC) plays a critical role in the formation of the catalyst/ionomer interface on the catalyst layer (CL). In this study, the effect of ionomer dispersion state on catalyst ink dispersion and the construction of a reasonable CL was investigated. The study of catalyst inks revealed that the dispersion of n-propanol (NPA) -ionomer dispersion or sonication could effectively reduce the catalyst particle size in inks. For shear-dispersion and homogenizer-dispersion inks, the catalyst particle size was reduced from 6.17 nm to 5.12 nm and from 5.12 nm to 4.67 nm, respectively. The ionomer dispersion was capable of significantly reducing the size of agglomerates in the ink, which resulted in a reduction in the particle size of agglomerates on the surface of the cathode CL and an improvement in its flatness. The pore size distributions of the MEA cathode catalyst layers showed that water bath ultrasonic treatment of the ionomer could result in a more reasonable pore structure for the catalyst layer. The single-cell test revealed that changing the ionomer's dispersion state could significantly increase the fuel cell's output voltage to 0.707 V at 1000 mA cm−2, and the cell's power density to 1028 mW cm−2 at 2000 mA cm−2. 相似文献
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