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排序方式: 共有212条查询结果,搜索用时 187 毫秒
1.
《Ceramics International》2020,46(14):22282-22289
Self-assembly is an emerging strategy for preparing composite cathodes with good oxygen electrochemical reduction activity and congenital chemical compatibility for intermediate-temperature solid oxide fuel cell (IT-SOFC). Here we report that a self-assembled BaCo0.6Zr0.4O3-δ (BZC-BC) nanocomposite is prepared through one-pot glycine-nitrate process and exhibits high cathode performance. The BZC-BC nanocomposite is composed of 62 mol% cubic perovskite BaZr0.82Co0.18O3-δ (BZC) as an ionic conductor and 38 mol% hexagonal perovskite BaCo0.96Zr0.04O2.6+δ (12H-BC) as a mixed ionic and electronic conductor. The BZC-BC nanocomposite has the pomegranate-like particles aggregated with a larger number of nanoparticles (50-100 nm) which greatly enlarge the three-phase boundary sites. The BZC-BC nanocomposite exhibits a thermal expansion coefficient of 12.89 × 10−6 K−1 well-matched with that of Ce0.8Gd0.2O3-δ (12.84 × 10−6 K−1) electrolyte. The high electro-catalytic activity of BZC-BC nanocomposite cathode for oxygen reduction is reflected by the low polarization resistances of oxygen ions incorporation at cathode/electrolyte interface (0.02823 Ω cm2), oxygen species diffusion (0.03702 Ω cm2) and oxygen adsorptive dissociation (0.07609 Ω cm2) at 700 °C. The single cell with BZC-BC nanocomposite cathode achieves the maximum power density of 1094 mW cm−2 at 650 °C and shows good stability under 25 h run. 相似文献
2.
3.
《Journal of the European Ceramic Society》2006,26(10-11):1929-1932
In this work, sintering behaviour of Bi2O3–ZnO–Nb2O5 compounds was investigated in order to develop LTCC materials with suitable microwave properties. Structure, dielectric properties and sintering were studied for ceramic dielectrics based on the system: Bi2ZnNb2O9 with the pyrochlore structure and ZnNb2O6 with a columbite one. The work was carried out over a wide range of initial components concentration. Ceramic samples of these materials were prepared by the mixed oxide technique. The effect of adding glass to the materials have been discussed. The sintering behaviour, dielectric permittivity, quality factor and crystal structures have been characterized for ceramic samples depending on compositions. Low-temperature co-firable ceramic material with ɛ ∼ 30, τɛ = 0 and Q × f = 3500 GHz based on the above system was synthesized. 相似文献
4.
《Journal of the European Ceramic Society》2021,41(16):48-59
Zirconium Carbide (ZrCx) was irradiated with 10 MeV Au3+ ions to a dose of 10 displacements per atoms (dpa) and subsequently with 100 and 300 keV electrons in a transmission electron microscope (TEM). After ion irradiation, dislocation loops were observed in the microstructure and an increase in the number of carbon vacancies was revealed by Raman spectroscopy. Grazing incidence X-ray diffraction (GIXRD) analysis showed that neither amorphization nor oxidation occurred during ion irradiation of the specimen. Subsequent electron irradiation of the pre-implanted ZrCx foil led to formation of nanosized tetragonal ZrO2 precipitates (5−10 nm diameter) on the surface of the TEM lamella. The formation of the new oxide phase was not related to the electron beam-induced heating of the specimen, but to electron stimulated oxidation caused by the residual oxygen inside the transmission electron microscope. Changes in size and density of ZrO2 crystallites were observed between the pristine and ion irradiated ZrCx regions following electron irradiation, suggesting that the initial microstructure of the ZrCx substrate played a key role in the nucleation and growth of the oxide islands. The obtained results provide insights into the microstructural response of ZrCx to different types of radiation and the inadvertent effects of the electron beam during TEM analysis of in-situ and ex-situ ion irradiated ZrCx. Additionally, the findings of this work suggest a method to prepare local ZrO2 nanoprecipitates within ZrCx grains by selective electron beam irradiation. 相似文献
5.
Jun Wang Zhiping Sun Baoluo Shen Shengji Gao Rulin Zuo Cong Li Sijiu Huang 《Journal of Materials Engineering and Performance》2006,15(3):316-319
The relationship between secondary carbide precipitation and transformation of the 16Cr-1Mo-1Cu white iron and abrasion resistance
were investigated. The results show that secondary carbide precipitation and transformation at holding stage play an important
role in the hardness and abrasion resistance. After being held for a certain time at 853 K for subcritical treatment, the
grainy secondary carbide, (Fe,Cr)23C6, precipitated first and then Fe2MoC or MoC carbides precipitated in the alloy, both of which improve the bulk hardness and abrasion resistance of the alloy.
The reasons for these improvements are the secondary carbide precipitates from the austenite and the retained austenite transforms
into the martensite, both make the matrix strengthen. So the matrix has more effective support to the harder eutectic carbide
against exterior abrasion. With expanding the holding time, the in situ transformation from the granular (Fe,Cr)23C6 carbide into laminar M3C carbide causes the formation of the pearlitic matrix and an associated decrease of the alloy abrasion resistance. 相似文献
6.
对锆-4合金低周疲劳裂纹扩展过程进行了探索性的研究。通过分析锆-4合金低周疲劳断口在裂纹扩展方向上能量及分形维数变化趋势,发现锆-4合金动态裂纹扩展中扩展期由3个阶段组成,每一阶段的能量和分形维数都不同。A-B段的能量最小,归一化值为0-0.0156,A-B段的分形维数居中,在工工方向均值为2.2796,标准差为0.0277,在LH方向均值为2.4516,标准差为0.0592。D-E段能量远大于A-B段,归一化值为0.8754~0.9652,但分形维数最小,LL方向均值为2.2214,标准差为0.0131,LH方向均值为2.3477,标准差为0.0550。F-H(或G-H)段能量最大,归一化值达到1,同时分形维数也达到最大,LL方向均值为2.3414,标准差为0.0704,LH方向均值为2.5398,标准差为0.0263。虽后,根据二次电子成像原理以及锆-4合金低周疲劳断口的形貌特征对此现象进行了初步分析。 相似文献
7.
Phase formation and modification of corrosion property of nitrogen implanted Ti-Al-V alloy 总被引:1,自引:0,他引:1
In the present investigation, polished samples were implanted with nitrogen ion at an energy of 60 keV and implantation doses were 1×1016, 5×1016, 1×1017 and 6×1017 ions/cm2. Glancing incidence X-ray diffraction was employed on the implanted specimens to understand the phases formed with increasing dose. The valence states of nitrogen, titanium and carbon on the sample surfaces were analyzed by X-ray photoemission spectroscopy. The corrosion resistance was examined by the electrochemical methods in a solution with pH=10 at room temperature in order to determine the optimum dose that can give good corrosion resistance in a simulated nuclear reactor condition. Scanning electron microscopy was used to observe the topographies of nitrogen-implanted Ti-Al-Zr after potentiodynamic measurement. It was found that implanted nitrogen dissolved in titanium matrix with increasing dose and the resultant nitrides such as TiN and Ti2N precipitated. Implantation of nitrogen ions into the surface of Ti-Al-V alloy improves its corrosion resistance, and the increase of the corrosion resistance depends on the nitrogen dose employed; the maximum improvement of the corrosion resistance was observed at a dose of 1×1017 N+/cm2. 相似文献
8.
Several V-W-Ti alloys with about 50% reduction in thickness by cold rolling were isochronally annealed at temperatures from 100 to 1100 °C. Hardness was measured after the annealing. By comparison with V4Cr4Ti and V4Ti alloys, the V6WTi alloy was found to begin recovery at a temperature about 100 °C higher, while the full recrystallization temperature was around 900 °C for all of the alloys. Hardness decreased successively above 500 °C in V8W, as is the case in pure V. Impurity induced hardening was observed around 300 °C only in the alloys without Ti. Precipitation and the interaction between interstitial impurities and dislocations were supposed to be the main contributors to the different recovery and recrystallization behaviors of the alloys. 相似文献
9.
《Carbon》2014
Applying a first-principles computational approach, we have systematically analyzed the effects of [2+2] cycloaddition oligomerization of fullerene C60 chains on their junction electronic and charge transport properties. For hypothetical infinite C60 chains, we first establish that the polymerization can in principle increase conductance by several orders of magnitude due to the strong orbital hybridizations and band formation. On the other hand, our simulations of the constant-height scanning tunneling microscope (STM) configuration shows that, in agreement with the recent experimental conclusion, the junction electronic structure and device characteristics are virtually unaffected by the C60 chain oligomerization. We further predict that the switching characteristics including even the ON/OFF-state assignment will sensitively depend on the substrate metal species due to the Fermi-level pinning at the substrate-side contact and the subsequent energy level bending toward the STM tip-side contact. We finally demonstrate that a force-feedbacked nanoelectromechanical approach in which both of the C60–electrode distances are kept at short distances before and after switching operations can achieve a metal-independent and significantly improved switching performance due to the Fermi-level pinning in both contacts and the large intrinsic conductance switching capacity of the C60 chain oligomerization. 相似文献
10.
《Journal of Industrial and Engineering Chemistry》2014,20(4):1591-1595
A sample of 86 wt% MgH2–10 wt% Ni–2 wt% NaAlH4–2 wt% Ti (named MgH2–10Ni–2NaAlH4–2Ti) was prepared by reactive mechanical grinding. Activation of the sample was not required at 573 K. At the first hydriding–dehydriding cycle (n = 1), the sample absorbed more than 5 wt% H at 573 K under 12 bar H2 for 60 min. The hydriding rate increased as the temperature increased from 423 K to 553 K. MgH2–10Ni–2NaAlH4–2Ti showed quite high hydridng rates at relatively low temperatures of 423 K and 473 K under 12 bar H2, absorbing 4.02 wt% H for 60 min at 473 K. 相似文献