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1.
In this work, TiO2 nanoparticles are surface modified by NH2-terminated organic moieties arised from 4,4′-methylene diphenyl diisocyanate (MDI). These nanoparticles are incorporated into ether-based segmented polyurethane (SPU) matrix. MDI is utilized as monomer together with poly(tetramethylene oxide) (PTMO) comonomer for preparing the final polymer as well. The NH2-functionalized TiO2 nanoparticles are covalently linked to the NCO terminals of the resulting SPU macromolecules during film preparation stage. Therefore, in addition to butylene glycol, these surface modified nanoparticles with enhanced organophilicity could play the role of the second chain extender of NCO-capped SPU macromolecules through formation of urea linkages. Optical and thermal behaviors of the transparent and flexible film (SPU/TiO2–MDI) is compared with those of unmodified TiO2 (SPU/TiO2) and TiO2-unloaded SPU films. Though the particle loading is only 5 wt.%, incorporation of TiO2 and TiO2–MDI nanoparticles into the SPU polymer enhances significantly the light absorption in UV region at 300–400 nm. SEM images of the prepared films clearly show a considerable decrease in particle aggregation for TiO2–MDI into SPU matrix compared to that of unmodified TiO2. TG analyses indicate a one-step decomposition pattern with onset temperatures of about 360 and 380 °C for neat SPU and SPU/TiO2–MDI, respectively. Moreover, DTA thermograms of both nanocomposites show obviously two exothermic phase transitions in the thermal range of 330–440 °C. 相似文献
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Haddaji Younesse Hamdane Hasna Majdoubi Hicham Mansouri Said Allaoui Driss El bouchti Mehdi Tamraoui Youssef Manoun Bouchaib Oumam Mina Hannache Hassan 《SILICON》2021,13(7):2389-2400
Silicon - Geopolymers produced with metakaolin (MK) and thermally untreated phosphate sludge (PS) are beneficial and environmentally advantageous materials, but their fragility limits its... 相似文献
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In this paper, a nano-scratch testing approach was used to measure and evaluate the abrasion wear resistance of high-chromium white cast irons in order to understand the wear mechanism in the interaction between the high-chromium white cast iron and the cBN cutting tool during the machining process. Scratch testing was performed on a nanoindentation instrument using a diamond indenter as the scratch tool. Linear multi-pass scratches in the same path were made on pre-worn surfaces of test materials. The correlation of the scratching resistance and tool wear measured from the machining is presented by the flank wear and maximum scratch depth. The appearance of the cutting edge on a cBN tool suggests that the abrasion wear is mainly related with a combined effect of the carbides and the matrix during machining the high-chromium white cast iron. 相似文献
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《Materials Letters》2005,59(24-25):3069-3072
The nanocrystalline ribbons Fe90.3−xZr7B2.7Cux with low Cu contents can be directly obtained through melt-spinning technique with an appropriate low quenching speed such as 22 m/s. Sizes of bcc-Fe grains precipitated in Fe90.3−xZr7B2.7Cux as-spun ribbons were 17 nm for x = 0.75, 15 nm for x = 1 and 12 nm for x = 1.25. The addition of Cu reduces grain size of bcc-Fe in as-spun nanocrystalline Fe90.3−xZr7B2.7Cux ribbons. Among the investigated samples (0.5 ≤ x ≤ 1.5), the largest magnetoimpedance can be obtained in the nanocrystalline Fe80.3Zr7B2.7Cu1 as-spun ribbon with x = 1. The value of magnetoimpedance (Z(H) − Z(0)) / Z(0) under H = 90 Oe for Fe80.3Zr7B2.7Cu1 as-spun ribbon reaches − 28.2% at a frequency of 1 MHz. 相似文献
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高温合金因优良的综合高温性能在航空航天、石油化工等领域有广泛应用,高温合金环锻件主要用于机匣、燃烧室、密封环等部件。随着高性能航空发动机的发展,对高品质高温合金环锻件的需求日益增加。以往高温合金研究重点在于涡轮盘和叶片材料的合金优化设计、制备工艺和变形机理研究等,而对高温合金环锻件研究报道稍显薄弱。为此,本文总结了高温合金环形件环轧技术的发展、数值模拟在高温合金环轧技术探索中的应用、主要高温合金环锻件材料的种类以及高温合金环锻件组织控制的难点,以期为高品质高温合金环锻件的研发和制备提供一定的理论参考。 相似文献
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